Toward multi-functional polymer composites through selectively distributing functional fillers

The distribution of functional filler is known to have significant influence on various functionalities, yet, not been systematically investigated. Herein, we use a blends system based on PA12/PA6 containing SiC and low-temperature expandable graphite (LTEG) to study it. The effect of filler distribution in such blends on various functionalities including: thermal conductivity, electrical conductivity, and electromagnetic interference (EMI) shielding ability, has been systematically studied. Further study on altering filler distribution with polished PA6-LTEG and PA6-LTEG in different sizes reveals that, polished particle surface results in reduced electrical and thermal conductivity; and smaller particle size leads to enhanced electrical conductivity, thermal conductivity and EMI shielding ability. Finally, theoretical approach on thermal conductivity demonstrates that the system illustrates very effective contribution in thermal conductivity from large PA6-LTEG “filler” comparing to much smaller traditional fillers. Such study could provide a guideline for the processing of functional polymer composites.     

High shear dispersion technology prior to twin roll casting for high performance magnesium/SiCp metal matrix composite strip fabrication

SiC particulate (SiC_p) reinforced AZ31 magnesium alloy composite strips were produced by a novel process. In the process, a high shear technique was utilised to disperse the reinforcing particles uniformly into the matrix alloy, and AZ31/5 vol%SiC_p slurry was solidified into thin strip by a horizontal twin roll caster. The experimental results showed that the AZ31/5 vol%SiC_p strip obtained with high shear treatment exhibited a significantly refined microstructure and uniform distribution of reinforcing SiC particles. High cooling rate in the TRC process was also considered to contribute to the grain refinement of the matrix alloy, together with the possible heterogeneous nucleation effect of the reinforcing particles. The mechanical properties of the high shear treated composites strips showed enhanced modulus, yield strength and ductility by hardness and tensile tests. The experimental results were discussed in terms of the microstructural features and the macroscopic reliability, where necessary, analytical and statistical analyses were conducted.     

Effect of annealing temperature and graphene concentrations on photovoltaic and NIR-detector applications of PbS/rGO nanocomposites

The effect of annealing temperature on photovoltaic and near-infrared (NIR) detector applications of PbS nanoparticles (NPs) and PbS/graphene nanocomposites was investigated. The products were synthesized by a simple co-precipitation method and graphene oxide (GO) sheets were used as graphene source. Several characterization techniques were used to show transfer of the GO into reduced graphene oxide (rGO) during the synthesis process. In addition, the effect of graphene concentrations on morphology, structure, photovoltaic, and detector parameters of the samples were studied. Transmission electron microscope (TEM) images showed that, the PbS NPs were agglomerated, while, the PbS/rGO nanocomposites were dispersed completely after annealing under H₂/Ar gas atmosphere. UV–visible spectrometer showed an absorption peak for all samples in the near infrared red (NIR) region of the electromagnetic spectrum. The results indicated that, photocurrent intensity, responsivity of the samples to an NIR source, and solar-cell efficiency were affected by annealing of samples and graphene concentrations.     

Corrosion behaviour of porous Ni-free Ti-based bulk metallic glass produced by spark plasma sintering in Hanks' solution

Porous bulk metallic glasses (BMGs) are promising biomedical materials to be used for surgical implants. Here we report on successful formation of porous Ni-free Ti-based BMGs with a diameter exceeding 15 mm by spark plasma sintering the mixture of the gas-atomized Ti-based (Ti₄₅Zr₁₀Cu₃₁Pd₁₀Sn₄) glassy alloy powder and solid salt powder, followed by leaching treatment into water to eliminate the salt phase. Corrosion behaviour of the produced porous Ti-based BMGs was investigated in Hanks' solution. The potentiodynamic polarization curves showed that the anodic current density in the porous Ti-based BMGs slowly increased during anodic polarization, suggesting the crevice corrosion.     

Modelling the simulation of impact induced damage onset and evolution in composites

This paper presents two modelling strategies for the simulation of low velocity impact induced damage onset and evolution in composite plates. Both the strategies use a global–local technique to refine the mesh in the impact zone in order to increase the accuracy in predicting the impact phenomena without affecting the computational cost. Cohesive elements are used to simulate the inter-lamina damage behaviour (delaminations) and Hashin’s failure criteria are adopted to predict the intra-lamina failure mechanisms. The two modelling strategies differ in terms of input parameters for the inter-lamina and intra-lamina damage evolution laws and in terms of modelling solutions in the impacted area. Comparisons between numerical and experimental results on composite plates subjected to different impact energies, according to the ASTM D7136 requirements, have been used to assess the peculiarities and the fields of application for the two proposed modelling strategies. Both the strategies have been tested by adopting the finite element code ABAQUS®. The different approaches to set the parameters of cohesive elements’ constitutive laws and Hashin’s criteria and the different choices made in quantifying the dependence of failure criteria on the finite elements’ average size have been taken into account.     

