Alternating,all-trans polyenynes: Model compounds for poly(diacetylene)s with defined conjugation length

The syntheses of polyenynes as model compounds for poly(diacetylene)s (PDAs) are described. Variation of properties (UV–VIS, Raman, NMR and bond geometries) as a function of the chain length was investigated. After extrapolation to infinite chain length these data were compared to those for PDAs. From UV–VIS spectra a value of λ = 551 nm (2.25 eV) was calculated corresponding to the electronic transition of a single polyenyne chain. This energy is located at the low energy end of a yellow PDA solution spectrum. From Raman scattering v_(C?C) = 2108–2128 cm^?1 and v_(C?C) = 1505–1532 cm^?1 were calculated after extrapolation. Similarly sp-C¹³C NMR data yielded a shift of δ = 100 ppm. These data are almost identical to data known for yellow PDA solutions. Bond geometries are almost identical to those of poly(diacetylene)s and theoretical data.     

SOLUBILISATION OF NITROGENOUS CONSTITUENTS OF BREWERS' SPENT GRAIN

The extraction of nitrogenous material from Brewers' spent grain (BSG) by solvents (water, sodium chloride solution, aqueous alcohol, acidic and alkaline solutions) commonly used to extract cereal proteins, resulted in the relatively low (0·2 to 8·5%) recovery of the total nitrogen. The recovery of nitrogenous material by the use of aqueous alkaline solutions was increased from 3–4% to 41% when the BSG was subjected to cellulase incubation prior to extraction. Approximately 75% of the nitrogen was solubilized with trifluoracetic acid. Detergent solutions (acid, neutral) solubilized more than 80% of the total nitrogen of the BSG. The low solubility of the nitrogenous constituents by conventional protein solvents could be the result of association between cellulosic material and protein.     

一种混沌信号去噪方法的研究

以Takens嵌入定理和影子定理为理论依据，提出一种能对混沌信号去噪的局部投影方法。该方法不需潜在动力学系统的先验知识，符合工程实用的要求。通过实验结果表明这种方法对混沌信号去噪很有效。     

交联型聚醚聚氨酯的表征、力学性能及其碱金属盐络合物的导电性能

采用三羟甲基丙烷（ＴＭＰ）作交联剂与聚乙二醇（ＰＥＯ－１５４０）和甲苯二异氰酸酯（ＴＤＩ）反应，得到了具有较好力学性能的交联型聚醚聚氨酯（ＰＥＵ），该聚合物与ＬｉＣｌＯ４的结合物具有较高的室温电导率（σ３０℃＝１．８７×１０￣（－４）Ｓ／ｃｍ）。采用全反射红外光谱（ＡＴＲ－ＩＲ）对聚合物的结构进行了表征。对聚合物的组成、不同ＴＤＩ类型及络合盐浓度对聚合物力学性能及其络合物电导率的影响进行了探讨。低度交联聚合物的络合物，其电导率与温度的关系符合建立在自由体积理论上的ＶＴＦ方程，表明络合物中离子的传导主要是在无定形区域进行，与自由体积有关。     

LXT384接口芯片的几种环回形式

LXT384是一个用于SONET/SDH设备的八进制T1/E1/J1线路接口单元芯片。文中简述了该芯片在实际应用中进行自检的若干种不同的环回形式(包括：模拟环回、数字环回、运程环回等)，直观地指出了各种环回形式的特点和区别。     

Application of the dynamical flexural resonance technique to industrial materials characterisation

The determination of the Young’s modulus and damping coefficient Q⁻¹ by means of non-destructive vibrating techniques has been applied to bulk and coated industrial materials. Extensions of a previous analytic model of composite beam allow to determine accurately the macroscopic modulus of each component of multilayered structural materials as coated superalloys or nitride-hardened steels. Furthermore, the study of glasses and polymers has been investigated. An attempt of normalisation of the modulus versus temperature curves allows to establish master curves depending on the specific structure, from metallic glasses to polymeric glasses. Finally a comparison of dynamical modulus and Q⁻¹ values measured between resonant (>1 kHz) and subresonant techniques (10⁻³ to 10 Hz) in relation to the loading frequencies applied in real conditions has been under folder. For metallic materials such as forged or rolled titanium alloys, the brittle-to-fragile transition occurs abruptly or smoothly with a shift of 300 K following the range of excitation frequencies.     

An introduction to Wu's method for mechanical theorem proving in geometry

Wu's algebraic method for mechanically proving geometry theorems is presented at a level as elementary as possible with sufficient examples for further understanding the complete method.The work reported here was supported by NSF Grant DCR-8503498.     

丙烯酸酯与甲基丙烯酸酯的共聚及性能研究

采用悬浮聚合法，以丙烯酸－２－乙基－己酯与甲基丙烯酸十二酯为单体，合成了共聚型高吸油性树脂。研究了共聚单体的配比、交联剂用量、引发剂用量诸因素对高吸油性树脂的性能影响。制得的树脂可以吸其自身质量的１１．８倍的煤油、１４．７倍的苯、６．５倍的泵油。     

聚合物冷拉过程的流函数分析

用流函数法分析了聚合物拉伸成形时，颈缩的发生和扩展过程，文中论证了采用流函数法的优越性和适用性，并将流函数法计算结果和有限元法计算结果作了对比。