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41.
东营凹陷古近系烃源岩超压特征及分布规律 总被引:26,自引:1,他引:25
统计分析1307口探井实测压力系数和83l口探井使用的钻井液密度数据,发现东营凹陷古近系沙三段、沙四段普遍存在异常超压,超压(压力系数1.1-1.5)主要出现在2100-3500m深度,强超压(压力系数大于1.5)主要出现在2800-3500m深度。东营凹陷沙三段、沙四段主力烃源岩超压平面分布具有北高南低、东高西低的总体特点,超压主要分布在洼陷带、断裂构造带和中央背斜带上。烃源岩压力系数等值线北部陡坡带比较密集,南部缓坡带相对稀疏。生油洼陷中心附近异常高压带的分布与生油洼陷基本一致,洼陷深陷区压力系数很大,向周围斜坡和构造高部位呈辐射状逐渐减小至正常,压力分布带与洼陷、边缘斜坡和构造较高部位的欠压实与压实带发育、分布规律的一致性很好。图3表l参9 相似文献
42.
F Javier Álvarez‐Hornos Carmen Gabaldón Vicente Martínez‐Soria Paula Marzal Josep‐Manuel Penya‐roja 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(5):643-653
BACKGROUND: Two peat biofilters were used for the removal of toluene from air for one year. One biofilter was fed with pure toluene and the other received 1:1 (by weight) ethyl acetate:toluene mixture. RESULTS: The biofilters were operated under continuous loading: the toluene inlet load (IL) at which 80% removal occurred was 116 g m?3 h?1 at 57 s gas residence time. Maximum elimination capacity of 360 g m?3 h?1 was obtained at an IL of 745 g m?3 h?1. The elimination of toluene was inhibited by the presence of ethyl acetate. Intermittent loading, with pollutants supplied for 16 h/day, 5 days/week, did not significantly affect the removal efficiency (RE). Biomass was fully activated in 2 h after night closures, but 6 h were required to recover RE after weekend closures. Live cell density remained relatively constant over the operational period, while the dead cell fraction increased. Finally, a 15 day starvation period was applied and operation then re‐started. Performance was restored with similar re‐acclimatization period to that after weekend closures, and a reduction in dead cell fraction was observed. CONCLUSION: This study demonstrates the capacity of the system to handle intermittent loading conditions that are common in industrial practices, including long‐term starvation. Copyright © 2008 Society of Chemical Industry 相似文献
43.
Fadila Ayati Majda Aziza Rachida Maachi Abdeltif Amrane 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(1):27-33
BACKGROUND: Three groups of amino acids were previously characterized based on their ability to be assimilated as carbon source by Penicillium camembertii. To describe the diauxic growth recorded on glucose and amino acids from the second group, such as arginine, an unstructured model was previously developed, based on the sequential consumption of both carbon substrates, glucose, followed after its exhaustion, by arginine. The model was modified to describe also the behaviour recorded during growth on other amino acids. RESULTS: The growth model involved the carbon substrate consumption (Verlhust model) and the biomass on carbon substrate yield. Glucose was therefore considered during P. camembertii growth on nitrogen source amino acids (lysine—first group); and amino acid consumption was considered during growth on carbon source amino acids (glutamate—third group), with glucose being dissimilated only for energy supply. The excess nitrogen from amino acids was released as ammonium; the linking of this production to growth was found to increase with the ability of the amino acid to be assimilated as carbon source by P. camembertii. CONCLUSION: The various metabolic behaviours recorded during P. camembertii growth on amino acids, in the presence of a primary carbon source such as glucose, were proved to be satisfactorily described by the model, showing the robustness of the model. Copyright © 2007 Society of Chemical Industry 相似文献
44.
茨21-133井CO2吞吐技术初步试验 总被引:1,自引:0,他引:1
茨榆坨油田茨13块原油属于普通稠油,1993年开始蒸汽吞吐采油,从第二轮开始效果明显变差,注汽返排率低,有效周期短,产量下降快,套管变形井增多。针对这些问题,在该区块茨21—133井进行CO2吞吐采油工艺现场试验,获得成功,增油效果明显。 相似文献
45.
