The isothermal and cyclic oxidation behaviour of two Co modified aluminide coatings at high temperature

The isothermal and cyclic oxidation behaviour of two Co modified aluminide coatings together with the simple aluminide coating were performed at 1000 °C and 1100 °C. All the three coatings show a much lower oxidation rate compared with the bare alloy. Results also indicate the addition of Co to the aluminide coating decreases the oxidation resistance slightly. It can be ascribed to that Co is easier to be oxidized than Ni at high temperature, and the Cr(W) rich phases which could act as a diffusion barrier are less in the coating with higher Co content.     

Heat treating of a ring rolled Ni–Fe–Cr superalloy

Abstract

Haynes HR-120 alloy (UNS N08120) is a nickel–iron–chromium alloy that exhibits high strength at elevated temperature and resistance to carburising and sulphidising environments. These properties make this alloy suitable for the production of components of land based turbines, including rings. Manufacture and heat treating of such rings require strict control of the processing variables, such as temperature and deformation ratios, as well as the time and temperature of the solution treatment, due to their effect on microstructure and mechanical properties. It is common practice to treat this alloy at temperatures above 1100°C to promote dissolution of undesired particles and recrystallisation of deformed structures, but it has been found that grain coarsening can occur during treatment. The present work presents the results of a series of solution heat treatments that were performed within a broad range of temperatures on industrial ring rolled pieces. It was found that the increment in time and temperature enhances the dissolution of intergranular precipitates that result in the improvement of mechanical properties, but grain coarsening is observed to occur when the material is treated for long times and high temperatures. The best combination of mechanical properties and grain size was obtained by treating the material for half an hour at 1050°C.     

Chemical Composition Design of Superalloys for Maximum Stress, Temperature, and Time-to-Rupture Using Self-Adapting Response Surface Optimization

We have adapted an advanced semistochastic evolutionary algorithm for constrained multiobjective optimization and combined it with experimental testing and verification to determine optimum concentrations of alloying elements in heat-resistant austenitic stainless steel alloys and superalloys that will simultaneously maximize a number of the alloy's mechanical properties. The optimization algorithm allows for a finite number of ingredients in the alloy to be optimized so that a finite number of physical properties of the alloy are either minimized or maximized, while satisfying a finite number of equality and inequality constraints. Alternatively, an inverse design method was developed, which uses the same optimization algorithm to determine chemical compositions of alloys that will be able to sustain a specified level of stress at a given temperature for a specified length of time. The main benefits of the self-adapting response surface optimization algorithm are its outstanding reliability in avoiding local minimums, its computational speed, ability to work with realistic nonsmooth variations of experimentally obtained data and for accurate interpolation of such data, and a significantly reduced number of required experimentally evaluated alloy samples compared with more traditional gradient-based and genetic optimization algorithms. Experimentally preparing samples of the optimized alloys and testing them have verified the superior performance of alloy compositions determined by this multiobjective optimization.     

Oxidation of a chromia-forming nickel base alloy at high temperature in mixed diluted CO/H2O atmospheres

Corrosion of a chromia-forming nickel base alloy, Haynes 230^®, has been investigated under impure helium containing a few Pa of CO and H₂O at 900 °C. It has been found that this alloy reacts simultaneously with CO and H₂O. Oxidation by CO has been revealed to occur mainly in the first hours. CO diffuses through the scale via short-circuit pathways and oxidizes Al, Cr and Si at the oxide/metal interface. Kinetics of CO oxidation has been investigated and several rate limiting steps are proposed. In the long term, H₂O is the major oxidant of chromia-forming nickel base alloys in impure helium.     

Creep life prediction for udimet 720 material using the initial strain method (ISM)

Despite of considerable research results of uniaxial tension creep available for superalloys, few studies have been made on high temperature creep using the Initial Strain Method (ISM). In this paper, the real-time prediction of high temperature creep strength and creep life for the nickel-based superalloy Udimet 720 (high-temperature and high-pressure gas turbine engine materials) was performed on round-bar type specimens under pure static load at the temperatures of 538°C, 649°C, and 704°C. The predictive equation derived from the ISM in creep tests showed better reliability than those from LMP(Larson-Miller Parameter) and LMPISM (Larson Miller Parameter-Initial Strain Method) specially for long time creep prediction (10³-10⁵h)