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排序方式: 共有7098条查询结果,搜索用时 38 毫秒
61.
通过失重法和极化曲线、线性极化两种电化学方法,研究了十二烷基二甲基(2-羟基)乙基氯化铵(122)、十四烷基二甲基(2-羟基)乙基氯化铵(142)和十六烷基二甲基(2-羟基)乙基氯化铵(162)对20#碳钢在5%盐酸中的缓蚀作用。并与新洁尔灭(十二烷基二甲基苄基溴化铵)进行了比较。结果表明,它们在酸性介质中具有很好的缓蚀作用。 相似文献
62.
The present investigation pertains to modeling of seawater desalination system. A simulation model was developed and verified for a small-scale reverse osmosis system. The proposed model combines material balances on the feed tank, membrane module andproduct tank with membrane mass transfer models. Finally a comprehensive simulation model has been developed incorporating the effect of mass transfer inhibition The model is non-linear differential equation representing the feed concentration as a function of operating time and space. The solution of the simultaneous differential equations was obtained using the fourth order Runge-Kutta method, due to self starting and stability. The model was verified using the experimental data from the literature [17,24]. Parameter sensitivity was carried out to select the proper step size. The simulation was run for over 1000 11 enabling a prediction of operational performance at high overall system recoveries. 相似文献
63.
64.
NiO-Ce0.8Sm0.2O1.9 (SDC) composites were synthesized using gel-casting technique. The electrochemical performance of the gel-cast (GC) Ni-SDC cermet as anode was investigated contrast with that fabricated from traditional mechanical mixing (MM) technique using fuel cells with about 35 μm-thick SDC electrolyte and Sm0.5Sr0.5CoO3-SDC cathode. Maximum power density of the cell with GC anode achieved 491 mW cm−2 at 600 °C, over 100 mW cm−2 larger than that with MM anode, inferring high catalytic activity of the GC anode. Impedance measurements on the fuel cell at open circuit showed that the anodic interfacial polarization resistance of the GC anode was 0.1 Ω cm2 lower than that of the MM anode. Long-term stability of the cell with GC anode in hydrogen was also performed, which showed that it can stabilize at least 7 days. 相似文献
65.
A.J. Dickinson L.P.L. Carrette J.A. Collins K.A. Friedrich U. Stimming 《Journal of Applied Electrochemistry》2004,34(10):975-980
This paper describes the effects of varying the Pt to Ru ratio in carbon-supported catalysts for methanol oxidation as a function of temperature. Previously these effects were studied in isolation, but now it is shown that the composition of a given catalyst as a function of temperature is extremely important for its activity towards methanol oxidation. Platinum rich 3:2 atomic ratio catalysts perform better than a 1:1 catalyst at 25 °C, where only Pt is believed to be active towards methanol dehydrogenation, since this process is a highly thermally activated process on Ru sites. This result is reversed at 65 °C, where the 1:1 catalyst displays much higher currents across the entire range of polarization. This may result from methanol dehydrogenation occurring on both Ru and Pt sites at higher temperatures. At an intermediate temperature, 45 °C, the 3:2 catalyst is seen to perform better at lower current values, while the 1:1 catalyst is superior at higher current densities, with the crossover occurring at 62 A g–1. As a consequence, when designing fuel cell catalysts, the composition of the catalyst employed should be tailored with respect to the exact operating conditions, in order to promote optimum fuel cell performance. 相似文献
66.
Rinaldo Gregorio Luiz Francisco Malmonge Guilherme Fontes Leal Ferreira Wilson Nunes Dos Santos Luiz Henrique Capparelli Mattoso 《应用聚合物科学杂志》2003,87(5):752-758
The real (ε′) and imaginary (ε″) components of the complex permittivity of blends of PVDF [poly(vinylidene fluoride)] with POMA [poly(o‐methoxyaniline)] doped with toluenosulfonic acid (TSA) containing 1, 2.5, and 5 wt % POMA–TSA were determined in the frequency interval between 102 and 3 × 106 Hz and in the temperature range from ?120 up to 120°C. It was observed that the values of ε′ and ε″ had a greater increase with the POMA–TSA content and with a temperature in the region of frequencies below 10 kHz. This effect decreased with frequency and it was attributed to interfacial polarization. This polarization was caused by the blend heterogeneity, formed by conductive POMA–TSA agglomerates dispersed in an insulating matrix of PVDF. The equation of Maxwell–Garnett, modified by Cohen, was used to evaluate the permittivity and conductivity behavior of POMA–TSA in the blends. A strong decrease was observed in POMA–TSA conductivity in the blend, which was bigger the lower the POMA–TSA content in the blend. This decrease could have been caused either by the POMA dedoping during the blend preparation process or by its dispersion into the insulating matrix. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 752–758, 2003 相似文献
67.
A. Sivashanmugam T. Prem kumar N. G. Renganathan S. Gopukumar 《Journal of Applied Electrochemistry》2004,34(11):1135-1139
In this work, we describe an evaluation of an Mg–Li alloy (Li: 13 wt %) for possible use in magnesium primary reserve batteries. Higher OCP for the Mg–Li alloy have been observed in 2 M MgCl2 and MgBr2 electrolyte. The corrosion rate of the Mg–Li alloy is found to be in the order: MgCl2 < Mg(COOCH3)2 < MgSO4 < MgBr2 < Mg(ClO4)2. Mg–Li alloys exhibit higher (81%) anodic efficiencies even when the current density is increased to 8.6 mA cm –2. It has been observed that Mg–Li/MgCl2/CuO cells offer higher operating voltage and capacity than those with the conventionally used Mg–Al alloy. 相似文献
68.
In recent years, polymer amines have been studied as an efficient corrosion inhibitor for iron in acid media. In this article, the performance of water soluble polyaniline as corrosion inhibitor for iron in 0.5M H2SO4 has been evaluated by potentiodynamic polarization, linear polarization, and electrochemical impedance spectroscopy and compared with the performance of the aniline monomer. It has been found that polyaniline is an efficient inhibitor, since the maximum efficiency of 84% has been observed at a concentration of 100 ppm, whereas the monomer has accelerated the corrosion. FTIR studies have shown that the polyaniline is strongly adsorbed on the iron surface and inhibits the corrosion effectively. However, aniline has been found to improve the passivation tendency of iron at higher concentrations. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2144–2153, 2006 相似文献
69.
70.
针对已有的3D实体真实性认证方法中实体的标识不与实体自身绑定且难以验证的问题,提出了一种面向3D实体的签名算法。给出了3D实体签名算法的设计思想、签名产生算法以及签名验证算法。在粗配准和精匹配阶段分别通过自旋图(Spin Image)和ICP(Iterative Closest Point)算法对签名表面和待测表面进行匹配,从而提高了验证的准确率。对所设计的签名算法进行了实验仿真,所获得的迭代误差和匹配率表明该算法可以区分原始和伪造的签名表面,进而证明了算法的有效性。 相似文献