基于Q学习的企业信息化冲突研究

信息化作为当前企业提升竞争能力的重要手段，在实施的过程中会面临多种技术和管理上的冲突。而对这些冲突缺乏足够的认识和有效的解决机制，会直接影响到信息化项目的成败。为此从信息化冲突产生的原因入手，建立信息化冲突的模型，剖析问题的实质，并构建了基于Q学习的冲突解决机制，为企业信息化过程中的冲突化解提供一定的指导。     

Effects of microstructure and C and Si additions on elevated temperature creep and fatigue of gamma TiAl alloys

The creep properties of K5 (Ti-46Al-3Nb-2Cr-0.2W) based alloys were analyzed in wrought processed microstructure forms. The brittle–ductile-transition-temperature (BDTT) depends distinctly on microstructure as well as strain rate, with the minimum value for each microstructure achieved at ∼10⁻⁶/s being about 680 °C and 780 °C, respectively. The greatest creep resistance is achieved in coarse-grained fully lamellar (FL) material and is related to the strong anisotropy of lath structure, large grain size and consequently high BDTT. Additional significant resistance improvement is realized with additions or increases of refractory elements (Nb or W) and decrease in Al content. The most remarkable improvements in primary as well as the minimum creep resistance are realized when small amounts of C or C + Si are added to generate incoherent (to gamma) carbide and silicide particles along γ/γ_T interfaces. The significance of primary creep is assessed for controlling subsequent creep behavior and discussed for its crucial role in satisfying the stringent design creep requirements for advanced rotational components. The accelerated or tertiary creep is used to explain the high temperature (870 °C) high cycle fatigue deformation that exhibits two-stage SN curves with the rapidly softening second stage.     

Imparting strength into nanofiberous yarn by adhesive bonding

Low strength is one of the main disadvantages of nanofibrous structures in some applications such as suture yarns. To overcome this matter, in the present research, a novel method was applied to improve the tensile properties of nanofiber yarns. For this purpose, nanofibers and particles of polyvinyl acetate (PVAc) were added as a hot melt adhesive to nanofiber yarns in order to initiate adhesive bonding between nanofibers by two approaches. In the first one, Nylon 66/ PVAc hybrid nanofiber yarn was produced in opposite charged nozzles set up. In another approach, PVAc particles were electrosprayed through one of the nozzles while nylon 66 nanofibers were producing through another one. Afterward, thermal treatment was carried out for 78 seconds on samples in different temperatures. The results indicate that tensile strength was improved up to 1.97 and 1.7 times in comparison to nylon 66 nanofiberous yarn by adding PVAc nanofibers and particles, respectively. FTIR analysis was also carried out to assess the hybrid sample composition after heat treatment.     

Experimental evidence for enhanced copper release from domestic copper plumbing under hydrodynamic control

We present experimental results to analyze copper release from biotic and abiotic pipe surfaces and its relation to flow parameters, from Reynolds Number (Re) 1027–11,618.For abiotic and biotic surfaces, increasing the flow velocity affected the time scale of the copper release but not necessarily the net amount of total copper incorporated into the bulk flow.For biotic conditions the total copper concentration in the bulk flow was an order of magnitude higher than for abiotic surfaces (3.65 mg/L vs. 0.32 mg/L). Similarly, higher flow velocities enhance the presence of larger size copper nanoparticles in the bulk flow.     

Electrochemical corrosion performance of Cr and Al alloy steels using a J55 carbon steel as base alloy

Cr- and Al-modified alloy steels using J55 carbon steel as base alloy were produced by remelting in a vacuum. Their corrosion resistance was estimated by open circuit potential, electrochemical polarisation measurements and immersion tests in a 3.5 wt.% NaCl solution. The modified alloy steels exhibit higher corrosion resistance with a more positive open circuit potential, lower corrosion current density and higher impedance than J55 steel. The immersion tests showed that the new alloy steels have lower corrosion rates and smaller pitting depth than J55 steel and a low-Cr steel.