The biosand filter (BSF) is a household slow sand filter that is operated intermittently such that an idle time of typically 18-22 h occurs in between daily charges of water. Virus attenuation during the idle time was investigated over repeated daily filtration cycles to capture the effect of media aging that encompasses processes occurring throughout the filter depth rather than restricted to the schmutzdecke at the media surface. A threshold aging period of about one to two weeks was required before virus attenuation began. The observed rates of MS2 and PRD-1 reduction were first-order and reached maxima of 0.061- and 0.053-log per hr, respectively, over seven-to-ten weeks. Suppression of microbial activity by sodium azide eliminated virus reduction during the idle time thus indicating that the operative media aging process was microbially mediated. The mechanism of virus reduction was not modification of media surfaces by physical/chemical or microbial processes. Instead, it appears that the activity of the microbial community within the filter is responsible. The most likely biological pathways are production of microbial exoproducts such as proteolytic enzymes or grazing of bacteria and higher microorganisms on virus particles. Implications of these findings for BSF design and operation and their relevance to other biological filtration technologies are discussed. 相似文献
Waterborne (WB) products are of growing importance in the car refinishes market. Especially WB basecoats are gaining increased market share during the last couple of years. The introduction of WB two-pack primers, fillers, clearcoats and single stage topcoats is hampered, however due to the lack of suited binder systems.
In this paper, new approaches will be presented for two-pack binder systems. A number of topics will be discussed in more detail: the design of the binders, the involved chemistry, the incorporation of stabilizing and reactive groups, the functionality and miscibility of the hardener. Based on these variables, the most important properties have been studied: film formation, reactivity, potlife and paint properties like hardness, appearance and water and solvent resistance. During the investigation, model studies have also been applied.
It is shown that some binder systems offer very attractive features in which a number of properties can be tuned, e.g. amine-functional emulsions combined with acetoacetate-functional hardeners result in an excellent level of properties suited for primer/filler application.
These binder systems have been used as the starting points for product development that resulted in new prototypes of low VOC WB products with a very attractive overall performance. 相似文献
The first stages of infrared drying of waterborne coating systems are controlled by the evaporation of their volatile components. In order to analyse the kinetics of drying during IR radiation, the evaporation behaviour of water and other solvents of waterborne coatings are investigated using a combined gravimetric and photoionization technique. The resulting specific evaporation rates under IR radiation are compared with those obtained by thermal annealing. It is shown that in the case of IR radiation heating of water, the mass transfer coefficients are much higher than by thermal annealing at the same driving potential. The dependence of the water absorption rates and the mass losses of different solvents on the humidity of the air was also determined. 相似文献
A modification in the alkyd based waterborne coatings was studied with the addition of 0.05%, 0.1%, 0.2%, and 0.3% nano-Al2O3. Corrosion performance of the nano-composite coatings were evaluated by applying these nanocomposites on mild steel substrate
and exposing them to salt spray, humidity, and accelerated weathering. Mechanical properties were studied by subjecting the
coating to scratch and abrasion test. The results showed that, with an increase in the concentration of nano-Al2O3 there was an improvement in the corrosion resistance, UV resistance, and mechanical properties of the coatings indicating
the positive effect of addition of nano-Al2O3 particles in the coatings. Further, the transparency of the coating was not altered, maintaining the optical clarity of the
coating. 相似文献
The aim of this research was to prepare waterborne polyurethane (WPU) coating blended with a series of poly(o-toluidine)-nano ZnO composites and study its anti-corrosion performance after its application over carbon steel. The synthesized composites were characterized by X-ray diffractometry (XRD), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). The corrosion resistance of coatings with and without nano ZnO were studied in 3.5% NaCl solution at a temperature of 25?°C, by electro-chemical techniques such as potentiodynamic polarization measurements and electrochemical impedance spectroscopy (EIS). It was observed that the composite coating containing 7% poly(o-toluidine)-nano ZnO composite had higher corrosion resistance than poly(o-toluidine) and 14% poly(o-toluidine)-nano ZnO composite. The presence of appropriate amount of ZnO significantly improved the corrosion resistance, due to the formation of passive layer on steel surface and the synergistic effects of poly(o-toluidine) along with a suitable amount of nano-ZnO reduced the porosity of the coating surface. 相似文献