TOC含量对页岩脆性指数影响分析

页岩储层的有效开发依赖水平井段的压裂,脆性指数是影响压裂施工设计的一个重要参数。有3种脆性指数计算结果常相互矛盾。通过基于岩心数据刻度对不同页岩层段测井响应特征的比较研究,发现总有机碳含量(TOC)对声波时差和补偿密度等用于计算脆性指数的测井曲线均有影响,是导致3种方法计算结果各不相同的主要原因。采用TOC校正方法与岩心实验数据约束测井评价可使3种计算结果非常接近,有效解决了TOC含量对脆性指数评价的影响。该方法在多口井中应用,效果良好。     

Cadmium and zinc in soil solution extracts following the application of phosphate fertilizers

This study investigated the solubility of cadmium and zinc in soils after the application of phosphate fertilizers containing those two metals. The solubility of cadmium and zinc was assessed by measuring their concentration in soil water extracts. Three monoammonium phosphate fertilizers containing various amounts of metals were applied on cultivated fields for 3 years at three different rates. In order to investigate the effects of long-term applications of fertilizers on the solubility of Cd and Zn, a similar design was used to apply contaminated fertilizers to soils in a laboratory experiment using a single fertilizer addition equivalent to 15 years of application. Phosphate fertilizers increased the concentration of Cd in soil extracts compared to control in 87% and 80% of the treatments in field and laboratory experiments respectively. Both increasing the rate of application and using fertilizer containing more Cd lead to higher Cd concentrations in extracts for the field and the laboratory experiments. The addition of the equivalent of 15 years of fertilizer application in the laboratory results in higher Cd concentration in extracts compared to the field experiment. For Zn, the fertilizer treatments enhanced the metal solution concentration in 83% of field treatments, but no significant correlations could be found between Zn inputs and its concentration in solution. In the laboratory, fertilizer additions increase the Zn concentrations in 53% of the treatments and decrease it in most of the other treatments. The decrease in Zn concentrations in the laboratory trial is attributed to the higher phosphate concentrations in the soil solution; which is presumed to have contributed to the precipitation of Zn-phosphates. For both trials, the metal concentrations in soil extracts cannot be related to the Zn concentration in the fertilizer or the rate of application. The high Zn to Cd ratio is presumably responsible for the Cd increase in the soil extracts due to competitive displacement by Zn. Finally, the observed acidification of soils with fertilizer application will also contribute to metal solubilisation.     

Kinetics of phenol mineralization by Fenton-like oxidation

The kinetics of hydrogen peroxide decomposition and the mineralization rate of phenol in homogeneous aqueous solution (pH < 3) via Fenton-like reaction were studied. Results were correlated with the generation of hydroxyl radicals as well as with iron speciation. Batch experiments were carried out in de-ionized water in a completely mixed batch reactor under a wide range of experimental conditions (3500 ≤ [H₂O₂] ≤ 8250 mg/L; 100 mg/L ≤ [Fe] ≤ 2350 mg/L; 2.5 ≤ [H₂O₂]/[Fe] ≤ 83; 0 mg/L ≤ [TOC] ≤ 1000 mg/L). Results demonstrated that the rate of hydrogen peroxide decomposition, phenol mineralization and ferrous ions formation depended on both the initial concentration of the phenol and on the weight ratio between hydrogen peroxide and iron. A linear correlation was found between the mineralization rate of phenol and the decomposition rate of hydrogen peroxide indicated that 10 g of hydrogen peroxide was required to mineralize 1 g of phenol.     

Peroxi-coagulation degradation of C.I. Basic Yellow 2 based on carbon-PTFE and carbon nanotube-PTFE electrodes as cathode

