新型复合聚结板式油水分离器

通过对聚结板式油水分离器传质过程机理的研究 ,开发出能够强化油水分离过程的新型高效复合聚结板。复合聚结板的两表面分别具有良好的亲水和亲油性能 ,从而使聚结板式油水分离器的分离效率提高 2 5 % ,处理能力增加 4 0 %。     

相容剂对聚丙烯／滑石粉增容作用研究

作者采用熔融接技方法制备PP-g-AA和PP-g-MAH,并比较了这两种相容剂对PP/滑石粉体系的增容效果。着重研究了引发剂含量、单体含量对PP-g-AA增容作用的影响以及PP-g-AA用量对PP/滑石粉体系力学强度的影响。     

Polypropylene (PP)–Acacia mangiumcomposites: the effect of acetylation on mechanical and water absorption properties

Acacia mangiumwood flour (AMWF)–polypropylene (PP) composites were produced at different filler loading (20, 30, 40, and 50 w/w) and mesh no. (35, 60, 80, and 100 mesh). The AMWF–PP composites (using unmodified or modified wood flour) were compounded using a Haake Rheodrive 500 twin screw compounder. The mechanical and water absorption (WA) properties of modified (only at mesh no. 100) and unmodified AMWF–PP composites were investigated. Increase in the mesh number (35–100) of the unmodified AMWF showed increased flexural and impact properties. Flexural modulus exhibited higher properties as the filler loading increased (20–50). However, flexural and impact strength showed the opposite phenomenon. Water absorption and thickness swelling increased as the mesh number and filler loading increased. This has been attributed to the presence of hydrophilic hydroxyl groups of the filler. Modified AMWF–PP composites exhibited higher mechanical properties and good water resistance when compared to unmodified AMWF–PP composites at all values of filler loading. The evidence of the failure mechanism (from impact strength) of the filler–matrix interface was analyzed using scanning electron microscope.     

沥青及聚丙烯纤维增韧粉煤灰-矿渣基地质聚合物的制备

本文采用双掺沥青和聚丙烯纤维对碱激发粉煤灰-矿渣基地质聚合物进行了强化增韧研究.结果表明当沥青及聚丙烯纤维掺量分别为1wt％和0.6wt％时,地质聚合物28 d龄期表现出9.7 MPa的最高抗折强度.XRD物相分析结果表明,双掺沥青和聚丙烯纤维对该地质聚合物的物相结构没有造成影响.SEM结合断裂韧度计算结果发现纤维与地质聚合物基体结合紧密,纤维的拔出长度较长,表明聚丙烯纤维可以提高试件的断裂韧度,达到增韧效果.     

聚丙烯离子交换纤维研究

利用超声波分散原理将苯乙烯（St）分散到聚丙烯纤维（PP）中，以过氧化苯甲酰（BPO）作为引发剂，使苯乙烯接枝到PP纤维表面，得到PP－g-St纤维；然后用浓硫酸将PP－g-St纤维磺化，制成强酸型离子交换纤维。研究了反应时间、反应温度等对离子交换纤维的质量摩尔浓度的影响，并用红外光谱加以表征。结果表明：温度90℃下磺化反应2h，可得到离子交换质量摩尔浓度为0.95mmol/g的强酸型离子交换纤维。     

Application of an interpenetrating network model to the solid deformation of a quenched isotactic polypropylene film

The molecular orientation and deformation mechanisms of a quenched isotactic polypropylene (iPP) film deformed at temperatures between 303 K and the melting point are studied. At draw temperature T_E less than 400 K where the degree of crystallinity does not change markedly, a linear relationship between molecular orientations of the crystalline and the amorphous phases is revealed and the slope is estimated about 1.82. The interpenetrating network (IPN) model, that takes into account the plastic response of the crystalline (C) network formed by a small portion of crystallites adhered through intercrystalline links and the pseudo-affine deformation of the crystallite enhanced amorphous matrix (CEAM) network, is able to account for inhomogeneous deformation behavior on the mesoscale accompanied with the localized necking in this T_E range. Meanwhile, the initial Young's modulus and the true yield stress exerted by the deformation of the rigid C network exhibit the Arrhenius type of dependence on T_E. The apparent shear modulus of the CEAM network as a function of T_E is discussed in relation to variations in numbers and average molecular weights of the crystalline and the amorphous sequences being manifested by small consecutive endothermic and exothermic peaks in the DSC curve. The IPN model becomes invalid for deformations above T_E=400 K where morphological changes are induced due to melting of crystallites as proved from the DSC measurement.     

常用的几种低热粘结温度柔软型PP短纤维的剖析与研讨

应用ＤＳＣ,ＷＡＸＤ,ＳＥＭ和红外光谱等技术对热轧法生产卫生用薄型非织造布的几种常用纤维进行了剖析,并对其形态结构、热性能、力学性能、含油率、含湿率、抗静电性和渗水性等进行了比较和研讨。结果表明：低热粘结温度ＰＰ短纤维多为细旦、低强、高伸度、低起始熔融温度和低序态,且适宜的含油率、含湿率和表面比电阻可保证梳理性好,成网均匀     

模拟夏季施工环境下混凝土早期收缩试验研究

对夏季高温日晒、风吹的施工环境进行了模拟,考察了采取两种养护措施和掺加三种特殊材料对混凝土在此模拟环境下早期收缩性能的影响.通过复掺聚丙烯纤维和膨胀剂,研制了一种在夏季施工环境下10d内几乎不产生收缩的混凝土,并对在夏季环境下混凝土的养护提出了具体的建议.     

聚丙烯透明剂的合成研究及应用

以山梨醇和二(三)甲基苯甲醛为原料,在酸催化下进行醇醛缩合反应,合成了多甲基苄叉山梨醇二缩醛(简称CT),并对影响产品收率的因素和CT对聚丙烯性能的影响进行了考察.CT能显著降低聚丙烯雾度(≤15%),提高光泽度(≥130%).     

聚丙烯装置聚合区设备布置及管廊的配管设计

结合工程特点及工艺流程,阐述了300 kt/a聚丙烯装置的布置原则,管道、管架设计要点和方法,以及需要注意的问题。