搪玻璃爆瓷的机理研究

对搪玻璃爆瓷的机理进行分析,验证了实验结果,提出解决搪玻璃爆瓷的工艺措施,对产品的工艺条件进行了探讨。     

ON STRUCTURES,PROPERTIES AND CHEMICAL BOND OF Te-Se-I GLASS AND OF ADDING As,Ge ELEMENTS ONE

Te-Se glass and adding As,Ge elements to itare studied with Selt-Consistent-Field Discrete Variatioal X_α(SEF-DV-X_α),one of the molecule orbital calculating meth-ods in quantum chemistry.The chemical bonding is used todiscuss the relations between structures and properties with thevarations of compositions of the glasses.The calculated re-sults show that the strength of covalent and ionic bonds areboth in the order of Ge-Se>As>Se>Te-Se,which is consis-tent with the experimental result of the glass-transition tem-perature(T_g) of the corresponding glasses.The Te-I bond inwhich Ⅰ atom is one-coordinate is sstronger than that in whichⅠ atom is two-coordinate,As-Ⅰ and As-As bonds are bothstronger than the two types of Te-Ⅰ bonds.The waek Te-Ⅰbonds have been replaced by the stronger As-Ⅰ and As-Asbonds,which is just the reason why As addition in TeX glass-es can obviously improve the thermal and chemical properties.     

STRUCTURES,PROPERTIES AND QUANTUM CHEMISTRY STUDIES OF As-S-X(X=Cl,Br,I)AND As-Y-Br(Y=S,Se,Te)GLASSES

As-S-X(X=Cl,Br,I)and As-Y-Br(Y=S,Se,Te)glasses are studied with Self-Consistent-Field Dis-crete Variational X_α(SCF-DV-X_α),one of the molecule orbital.calculating methods in quantum chemistry.The chemicalbonding is studied to discuss the relations between structuresand properties with the variations of compositions of theglasses.The calculated results show that the strength of cova-lent and ionic bonds are both in the order of As-S-Cl>As-S-Br>As-S-I as well as As-S-Br>As-Se-Br>As-Te-Br,it isconsistent with the experimental result of the glass-transitiontemperature (Tg) of the corresponding glasses.The differ-ences of chemical bond strength and Tg among As-S-X(X=Cl,Br,I)glasses are larger are larger than those among As-Y-Br(Y=S,Se,Te)glasses and the largest difference ofchemical bond strength is that of ionic bond of As-X amongAs-S-X(X=Cl,Br,I)glasses,so the variations of X(X=Cl,Br,I),the end atoms on the chains in the glasses,play themore important role to affect the struture and property of theglasse     

磷渣活性的试验研究与分析

本文在试验研究的基础上,分析了磷渣的玻璃含量与结构、激发方法和养护条件等对磷渣活性发挥的显著影响、研究结果对工程应用有一定参考价值。     

仿瓷玻璃酒瓶的研究与生产

与陶瓷酒瓶相比，玻璃酒瓶有许多优点，本文介绍了六种仿瓷玻璃酒瓶的化学组成和生产要点。     

中空玻璃微珠填充环氧树脂复合材料

讨论了用发电厂固体废料中的中空玻璃微珠填充Ｅ－４４环氧树脂制备轻质复合材料，实验详尽地考察了微珠填料，ＫＨ－５００偶联剂，固化剂（三乙基四胺，Ｔ－３１，三乙醇及液体四氢苯酐）及低聚酰胺等增韧剂等对所得的复合材料为力学性能的影响，并通过扫描电镜（ＳＥＭ）观察了材料的形态，其结果表明，偶联剂和增韧剂对复合材料的力学性能影响较大，中空玻璃微珠填充环氧树脂赋予基轻质，高强，价廉等特性。     

无碱玻璃中微量铁的化学状态分析

通过化学分析和先谱分析发现在无碱玻璃中有部分铁为网络形成体，其余的则为网络修饰体。所有的Ｆｅ３＋都以四配位形式存在；而Ｆｅ２＋只有少部分以四配位体存在，大部分的Ｆｅ２＋则呈六配位状态。     

EFFECT OF SILANE ON THE SURFACE OF SEALING GLASS

This paper,through XPS and IR analyseson the surface of sealing glass,identifies that the surfacetreatment of sealing glass by silane is a chemical process.Onthe basis of the analyses,the authors suggest an ideal chemicalbonding status between silane and glass surface.     

电子碰撞脱附对蒸发式镀膜玻璃附着强度的影响

本文论述了电子碰撞脱附对提高蒸发式镀膜玻璃附着强度的影响，提出一种对现有生产工艺的改进措施。     

玻璃熔窑火焰空间二维数学模型

本文在一定简化假设下,把玻璃池窑火焰空间划分成若干等温区和等温表面单元,由此建立了横焰池窑火焰空间的二维数学模型。文中用有限单元法和高斯积分计算各单元间的直接交换面积,通过逆矩阵求解总交换面积,最后用迭代法求解温度分布。文中模拟计算了火焰温度分布、对流系数、窑体表面散热等因素对池窑温度分布的影响。