Alignment of single wall carbon nanotubes (SWNT) in liquid crystalline (LC) polymer matrix imparting orientation to the nanotubes along the nematic director was studied by atomic force microscopy, measurements of electrical conductivity and Raman spectroscopy of the composite in the directions parallel and perpendicular to the nematic director. The composites were prepared through dispersion of SWNT with LC monomer in a common solvent, their alignment in nematic monomer and consequent UV polymerization of the monomer. The anisotropy of electrical and optical properties of the system depends strongly on the concentration of the nanotubes in the range of 1-10% SWNT being especially strong for smaller concentrations and negligible at higher loads. A simple semi-quantitative model is suggested to account for the orientational behavior of nanotubes in nematic matrices. It successfully describes the observed anisotropy of physical properties at microscale (up to 200 μm) in terms of anchoring of the polymer chains to the nanotubes surface and adjustment of the nanotubes orientation to the nematic direction due to such coupling. The increasing disorientation of the nematic domains at higher nanotubes loads is explained as a development of larger number of LC defects induced by the nanotubes in the nematic matrix due to their intrinsic nature of aggregation. The anisotropy of physical properties at macro scale (several millimeters) is much smaller and less dependable on SWNT concentration because differently oriented LC domains effectively wash out the anisotropy. 相似文献
46.
47.
48.
Methane/natural gas storage and delivered capacity for activated carbons in dry and wet conditions 总被引:1,自引:0,他引:1
Methane/natural gas storage and delivered capacity for three different activated carbons in dry and wet conditions were measured. In all tests the temperature of the bed was maintained constant at 277.15 K and pressure was increased up to 10 MPa. Natural gas storage capacity was less than methane storage capacity in dry conditions for all the three activated carbons tested, while the gas delivery was almost the same. One of activated carbon tested (NC120) showed the possibility of hydrate forming for pressures higher than 4 MPa but the amount of gas stored still was less than the amount stored in dry conditions over the whole range of pressure. The analysis of the gas delivered at each pressure steps shows that considerable amount of heavy components do not come out from the bed even at very low pressures in both dry and wet condition tests. Repeatability of the sorption/desorption processes - vital for possible commercial/industrial use - has been examined over various cycles. 相似文献
49.
A simple method has been devised for immobilization of acetylcholinesterase (AChE) covalent bonding to a multiwall carbon
nanotube (MWNT)-cross-linked cellulose acetate composite on a screen-printed carbon electrode (SPCE) and a sensitive and disposable
amperometric sensor for rapid determination of carbaryl pesticide is proposed. The immobilized enzyme was preserved on this
film because of the excellent biocompatibility and non-toxicity of cellulose acetate. Based on the inherent conductive properties
of the MWNT, the immobilized AChE had greater affinity for ATCl and excellent catalytic effect in the hydrolysis of ATCl.
MWNT improved the interface enzymatic hydrolysis reaction and increased the amperometric response of the sensor. Under optimum
conditions, the inhibition of carbaryl on AChE increased linearly with the increasing concentration of carbaryl in two ranges,
from 0.01 to 0.5 μg mL−1 and from 2 to 20 μg mL−1, with the correlation coefficients of 0.9985 and 0.9977, respectively. The detection limit was 0.004 μg mL−1 taken as the concentration equivalent to 10% decrease in signal. The sensor showed acceptable stability, accuracy and could
be fabricated in batches, thus it is economic and portable. This type of disposable enzyme-based amperometric sensor has extensive
application potential in environmental monitoring of pesticides. 相似文献
50.
Influence of pencil lead hardness on voltammetric response of graphite reinforcement carbon electrodes 总被引:1,自引:0,他引:1
Paulo Henrique Campos Prado Tavares Paulo Jorge Sanches Barbeira 《Journal of Applied Electrochemistry》2008,38(6):827-832
This work studied the voltammetric response of graphite reinforcement electrodes made of different pencil lead hardness. The
studies showed that harder graphite leads, regardless of their manufacturer, are more appropriate as electrode material for
voltammetric purposes due to their higher peak currents, increasing sensitivity and reproducibility, with ΔEp closer to the theoretical value for a reversible system. 相似文献