The electrochemical treatment of solutions containing C.I. Basic Yellow 2 (BY2) in aqueous solutions with carbon-PTFE (polytetrafluoroethylene) and carbon nanotube (CNT)-PTFE electrodes as cathode has been studied. The fabricated electrodes were characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The amount of electrogenerated H₂O₂ on the surface of these electrodes was investigated, too. The results showed that the amount of H₂O₂ obtained with the CNT-PTFE electrode was nearly three times higher than that of carbon-PTFE electrode. The decolorization efficiency of BY2 in peroxi-coagulation process reached 62% and 96% in the first 10 min by carbon-PTFE and CNT-PTFE electrodes at 100 mA, respectively. The effect of operational parameters such as applied current, initial pH and initial dye concentration was studied in an attempt to reach higher decolorization efficiency. The degradation and mineralization of BY2 using CNT-PTFE electrode were followed by total organic carbon (TOC) and GC–MS analysis. The results of TOC measurements indicated that peroxi-coagulation with carbon-PTFE allowed 81% mineralization after 6 h of electrolysis; whereas peroxi-coagulation with CNT-PTFE yields 92% mineralization under the same conditions. GC–MS analysis verified the identity of intermediates and a reaction pathway based on them was proposed.     

活性炭负载金属离子催化合成无毒增塑剂柠檬酸三辛酯的研究

以柠檬酸和正辛醇为原料,采用活性炭负载金属离子Sn^4＋、Fe^3＋、Ti^4＋为催化剂催化合成无毒增塑剂柠檬酸三辛酯,分别考察了催化剂种类、催化剂用量、醇酸物质的量比、反应温度、反应时间、醇酸物质的量比对酯化反应的影响,并对产品进行红外光谱分析。实验结果表明,以活性炭负载四氯化锡催化合成的最佳工艺参数：反应温度为200℃,催化剂用量为2．3g,醇酸物质的量比为1：4．5,反应时间为1．5h时,酯化率可达97．6％。     

电絮凝气浮法处理分散艳蓝E-4R废水的研究

采用电絮凝气浮法处理分散艳蓝E-4R染料废水,考察了电解时间、废水初始浓度、pH值及外加电解质氯化钠和絮凝剂等不同反应条件对废水处理效果的影响。结果表明,染料废水脱色率随着电解时间的加大而逐渐增大并随初始浓度的增大而慢慢降低;pH值在2.5~10范围内电解均可获得较高的脱色率。初始浓度为400 mg/L的染料废水,电解20 min后脱色率即达87.39%,但TOC去除率只有10.49%。投加50 mg/L氯化钠后,脱色率和TOC去除率分别达到93.61%和73.49%,TOC去除率提高60%以上。在电解的条件下投加不同絮凝剂能提高染料废水的处理效果,其处理效果从大到小依次为:硫酸铝>三氯化铝>硫酸亚铁,它们的适宜用量分别为50,100,100 mg/L。     

扩展近似时间最优伺服控制及其试验验证

针对带有惯性阻尼环节的典型伺服系统,提出一种能实现大范围快速定点运动的控制方案。控制方案首先利用时间最优控制律进行快速目标追踪,当系统速度下降到一定范围内时平滑切换成线性控制律。采用线性控制区内的闭环极点阻尼系统和自然频率作为设计参数,给出了全参数化的控制律。基于Lyapunov理论分析了控制系统的闭环稳定性。将该控制方案用于一个直流伺服电机的位置-速度环的定点位置控制,并进行了MATLAB数字仿真和基于TMS320F28335 DSC的试验研究。结果表明:所设计的控制系统可以对大范围的给定目标进行快速和准确的跟踪,且对扰动和系统参数差异具有较好的鲁棒性。     

Geochemistry of episodic sedimentation in Bizerte Lagoon,northern Tunisia

The decrease of the contents of TOC in sediment cores in the Bizerte Lagoon is synchronous with that of carbonates. This is attributed to a dilution phenomenon of the organic fraction by the carbonate component of the sediment in the lagoon. This phenomenon also can be explained by the effect of early diagenesis, resulting in the existence of more condensed products, or by removal of more labile organic fraction and/or by reorganization mechanisms leading to the solubilization of organic matter towards deep levels. It appears that the mechanisms controlling the geochemical sedimentation in the lagoon are similar to those observed today, with some occasional characteristics reflecting the impact of episodic phenomenon related to other factors and processes, especially a continental influence on the sediments, rather than marine influences.     

TOC-5000A总有机碳分析仪及其在环境监测中的应用

通过分别测定总碳和无机碳，计算二者的差值可得到总有机碳的测定值。本文介绍了岛津ＴＯＣ－５０００Ａ总有机碳分析仪的工作原理和性能特点，以及ＴＯＣ－５０００Ａ分析仪在环境监测中的应用。