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141.
Structural transformation and ionic transport properties are investigated on wet-chemically synthesized La1−xMnO3 (x=0.0–0.18) compositions. Powders annealed in oxygen/air at 1000–1080 K exhibit cubic symmetry and transform to rhombohedral on annealing at 1173–1573 K in air/oxygen. Annealing above 1773 K in air or in argon/helium at 1473 K stabilized distorted rhombohedral or orthorhombic symmetry. Structural transformations are confirmed from XRD and TEM studies. The total conductivity of sintered disks, measured by four-probe technique, ranges from 5 S cm−1 at 298 K to 105 S cm−1 at 1273 K. The ionic conductivity measured by blocking electrode technique ranges from 1.0×10−6 S cm−1 at 700 K to 2.0×10−3 S cm−1 at 1273 K. The ionic transference number of these compositions ranges from 3.0×10−5 to 5.0×10−5 at 1273 K. The activation energy deduced from experimental data for ionic conduction and ionic migration is 1.03–1.10 and 0.80–1.00 eV, respectively. The activation energy of formation, association and migration of vacancies ranges from 1.07 to 1.44 eV.  相似文献   
142.
Thermochemical analyses of interfacial reactions in titanium, zirconium, and hafnium diboride reinforced oxidematrix composites have been carried out to evaluate the chemical compatibility. The chemical reactivity of these diborides with oxygen and the high volatility of B2O3( l ) at reduced oxygen pressures are concerns during processing and operating conditions. The thermochemical stability and the vaporization behavior of B2O3( l ) are discussed in terms of partial pressures of dominant gaseous species of the boron-oxygen system at 1700 and 2300 K. The TiB2/ZrO2 and TiB2/HfO2 systems are thermodynamically stable in a limited oxygen pressure range. The TiB2/Al2O3 system is stable, but the reactions in this system may apparently be accompanied by formation of gaseous products (B2O3, AlO, Al2O, and lower boron oxides) in the presence of elemental oxygen. These thermochemical considerations are very useful in evaluating the effectiveness of oxides as diffusion barrier coatings on diboride reinforcements.  相似文献   
143.
Diamond growth with rates up to 100 to 140 μm/hr was achieved using an oxygen-acetylene combustion spraying technique in an atmospheric environment. Investigations on the processing indicated that the gas flow ratio, substrate position, substrate temperature, temperature distribution, and substrate pretreatment were the most important factors affecting the growth of diamond crystals. Evaluation by means of X-ray diffraction, Raman spectroscopy, scanning electron microscopy, and electron probe microanalysis showed that the synthesized diamond was nearly perfect in morphology, structure, and purity.  相似文献   
144.
Silicoaluminophosphate (SAPO-5) molecular sieves have been synthesised from reaction mixtures having a molar composition of: 0.7–1.0 Al2O3:0.7–1.0 P2O5:0.01–2.0 SiO2:xR:40 H2O (where R = (C2H3)3N or (C2H3)4NOH and x = 1.5–2.5 for (C2H5)5N and 0.5 for (C2H5)4NOH, at 473 K using various sources of alumina and silica. The effects of (i) varying the crystallinity of the alumina source (boehmite) and (ii) the use of different silica sources such as freshly prepared silica either from sodium silicate or paddy husk extract, silica gel from commercial water-glass, and tetraethyl orthosilicate have been studied. The crystallinity of boehmite has been found to have a strong effect on its reactivity towards the formation of SAPO-5. The activity of boehmite for SAPO-5 formation increased with a decrease in its crystallinity (or with increase in its moisture content). Any silica source devoid of sodium ions could be employed for the synthesis of SAPO-5. The process of crystallisation started as early as within 1.5 h of reaction and incorporation of silicon into the AlPO4 framework has been noted at this stage. Formation of some tridymite phase as impurity has been observed under conditions such as (i) SiO2 concentration > 1.7 mole and (ii) x > 2.0 when R = (C2H5)3N.  相似文献   
145.
DCPTA是近年来新发现的一种植物生长调节剂。对农作物具有明显的增产增质效果。文中就其新的合成方法进行了研究。  相似文献   
146.
部件试验模态综合的简便方法   总被引:4,自引:1,他引:3  
本文将一种基于完备模态基的模态综合技术应用于子结构的试验模态综合,获得成功。这种半试验半理论的模态综合方法是一种较为简便的、要求试验工作量较小的试验模态综合法,因为它只要求测量子结构的振动模态和频率即可。数值仿真结果表明,这种简便的试验模态综合法是行之有效的。  相似文献   
147.
用自蔓燃高温合成(SHS)技术及电弧熔融法制备的(Nb,Ti)C固溶体作基体,制备(Nb,Ti)C-35Ni金属陶瓷。结果表明用电弧熔融法制备的(Nb,Ti)C为基的试样具较优的室温力学性能(σ=1630MPa,KIC=18.0MPa),其陶瓷颗粒均匀分行粘结相之中并是包裹结构;而用SHS法制备的(Nb,Ti)C为基的试样其力学性能相对较差,其陶瓷颗粒无包裹结构.  相似文献   
148.
反应器网络综合优化方法的研究进展   总被引:3,自引:0,他引:3  
陈启石  冯霄 《现代化工》2002,22(5):14-18
反应器网络综合优化方法在选择反应器类型和反应工艺条件时,比传统的方法表现出了很大的优势。综述了各类反应器网络综合优化方法的基本原理和研究进展,并分析了它们的优缺点。这些方法有基于过程特征的方法,包括可得区法和导数分析法;超结构优化法;目标类方法,包括目标法、构造目标法和构造MINLP法;以及经验推断法和分布参数法等。最后分析了这方面研究的发展趋势。  相似文献   
149.
有机介质中合成二硫化钛   总被引:1,自引:0,他引:1  
本文研究了硫化氢与四氯化钛在某些有机介质中的反应,并提出了一个合成二硫化钛的新方法。该法是将干燥的硫化氢通入沸腾的四氯化铁的α-氯代萘溶液中,使硫化氢和四氯化钛发生复分解反应而生成二硫化钛。方法简便易行。X-射线物相鉴定及化学分析结果表明,产物为单一物相的、符合化学计量的二硫化钛。  相似文献   
150.
Asbestos fibres, of the chrysotile variety, and chopped carbon fibres were pretreated by an in-situ polycondensation technique eventually resulting in a polyamide coating on the fibre surface. Ionomer based composites containing either carbon or asbestos fibres in random in plane fibre orientation were prepared, and the influence of this coating process on the tensile properties was investigated. It was found that for the asbestos-filled composites the presence of the nylon 6,6 interlayer improves the tensile performance, especially at moderate polyamide depositions. This is not the case with the pretreated carbon-filled composites for which carbon fibres with higher polyamide contents are preferred. Combinations of the treated asbestos fibres with carbon and/or aramid fibres may be used to reduce the asbestos content in asbestos-only based engineering plastics.  相似文献   
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