乙醇电氧化的研究进展

简要地叙述了国内外乙醇电催化氧化的研究进展，着重介绍不同电极材料对乙醇电氧化的影响及目前所提山的机理，并对其可能的研究方向提出了建议。     

Proton and hydrogen formation by cyclohexyl benzene during overcharge of Li-ion batteries

This study provides experimental evidence for proton and hydrogen formation caused by the anodic electropolymerization of cyclohexyl benzene (CHB), which is a popular electrolyte additive for overcharge protection of lithium-ion batteries (LIBs). It is found that considerable H₂ evolution is observed in overcharged LiCoO₂/graphite cells, especially when CHB is included as an electrolyte additive. In order to confirm the proton generation during the CHB oxidation, Pt/Pt-rotating ring disc electrode (RRDE) measurements are performed in 1 M Li(C₂F₅SO₂)₂N ethylene carbonate/ethyl methyl carbonate (1/2, v/v) solutions with and without CHB. The cathodic ring current is intimately correlated to the anodic disc current, and the cathodic reaction at the ring is determined to be the reduction of the proton. The proton generation efficiency during the CHB oxidation is as high as 90%. Proton liberation is also observed during the anodic decomposition of the electrolyte solvents, although it occurs in a much less stoichiometric way compared with that during the CHB oxidation.     

APDT-00三极放电管全自动打印机的研制

介绍了新近研制的APTD - 0 0三极放电管全自动打印机的结构特点及整机设计的关键技术 ,阐述了自动上料机构、打印机构和控制电路的设计     

Calculation of fatigue limits of case-hardened specimens with consideration of mean stresses and residual stresses

 The strength of case-hardened parts under cyclic loading can be determined in an experimental manner, but this can produce a large amount of costs due to the expenditure of material and testing time. Therefore, a calculation method is developed, that strongly reduces the number of experiments. The presented model is based on Weibull's weakest-link concept and allows to compute the survival probability of a case-hardened part which is loaded close to the fatigue limit. The essential quantities in this model are the distribution of Vicker's hardness of the material, the exponents of the Weibull distribution of the volume and the surface, the residual stress state, the surface roughness and the surface oxidation depth. By integrating the survival probabilities of the surface and the volume, the survival probability of the entire specimen or part can be calculated, which allows to compute the fatigue limit. The necessary parameters have to be determined from reference specimens. The model is successfully examined by comparing experimental and calculated results of smooth and notched case-hardened specimens under alternating torsion, rotating bending, repeated tension and tension-compression. Received 20 August 2001 / Accepted 11 November 2001     

全夯式新型夯扩桩的工程应用及分析

介绍了全夯式新型夯扩桩的原理及实际应用情况，并对承载力进行简单的分析。     

提高特高含水期油藏采收率的方法及应用效果

针对胜索油田二区9-10单元的层间非均质和平面非均质性，运用水动力学方法，采用周期注水及增压注水改善单元的水驱油效果。经过6a的实施，单元的开发形势趋好，单元采收率提高9.62%，增加可采储量341.5kt，对同类型非均质性油藏改善水驱油效果，提高最终采收率具有借鉴意义。     

Non-destructive evaluation of residual stresses in thin films via x-ray diffraction topography methods

Quantitative x-ray diffraction topography techniques have been used to measure the residual strain magnitude and uniformity of deposition for Mo and W sputtered films on Si(100) substrates. High sensitivity rocking curve measurements were able to determine differential strains for films as thin as 2.5 nm; while Bragg angle contour mapping had similar sensitivity and was also able to assess coating uniformity and stress distribution over areas covering a whole wafer. Measurements of strain versus film thickness over a range of 2.5 nm to 80 nm showed that a critical thickness exists for maximum residual strain. Growth beyond this range produces stress relaxation. This non-destructive type of analysis could be employed on a wide range of film-substrate combinations.     

A mesomodel for the numerical simulation of the multiphasic behavior of materials under anisothermal loading (application to two low-carbon steels)

The determination of residual stresses induced by welding or heat treatment operations requires the use of complex models taking into account thermal, metallurgical and mechanical phenomena. In this paper, we propose a mechanical model in which each phase can follow its own constitutive law. This model also takes into account phase transformation plasticity, which is treated independently of the behavior of each phase. This model has been implemented into the French FEM code Castem 2000. The interest of the proposed method is that it allows one to mix any type of nonlinear behavior using Taylor homogenization hypothesis. There is no need to develop a theory to get the equations of the homogenized material law. Two numerical examples demonstrate the efficiency and the flexibility of this approach. The results obtained are compared to experimental values for a typical welding situation and a high-temperature response. This comparison seems to indicate that viscous effects in the materials have a significative influence on the residual stresses produced by welding.     

Ti基MnO_x型DSA析氧电极材料的性能

本文报导了新型 Ti/SnO_2+MnO_x+RuO_2/MnO_x(DSA)电极材料的各种性能,其中包括电极的导电性、表面粗糙度、电化学活性表面积、析氧阳极特性等,并用 X 射线衍射法进行了物相分析、用 SEM观察了表面形貌。确认该电极性能良好,加之成本较低,可作为酸性介质中的析氧电极材料。     

Influence of heat transfer on anodic oxidation of aluminium

The influence of convective heat transfer on constant current density anodizing of aluminium in sulfuric acid has been examined in a wall-jet electrode reactor. The uniformity of the anodic film thickness is related to the local electrode temperature distribution, which is dependent on the convection. The higher the local temperature, the greater the local oxide thickness. An increased local temperature enhances local field assisted oxide dissolution at the pore bases, and consequently acts to increase the local current density. At relatively high current densities, local features develop on the electrode surface, accompanied by high initial, local temperature rises. The relevance of such local features, limiting useful oxide growth, is considered further.