Corrosion behaviour of Ni-Zr-Ti-Si-Sn amorphous plasma spray coating

Ni₅₉Zr₂₀Ti₁₆Si₂Sn₃ amorphous material was deposited by a vacuum plasma spraying technique onto steel and copper substrates in order to investigate their behaviour in a corrosive environment. For comparison, the same alloy was prepared as amorphous ribbons by melt spinning. The amorphous nature of the coatings and ribbons was characterized by XRD, DSC and TEM, while XPS and AES analyses were performed to understand the origin of passivation and mode of corrosion. The corrosion behaviour of the coating was studied in H₂SO₄ and HCl solutions open to air at room temperature. Potentiodynamic polarisation and galvanic coupling tests were carried out on the substrate and the coating. It was found that the formation of Zr-, Ti- and Si-rich passive oxide layers provide a high corrosion resistance in H₂SO₄ solution while the breakdown of the passive layer by chloride ion adsorption was responsible for pitting corrosion of the Ni₅₉Zr₂₀Ti₁₆Si₂Sn₃ amorphous ribbons in HCl solution. Galvanic corrosion was the dominant corrosion mechanism for the coating/copper hybrid structure, in contrast to the Ni₅₉Zr₂₀Ti₁₆Si₂Sn₃ amorphous coating, which efficiently protected the steel substrate in the corrosive environment.     

Ni－Fe－Cr－B－Si涂层超塑扩散焊接的强化效应及耐磨性

研究了Ｎｉ－Ｆｅ－Ｃｒ－Ｂ－Ｓｉ合金涂层超塑性扩散焊接及焊接后的强化效应。通过对涂层的组织结构分析、硬度及耐磨性能的测试表明，当基材（５ＣｒＭｎＭｏ钢）与涂层产生协调超塑变形时，涂层原颗粒间、涂层与基材结合界面完全焊合。超塑焊合后的涂层比高频重熔及火焰重熔涂层硬度（ＨＶ）提高１００－１５０，耐摩擦磨损性能提高３０％。指出，沉淀强化、细晶强化及晶内位错密度增加是引起涂层强化效应和提高耐磨性的主要因素。     

Stannate and permanganate conversion coatings on AZ31 magnesium alloy

The formation of stannate and permanganate–phosphate conversion coatings on AZ31 magnesium alloy was investigated in situ by EIS measurements and their protective performances were studied by different electrochemical techniques in diluted (0.05 M) sodium sulphate solution.The influence that short or long treatment times exert on the performances of such conversion coatings is discussed. While permanganate–phosphate baths always built layers characterized by penetrating cracks, long stannate baths produced layers without interconnected porosity, but were defective. This accounted for the initial greater protectiveness achieved with the stannate treatment; nevertheless, the easy penetration of the electrolytic solution through such a layer quickly decreased its corrosion resistance.     

Study on structure and magnetic entropy changes of Ce2-xPrxFe16.5Co0.5 alloys

A series of Ce2-xPrxFe16.5Co0.5 alloys were preparedby arc melting under purified argon atmosphere. The structure and magnetic entropy changes in Ce2-xPrxFe16.5Co0.5 alloys were investigated by means of X-ray diffraction pattern and MPMS XL-7 magnetometer. The experimental results show that the crystal structure of Ce2-xPrxFe16.5Co0.5 alloys keeps in TH2Zn17-type rhombohedral, and the Curie temperature of Ce2-xPrxFe16.5Co0.5 alloys can be shifted to room temperature around by a composition adjustment. The magnetic entropy changes (-ΔSM) in Ce2-xPrxFe16.5Co0.5 alloys are relatively large, and a platform of magnetic entropy changes appearsnear the temperature TC. Ce2-xPrxFe16.5Co0.5 alloys are the potential working media for magnetic refrigeration with their stable chemical properties and especially low price.     

弹链粉末涂装可行性探讨

通过炮用弹链粉末静电喷涂工艺试验,验证了弹链粉末涂装的可行性。粉末涂装工艺能够提高炮用弹链的防蚀性,简化工序。     

冷热循环工艺中冷热转移速率对LY12铝合金尺寸稳定性的影响

研究了冷热转移速率对LY1 2铝合金微屈服强度和残余应力的影响。结果表明 ,提高冷热转移速率易使材料中形成稳定的位错组态 ,从而有利于提高微屈服强度 ;对于圆柱和圆环试样 ,提高冷热转移速率不利于降低残余应力。分析认为 ,冷热转移速率应根据工件几何形状和尺寸进行相应调整。     

Corrosion resistance of electroplated Zn-Co alloy coating

By the NSS test and the test in SO2 gas atmosphere and detecting the φcorr-t curves, Rp-t curves and the cyclic voltammogram curves, the corrosion resistance of the electroplated Zn-Co alloy coating was studied. The corrosion resistance of the electroplated Zn-Co alloy coating is three times higher than that of the galvanized coating. Because the corrosion resistance of the Zn-Co alloy coating is especially remarkable in SO2 gas atmosphere, it is particularly fit to be used as a protective coating in industrial atmosphere. The reason why the Zn-Co alloy coating has such a high corrosion resistance is that its corrosive product has a comparatively great role in depressing the corrosive process.     

提高Cr12MoV钢冷作模具寿命的措施

从原材料改锻、预备热处理、淬火及回火、深冷处理、表面强化处理等方面分析介绍了提高Cr12MoV钢冷作模具寿命的一些方法和措施 ,并通过实例表明 ,采用这些方法和措施可较大幅度地提高模具寿命     

片状变燃速发射药燃烧性能的数值计算

为研究包覆方式对片状发射药燃烧性能的影响,建立了不同包覆方式下多层片状发射药的物理模型,并推导了形状函数和燃气生成猛度表达式,利用Matlab软件对不同的宽厚比、长厚比及多层结构的片状发射药进行了数值计算;制备了不同长厚比的片状变燃速发射药,并进行了密闭爆发器实验。结果表明,四面包覆和全包覆可以很好地消除临界宽厚比对片状发射药燃烧性能的影响;与两面包覆的片状发射药相比,四面包覆和全包覆的片状发射药能够延缓内层药减面燃烧的时间,其燃气生成猛度的阶跃程度分别提高了1.17%和1.23%,呈现出良好的燃烧渐增性。     

聚酯型粉末涂层附着力异常的原因分析

针对热镀锌板表面聚酯型粉末涂层附着力异常的问题,对比了涂层脱落和正常前处理的基材表面形貌、元素组成、清洁度和红外光谱,得出涂层附着力异常的原因为基材表面在喷涂前发生氧化和油污未除净,给出了相应的解决措施。