基于机器学习算法的AMSR-2地表温度降尺度研究

MODIS日尺度的地表温度受到天气影响,有效像元信息严重缺失,这对数据稀缺区域尤为重要。以古尔班通古特沙漠为研究区,探索了采用AMSR-2的垂直极化亮度温度与植被指数对地表温度空间降尺度的方法,并用此方法填补了2018年MODIS的缺失像元。(1)通过十折交叉验证,对4种机器学习算法（Cubist、DBN、SVM、RF）、10个波段组合、2个空间尺度（5 km、10 km）下的训练模型进行了分析,表明RF算法精度明显高于其他3种算法,C09波段组合的验证精度高于其他波段组合。(2)构建了2个鲁棒性的随机森林算法地表温度降尺度模型（5 km|RF|09、10 km|RF|09）,将AMSR-2亮度温度降尺度到1km分辨率,表明5 km|RF|09模型反演结果更为合理,MODIS与站点验证的R2分别为0.971、0.930,RMSE分别为3.38 K、4.71 K,MAE分别为2.51 K、3.84 K。(3)降尺度结果填补MODIS地表温度缺失像元,将其应用到古尔班通古特沙漠长时间序列的陆表温度分析,可为数据稀缺区域数据获取提供科学参考。     

硬脂酸修饰Lipolase脂肪酶的性能

采用N-羟基琥珀酰亚胺活化法用硬脂酸对Lipolase脂肪酶进行了化学修饰。研究了Lipolase脂肪酶的水解活力和酯化活力,重点研究了界面催化活性和表/界面张力。实验结果表明:与未修饰酶相比,修饰Lipolase的水解活力略有下降,但正己烷中的酯化活力和界面水解活力均明显提高;修饰Lipolase降低表面张力与界面张力的能力提高。用LB技术制备Lipolase的单分子层膜,发现修饰Lipolase的∏-A曲线上移,表明修饰Lipolase更易在表面形成单分子层膜。可见Lipolase脂肪酶经硬脂酸修饰后界面活性提高、有利于在有机相或两相界面催化化学反应。     

Application of functionalized magnetic silica nanoparticles for selective induction of three coumarin metastable polymorphs

The precise control of active pharmaceutical ingredient(API) crystal nucleation and polymorphism is a key consideration in pharmaceutical manufacturing.In this study,tunable nanoparticles were developed to regulate the nucleation process of coumarin.Magnetic silica nanoparticles with four different functional groups(-NH₂,-COOH,-SH,-NCO) were prepared and coated on the substrate for inducing the crystallization of coumarin.Confined melt crystallization and microspacing sublimation crys...     

Insights into the confinement effect on isobutane alkylation with C4 olefin catalyzed by zeolite catalyst: A combined theoretical and experimental study

Elucidating the confinement effect harbours tremendous significance for isobutane alkylation with C₄ olefin. Herein, the confinement effect over zeolite catalysts was elucidated by combining DFT calculations, experiments(using the novel Beta zeolite exposing only external surfaces(Beta-E) and conventional Beta-I zeolite with both external and internal surfaces) and multi-techniques(e.g., TGA-DTG,HRTEM, SEM and XRD). It is found that the main active sites for C₄ alkylation r...     

张力控制的变频系统

在工业生产的很多行业中,都需要进行精确的张力控制,保持张力的恒定,以提高产品质量。在传统的张力控制中,收卷与放卷设备经常需要维护,且维护费用高,给企业带来了很多的不便,因此采用张力控制的变频控制系统将逐步取代传统的张力控制。通过研究张力控制变频系统的工作原理,引入张力专用变频器,可以很好解决收卷的各种问题。文中以超级压光机为例,进行了阐述。     

