助剂对Pd/树脂醚化催化剂催化性能的影响 Ⅰ.铝助剂的影响

研究了不同助剂对Ｐｄ／树脂醚化催化剂在临氢条件下对催化裂化汽油Ｃ５馏份与甲醇和Ｈ２反应的催化性能的影响。结果表明，在Ｐｄ／树脂醚化催化剂中引入Ｚｒ、Ｔｉ、Ｂ、Ｓｎ和Ａｌ等助剂后，都能改善催化剂的醚化、双键异构和二烯烃选择性加氢活性，其中以Ａｌ、Ｓｎ为最好。Ａｌ助剂的体积质量和负载方式对Ｐｄ－Ａｌ／树脂醚化催化剂的活性有影响。ＢＥＴ方法和Ｘ－射线荧光光谱分析（ＸＦＳＡ）表明，Ａｌ助剂对Ｐｄ－Ａｌ／树脂醚化催化剂的表面积、孔结构和Ｐｄ离子交换量影响较小。     

Li2O在保护渣中的作用

采用在不同玻璃性的两种基渣中加入Ｌｉ２Ｏ为研究Ｌｉ２Ｏ对保护渣粘度，熔化温度及玻璃性能的影响，并对Ｌｉ２Ｏ改善保护渣玻璃性的机理进行了探讨，提出了寻找高速连铸保护渣中Ｌｉ２Ｏ的代用物的一种方法。     

XH－Ⅰ型岩石铵梯炸药研究

文章论述利用过期火药的一种新途径。在２号岩石铵梯炸药中加入粉碎的过期火药以代替部分梯恩梯，制成一种ＸＨ－Ⅰ型岩石铵梯炸药，适用于各种爆破工程。并具有较高的经济效益和社会效益。     

Final Drying of Whole Milk Powder in Vibrated-Fluidized Beds

Vibro-fluidized beds are widely used in drying sticky powders and agglomerated materials as milk powder. Using a vibro-fluidized laboratory scale dryer, this work is aiming at analyzing preliminarily the effect of its operational variables on the drying kinetics and characteristics of whole milk powder. The full-factorial design technique with three replications at the central point has been employed to generate data and correlations to quantify the effect of inlet air temperature, air flow rate, and vibration bed amplitude on the drying curves and the milk powder properties related to its faster reconstitution in water (as tapped density, Hausner cohesion ratio, agglomerate size distribution, and internal pore concentration). Results obtained are analyzed and discussed to identify the adequate operation condition for final drying whole milk powder in vibro-fluidized beds, assuring a high product quality.     

一种制备磁性粉末的新技术--均匀颗粒成型法

采用均匀颗粒成型法（Uniform Dropler Spray-UDS）制备Fe基合金粉末，该方法制备的颗粒粒度分布均匀，性能一致，大大优于传统的粉末制备方法（如破碎法、气雾化），具有广阔的应用前景。本文分析了粉末制备过程中颗粒尺寸的影响因素，结果表明：颗粒的大小主要取决于坩埚底部小孔、坩埚内外气体压强差以及振荡频率三个独立变量。     

织物树脂层压复合材料抗弹性能研究

针对防弹织物树脂层压复合材料的研制，考察了层压复合材料面密度，纤维类型，树脂体系，铺层混杂方式及纤维混杂分数，织物铺层，预置分层等因素对层压复合材料靶板弹道冲击性能的影响。     

Influence of Ti Powder Characteristics on Combustion Synthesis of Porous NiTi Alloy

Porous NiTi shape memory alloy (SMA) is a novel biomedical material used for human hard tissue implant .The influence of elemental titanium powder characteristics such as powder morphology, particle size and specific surface area( SSA) on the minimal ignition temperature ,combustion temperature and final product of porous Ni-Ti SMA fabricated by combustion synthesis method was investigated in this paper by scanning electron microscopy (SEM) and laser diffraction.The preliminary data indicated that the titanium powder characteristics had a strong effect on combustion synthesis of porous NiTi SMA.     

纳米NiO粉体的制备及其表征

采用溶胶转化－凝胶法制备了纳米级NiO粉体。Ni(OH)2粉体的TG－DSC分析表明：在升温速率为10℃/min的条件下，粉体在489K时开始显著分解，626K时分解完毕。X－射线衍射分析表明：分解产物为纯净的NiO2。NiO粉体的化学成分分析表明：其纯度高于国家标准。TEM电镜分析表明：NiO粉体呈单分散的球形或棒状颗粒。对NiO粉体的热敏性能有待进一步研究。     

Oxidation of porous nanocrystalline titanium nitride. II. Scale structure and composition

We have used x-ray phase analysis to study the composition of the products of reaction between oxygen and nanocrystalline powders with particle sizes 15, 40, 55, and 80 nm, and also specimens pressed (and sintered) from them. The powders were oxidized in air at 100°C (400 h) to 500°C (5 min), while the sintered specimens were oxidized at 600–900°C for 15, 120, and 240 min. In all cases, in the initial oxidation step the oxynitride Ti(O_xN_y) is formed, which over time is oxidized to TiO, Ti₂O₃, Ti₃O₅, TiO₂ (anatase) and TiO₂ (rutile). In the range 600–800°C, formation of a continuous oxide layer and conversion of anatase to rutile slows down diffusion of oxygen in the scale. We have established that at 900°C, the growth rate of the scale thickness increases and so the reflections from the oxynitride are barely noticeable on the diffraction patterns taken from the surface of the oxidized specimen. In these diffraction patterns, along with strong reflections from the rutile, we also observed weak reflections from lower oxides and anatase, which may be due to reaction between oxygen and the titanium ions diffused to the scale surface. We have concluded that at T > 850°C, the mechanism for oxidation of TiN changes. This is due to superposition of counterdiffusion of titanium ions on the diffusion of oxygen. __________ Translated from Poroshkovaya Metallurgiya, Nos. 3–4(448), pp. 72–78, March–April, 2006.     

单壁纳米碳管/纳米铝基复合材料的增强效果

用半连续氢电弧法和活性氢等离子蒸发法分别制备出单壁纳米碳管(SWNTs)和纳米A1粉体，然后用提纯后的SWNTs和纳米A1粉体制备出SWNTs含量(质量分数)分别为0、2．5％、5．0％、7．5％和10.0％的单壁纳米碳管／纳米铝基块体复合材料．SWNTs对高强度纳米A1基体具有显著的增强作用，当SWNTs含量小于5．0％时，材料的硬度随着SWNTs含量的提高线性上升．其中5％SWNTs和纳米A1的复合增强效果最好，其硬度可达2.89GPa，大约是粗晶A1(0．15GPa)的20倍．当SWNTs含量超过5．0％时，增强效果开始缓慢的下降．讨论了单壁纳米碳管增强纳米铝基复合材料的强化机制．