丙烯高温氯化法生产环氧氯丙烷技术分析

由于环氧树脂、合成甘油等产品需求强劲。促使国内环氧氯丙烷需求量的快速增长。但国内的生产能力和产量远不能满足实际需要.需大量进口。丙烯合成环氧氯丙烷技术成熟、原料供应充足、投资不算太大、利润率较高.能使投资者得到较满意的回报。     

钛酸酯催化环氧树脂固化动力学研究

用FTIR“原位”技术,研究了钛酸酯(Tc-114)偶联剂对环氧E-44和二氨基二苯基甲烷(DDM)固化反应的催化作用,得出固化程度与时间的关系曲线。又根据DSC曲线,分别算出加有Tc-114和不加Tc-114的两个固化体系的反应表观活化能和反应级数。结果表明,Tc-114的存在使环氧固化反应活化能降低,催化作用明显。     

有机纤维材料用软膜乳液阻燃剂的制备

采用甲醛、尿素、三聚氰胺、脒基脲磷酸盐为原料,以硼砂、硼酸、氨水为pH调节剂合成了保护胶;在保护胶存在下,以预乳化的丙烯酸酯混合单体于82-88℃共聚合成乳液,将其涂布于有机纤维材料,干燥后得软膜透明阻燃涂层。用其处理的涤棉布阻燃性能为:损毁长度68mm、续燃时间1s、阴燃时间3s、氧指数62、吸附干量287g/kg,处理的纸板的阻燃性能为:平均炭化长度77mm、平均续焰时间2s、平均续灼燃时间32s、吸附干量283g/kg。     

有机硅丙烯酸酯增深剂的制备及应用

由乙烯基三乙氧基硅烷与KH-550、丙烯酸酯类单体在阴/非离子表面活性剂存在下，通过乳液聚合制得带蓝光的半透明有机硅丙烯酸酯乳液．该乳液粘度小，有机硅质量分数15％，总固体质量分数30％，该增深剂既可单独使用，也可与氨基硅油乳液复配，经蓝色16电力纺、黑色03双绉等真丝产品增深，其增深度可达15％，但亲水性有所下降．     

硫磷化丙烯酸酯的合成及应用

以硫磷化合物和丙烯酸酯为原料，合成了硫磷化丙烯酸酯极压抗磨剂，该剂具有良好的热氧化安定性，水解安定性及抗乳化性能。用该剂复配抗氧剂，金属钝化剂，防锈剂及其它抗磨剂所调制的复合剂应用于32^#HM抗磨液压油中模拟数据全部达到标准要求指标。     

UV-固化光纤色标油墨

报导了一类新型的化学功能材料———ＵＶ固化光纤色标油墨。该材料由可ＵＶ固化的有机硅环氧安息香酸丙烯酸酯（ＳＥＢＡ）和脂环族环氧丙烯酸酯（ＡＣＥＡ）两种光敏预聚物为基料，以自行合成的光敏染料———分散红氨基甲酸酯丙烯酸酯（ＲＵＡ）、分散蓝氨基甲酸酯丙烯酸酯（ＢＵＡ）和吖啶黄氨基甲酸酯丙烯酸酯（ＹＵＡ）为着色剂，加入必要的添加剂配制而成的ＵＶ固化光纤色标油墨。该色标油墨已在光纤生产中得到应用。     

改性己二胺制备TG301环氧树脂室温固化剂

已二胺经与环氧树脂进行羟烷基化及与丙烯腈进行氰乙基化反应达到改善低熔点低毒性．低脆性的综合效果．文中介绍了改性乙二胶固化剂的制备方法，质量指标和有关固化特性等．     

Investigation into the morphological and mechanical properties of date palm fiber-reinforced epoxy structural composites

This study aims to examine the morphology and mechanical properties (tensile, flexural, and compressive) of epoxy composites reinforced with epoxy date palm leaves (EDPL), epoxy date palm branch (EDPB), and epoxy/hardener date palm core shell (EDPC) fibers (particle size <1 μm depend on the date palm fibers). A three-step technique was used to obtain the composites. The EDPL composites showed a maximum tensile strength of 3.45 MPa, while the EDPB composites showed maximum compressive and flexural rigidity of 9.46 and 5.55 MPa, respectively, owing to the good compatibility of fiber-matrix bonding. In this work, epoxy composites reinforced with date palm fibers (DPF) leaves, branches, and core shell were recycled using a cost-effective and easily reproducible three-step technique. EDPC fibers fabricated with 64.65% weight carbon fibers content demonstrated improved tensile strengths and stiffness properties. The three samples of palm date composites revealed mechanical properties that could be used to trial these fibers for manufacturing purposes, and to exploit their extraordinary mechanical properties shown in current results.     

Synergistic effects of organically modified montmorillonite in combination with metal oxides on the fire safety enhancement of intumescent flame-retarded epoxy resins

Synergistic effects of organically modified montmorillonite (OMMT) in combination with different metal oxides (Bi₂O₃, Sb₂O₃, and MoO₃) on the fire safety enhancement of the intumescent flame-retarded epoxy resins (EPs) were systematically evaluated. The results from X-ray diffraction (XRD) and scanning electron microscopy (SEM) analyses show that the OMMT and metal oxides acquire a uniform distribution in the EP matrix, and OMMT platelets exhibit a fully exfoliated state. The flammability and thermogravimetry (TG) tests show that the intumescent flame retardant (IFR)-OMMT-metal oxide ternary system can endow EPs with the higher synergistic efficiencies on the enhancement of flame retardancy, smoke suppression properties, and charring ability compared to those of IFR or IFR-OMMT system, and the synergistic efficiency is the following order: IFR/OMMT/Sb₂O₃ > IFR/OMMT/MoO₃ > IFR/OMMT/Bi₂O₃. In particular, the sample, filled with 1.5 wt% OMMT, 1.5 wt% Sb₂O₃, and 27 wt% IFR, passes the UL94 V-0 rating and acquires the highest limiting oxygen index value of 28.5% among the samples. The IFR-OMMT-metal oxide ternary system exerts a better synergistic effect on the generation of crosslinking and aromatic structures that supply the excellent charring effect and barrier effect for the EPs, and the synergistic efficiency of IFR-OMMT-metal oxide ternary system is varied with the types of metal oxides.     

环氧树脂流变学的研究进展

综述了近20年来环氧树脂流变学的研究进展。利用流变学来指导环氧树脂的最新应用,包括环氧树脂电子浆料例如底部填充胶（underfill）,环氧树脂基复合材料,环氧树脂涂料,环氧树脂黏合剂,环氧树脂与其他树脂/橡胶的复合体系等。环氧树脂体系中的填料规格、加入量以及环氧树脂的固化过程与黏度等流变指数息息相关。随着芯片等领域技术的快速发展,流变学在环氧树脂中的应用还会得到进一步加强。