Interfacial and emulsifying behaviour of crayfish protein isolate

The interfacial behaviour of adsorbed protein films constituted with a crayfish protein derivate that is typically produced as by-product from the food industry, has been studied at the air-water and oil-water interfaces. An analysis of the surface pressure under compression-expansion cycles of this protein was carried out as a function of time, concentration and pH (2 and 8). Besides, interfacial tension and adsorption kinetics also were determined as a function of time at different concentrations and pH values. Interfacial rheological properties were studied under dilatational deformations applied to a single droplet, either at the initial step of film formation or once the interfacial tension was at equilibrium and the film was completely formed. The contribution of the interfacial properties to the behaviour of oil-in-water emulsions stabilised with this protein derivative were also analysed. Finally, droplet size distributions obtained for concentrated emulsions stabilised by crayfish protein were analysed and related to the interfacial tension behaviour. We have demonstrated that crayfish proteins at pH 8 show higher solubility, smaller aggregates and better interfacial activity (higher surface pressure and lower interfacial tension) with higher interfacial viscoelasticity, than at pH 2. A two-dimensional model of the results showed that oil-water and air-water interfaces are clearly related to the improved stability of emulsion made with crayfish proteins at pH 8.     

酶解泥鳅蛋白制备小分子肽的工艺研究

以泥鳅为原料,酶解泥鳅蛋白制备小分子肽。运用响应面分析法优化泥鳅蛋白酶解的工艺条件,探讨了泥鳅蛋白酶解过程中液料比、酶解温度、酶解时间对多肽得率的影响。结果表明,泥鳅蛋白酶解的工艺条件为:液料比1.3、酶解温度57℃、时间9.42h,肽的得率为36.3%(模型预测值为36.37%)。通过OriginPro7.0软件计算,在显著性水平P>0.05下,预测值与实际值无显著不同,表明运用响应面分析法优化泥鳅蛋白酶解工艺条件是可行的。     

建筑设计中的"面造型"

从建筑形式的构成元素入手,分析其中的"面"与"体"的关系,以认知心理学为依据,从建筑形式中抽象出"面"的概念,提出"面造型"设计方法,并结合近年优秀建筑作品进行造型手法归纳.     

焙烧还原条件下硬脂酸钠改性水滑石的制备及应用

以镁铝碳酸根型水滑石MgAl-CO₃-LDHs(LDHs)为前驱体,硬脂酸钠(NaSt)为改性剂,通过焙烧还原法在硬脂酸钠的溶液中制备硬脂酸钠改性水滑石LDHs-NaSt,采用X射线衍射仪(XRD)、傅里叶转变红外光谱仪(FTIR)和扫描电镜(SEM)对结构进行表征,并研究不同改性剂加入量条件下得到的改性水滑石对聚氯乙烯(PVC)热稳定性能的影响。结果表明,在氮气保护下,焙烧后的水滑石可以成功复原,硬脂酸钠对LDHs的改性为表面改性,但影响复原水滑石的结晶度。改性水滑石可以改善PVC的初期着色性和长期热稳定性,随着改性剂浓度的增大,当NaSt与LDHs质量比为1∶4时,静态热老化时间可以达到370 min,比未改性水滑石热稳定性能提升了61%。     

改性氢氧化镁的制备及在HDPE中的应用

以低品位菱镁矿为原料,γ-(甲基丙烯酰氧)丙基三甲氧基硅烷(KH570)为改性剂,通过蒸氨-沉镁改性-水热过程制备改性氢氧化镁[KH570-Mg(OH)₂],改性剂在Mg(OH)₂生成体系中加入。采用吸油值、活化指数、红外光谱(FTIR)、X射线衍射(XRD)等手段对改性结果进行表征,在改性时间为60min,改性剂用量为2%,并进行水热处理工艺制备的Mg(OH)₂改性效果最好,改性后Mg(OH)₂活化指数达到了98.75%,吸油值为53.05 mL/100g,接触角为149°。整个工艺连续且可循环,为制备疏水性Mg(OH)₂工业生产提供实验基础。并将改性前后的Mg(OH)₂应用于高密度聚乙烯(HDPE),测试其阻燃和力学性能,结果表明,KH570-Mg(OH)₂添加量为40%时,HDPE/KH570-Mg(OH)₂复合材料的氧指数为29.5%,达到阻燃级别,拉伸强度为18.40 MPa,断裂伸长率为217.11%...