Compact difference method for solving the fractional reaction–subdiffusion equation with Neumann boundary value condition

In this paper, we derive a high-order compact finite difference scheme for solving the reaction–subdiffusion equation with Neumann boundary value condition. The L1 method is used to approximate the temporal Caputo derivative, and the compact difference operator is applied for spatial discretization. We prove that the compact finite difference method is unconditionally stable and convergent with order O(τ^2?α+h⁴) in L₂ norm, where τ, α, and h are the temporal step size, the order of time fractional derivative and the spatial step size, respectively. Finally, some numerical experiments are carried out to show the effectiveness of the proposed difference scheme.     

一种反应釜温度模糊控制器的设计与实现

反应釜是化工生产过程中的关键设备,准确控制反应釜内温度是提高化工产品的质量和产量,实现优质、稳定和节能生产的有效途径.本文基于模糊控制理论,设计一种反应釜内温度模糊控制器,研究模糊控制器输入和输出变量的确定、精确量的模糊化、模糊控制规则的设计、输出量的模糊判决和基于规则修改的模糊控制方法.以STM32F103RB单片机为核心搭建硬件平台,采用单线数字温度传感器DSl8B20实现多点温度采集,并实现了基于单片机的反应釜温度智能控制硬件系统.     

考虑桩顶水平反力的水平受荷单桩弹塑性解析解

基于线性地基反力法和土体的弹塑性本构关系,对桩顶水平反力系数不为零时的水平受荷桩进行了研究,给出了桩顶土屈服临界荷载（水平力、弯矩）的耦合关系式。研究结果表明,当荷载大于临界荷载时,桩顶土发生塑性屈服,其塑性屈服深度随荷载的增加而增加,但其塑性区扩展速率随桩顶荷载的增加而逐渐减小。给出了弹性区与塑性区桩内力耦合的矩阵方程及其迭代求解格式;利用曲面拟合软件给出了塑性区换算深的计算公式。通过工程算例验证,证明该方法可靠快捷,便于手算,值得推广。      

空间机械臂全局反作用优化及其地面试验研究

针对空间机械臂在运动过程中对其基座产生力／力矩反作用这一问题进行了分析,并提出一种关节轨迹参数化的全局反作用优化方法,用于减小机械臂的反作用力／力矩．基于气浮轴承方法,建立了3自由度空间机械臂反作用优化地面实验系统．最后,采用3自由度机械臂验证了该方法的有效性．     

Computational simulation of Belousov–Zhabotinskii oscillating chemical reaction

The suitability of computational simulation of the Belousov–Zhabotinskii oscillating chemical reaction by differential kinetic methodology for resolving nonlinear multi-component system is demonstrated in this work. According to the Field–KÖrÖs–Noyes mechanism and the Oregonator model, the change of the concentrations of HBrO₂, bromide ion and cerium ion are simulated. The results of computational simulation are consistent with experimental results very well. At the same time, the effect of variables and parameters, especially the rate constant on the oscillation curve, are investigated deeply. A simple method of estimating rate constants is obtained through simulation the concentrations of key components of the system, and then comparison the simulation results with the experimental ones. The reasonable rate constant is also proposed.     

计算机曲线拟合求解析氢反应的动力学参数

应用电化学稳态极化方法,研究1M NaOH电解液中镍硫合金电极表面析氢反应电催化活性与沉积层中含硫量之间的关系.根据析氢反应机理,用理论电化学极化方程拟合实验稳态极化曲线,得到不同含硫量的镍硫合金电极表面氢原子吸附和脱附反应的速率常数、反应对称系数等动力学参数.     

Energy conversion at liquid/liquid interfaces: artificial photosynthetic systems

This chapter focuses on multielectron reactions in organized assemblies of molecules at the liquid/liquid interface. We describe the thermodynamic and kinetic parameters of such reactions, including the structure of the reaction centers, charge movement along the electron transfer pathways, and the role of electric double layers in artificial photosynthesis. Some examples of artificial photosynthesis at the oil/water interface are considered, including water photooxidation to the molecular oxygen, oxygen photoreduction, photosynthesis of amphiphilic compounds and proton evolution by photochemical processes.     

Amine Coordinated Electron-Rich Palladium Nanoparticles for Electrochemical Hydrogenation of Benzaldehyde

Electrocatalytic hydrogenation (ECH) is a burgeoning strategy for the sustainable utilization of hydrogen. However, how to effectively suppress the competitive hydrogen evolution reaction (HER) is a big challenge to ECH catalysis. In this study, amine (NH₂ R)-coordinated Pd nanoparticles loaded on carbon felt (Pd@CF) as a catalyst is successfully synthesized by a one-step solvothermal reduction method using oleylamine as the reducing agent. An exceptional ECH reactivity on benzaldehyde is achieved on the optimal Pd@CF catalyst in terms of a high conversion (89.7%) and selectivity toward benzyl alcohol (89.8%) at −0.4 V in 60 min. Notably, the Faradaic efficiency for producing benzyl alcohol is up to 90.2%, much higher than that catalyzed by Pd@CF-without N-group (41.1%) and thecommercial Pd/C (20.9%). The excellent ECH performance of Pd@CF can be attributed to the enriched electrons on Pd surface resulted from the introduction of NH₂ R groups, which strengthens both the adsorption of benzaldehyde and the adsorbed hydrogen (H_ads) on Pd, preventing the combination of H_ads to form H₂, that is, inhibiting the HER. This study gives a new insight into design principles of highly efficient electrocatalysts for the hydrogenation of unsaturated aldehydes molecules.     

Rational Design and Synthesis of Extremely Efficient Macroporous CoSe2–CNT Composite Microspheres for Hydrogen Evolution Reaction

Uniquely structured CoSe₂–carbon nanotube (CNT) composite microspheres with optimized morphology for the hydrogen‐evolution reaction (HER) are prepared by spray pyrolysis and subsequent selenization. The ultrafine CoSe₂ nanocrystals uniformly decorate the entire macroporous CNT backbone in CoSe₂–CNT composite microspheres. The macroporous CNT backbone strongly improves the electrocatalytic activity of CoSe₂ by improving the electrical conductivity and minimizing the growth of CoSe₂ nanocrystals during the synthesis process. In addition, the macroporous structure resulting from the CNT backbone improves the electrocatalytic activity of the CoSe₂–CNT microspheres by increasing the removal rate of generated H₂ and minimizing the polarization of the electrode during HER. The CoSe₂–CNT composite microspheres demonstrate excellent catalytic activity for HER in an acidic medium (10 mA cm^?2 at an overpotential of ≈174 mV). The bare CoSe₂ powders exhibit moderate HER activity, with an overpotential of 226 mV at 10 mA cm^?2. The Tafel slopes for the CoSe₂–CNT composite and bare CoSe₂ powders are 37.8 and 58.9 mV dec^?1, respectively. The CoSe₂–CNT composite microspheres have a slightly larger Tafel slope than that of commercial carbon‐supported platinum nanoparticles, which is 30.2 mV dec^–1.