基于色素谱吸收原理的肝储备功能无创测量系统

肝病一直是我国高发疾病,肝储备功能是肝病诊治中重要的生理参数,医院传统方法采用采血比色法进行肝储备功能测量.利用吲哚氰绿ICG色素指示剂对805 nm波长光的吸光效应,患者注射ICG色素,分别采集0 min、5 min、10 min、15 min的血液样本,通过比色测量,绘制ICG浓度代谢曲线,测量肝储备功能.为了避免采血法对测量结果和病人的不良影响,提出基于色素谱吸收原理的无创肝储备功能测量系统的设计方案.实验证明,利用805 nm和940 nm敏感波长以及吲哚氰绿ICG色素吸光特性,能较好地实现无创肝储备功能测量.     

在线激光乙炔分析仪在醋酸乙烯合成中的应用

本文介绍了以乙炔和醋酸为原料生产醋酸乙烯合成工艺中进行乙炔在线分析的重要性和传统检测方法的不足。在基于TDLAS技术基本原理的基础上,阐述了激光分析仪的性能特点和系统结构,以及在醋酸乙烯合成装置中乙炔在线检测应用中的优势。实际的应用结果表明,基于TDLAS技术的激光在线气体分析仪可以满足醋酸乙烯合成装置中乙炔浓度检测的应用要求。     

Detection of gases by correlation spectroscopy

This paper describes the detection of various common gases by means of correlation spectroscopy, employing a complementary-source-modulation (CoSM) approach based on compact light-emitting diode (LED) sources. Theoretical results for the quantitative detection of O₂, CO, and CO₂ by this CoSM method are presented, using, as their basis, spectral absorption data from the Hitran database. In demonstrating the proposed detection principle, new experimental results for the detection of O₂ in air are presented, with the use of practical low-cost LED sources.     

全固体化Nd：YVO_4单频绿光激光器

采用“面对面”激光二极管泵浦Ｎｄ：ＹＶＯ４和ＫＴＰ内腔倍频，获得单横模单纵横绿光输出。阈值泵浦功率为１２ｍｗ，实测的单端绿光最大单横模输出为７．３ｍｗ，最大单纵模输出为１．５ｍｗ，光光转换效率为１．９％。全固化系统设计小型紧凑，运转可靠。     

Influence of the additives argon, O2, C4F8, H2, N2 and CO on plasma conditions and process results during the etch of SiCOH in CF4 plasma

Reactive ion etch processes for modern interlevel dielectrics become more and more complex, especially for further scaling of interconnect dimensions. The materials will be damaged within such processes with the result of an increase in their dielectric constants. The capability of selected additives to minimize the low-k sidewall damage during reactive ion etching (RIE) of SiCOH materials in fluorocarbon plasmas was shown in different works in the past. Most of the investigated additive gases alter the fluorine to carbon ratio as well as the dissociation of the parent gas inside the etch plasma. The result is a changed etch rate, a modified polymerization behavior and other characteristics of the process induced SiCOH damage. Heavy inert ions like argon will be accelerated to the sample surface in the cathode dark space and enhance therewith the sputter yield on the SiCOH network [1]. In this paper the additives Ar, O₂, C₄F₈, H₂, N₂ and CO were added to a conventional CF₄ etch plasma. We try to provoke different changes in the plasma conditions and therewith in the process results. Contact angle measurements, spectroscopic ellipsometry, Hg-probe analysis, FTIR measurements and SEM cross-sections were used to overview the additive induced modifications. To understand the influences of the additives gases more exactly, changes in the physical and chemical plasma behavior must be analyzed. Therefore quadrupole mass spectrometry (QMS) and quantum cascade laser absorption spectroscopy (QCLAS) were used.     

氮在Fe-Cr-V液态高氮合金中的溶解行为

 采用MgO坩埚高频真空/加压感应炉在氮气压力04~10 MPa、温度1 570~1 640 ℃下,对加压感应熔炼Fe Cr V系高氮不锈钢进行了实验研究。结果表明,在30CaO 45Al2O3 25SiO2渣覆盖的情况下,氮在Fe 15Cr 10V、Fe 18Cr 10V、Fe 18Cr 15V和Fe 20Cr 20V液态合金中的溶解度分别为0595%、0736%、0776%和1020%,溶解度与氮分压的关系基本符合Sievert定律。渣对钢液吸氮和铝脱氧都起重要的作用,1 873 K、10 MPa氮气氛中,在30CaO 45Al2O3 25SiO2、40CaO 40Al2O3 20SiO2、40CaO 50Al2O3 10SiO2三种不同渣系作用下氮在液态Fe 18Cr 15V中的浓度分别是0776%、0849%和0884%。     

空气－氢气火焰原子吸收光谱法测定重整催化剂中低含量锡

提出用原子吸收光谱测定锡的新方法。使用空气－氧气火焰比用空气－乙炔火焰测锡的灵敏度提高了６倍，检测限达０．２３４μｇ／ｍｌ。考察了４种无机酸和２２种金属离子的干扰情况，试验表明加入三氯化铁可以消除多数金属离子的干扰。平行测定８份试样的相对标准偏差为１．８３％，分析结果用三种不同的分析方法进行了验证。本文为低含量锡的测定提供了新方法。     

某商住楼两种不同空调方案的能耗分析

采用BIN能耗分析的方法,对天津市某一商住楼空调系统的两种不同方案进行能耗分析,比较两种系统在能源消耗上的差别,并提出了系统节能改造建议。     

非对称量子阱中线性和三阶非线性光吸收系数的研究

主要研究了一个特殊非对称量子阱中的线性和三阶非线性光吸收系数。首先利用量子力学中的密度矩阵算符理论和迭代方法导出了线性和三阶非线性光吸收系数的表达式，然后以典型的非对称量子阱GaAs／AIGaAs材料为例作了数值计算。数值结果表明，入射光强以及系统的非对称性对总的光吸收系数有比较大的影响，从而为实验研究提供理论依据。     

脉冲光源原子吸收光谱仪信号数字处理软件的设计

通过实验室设计的脉冲光源钨丝原子吸收光谱仪,采集到一个分析信号和光源载波叠加的复合信号。为了从中提取原子吸收分析信号,首先对该复合信号进行数值微分,确定光源脉冲载波每个峰的坐标和相应的峰高,算出每个载波峰位相应的吸光度值,绘制吸收峰轮廓图;然后根据辛普森(Simpson)数值积分原理,求出吸收峰的面积,从而得到积分吸光度值。在微软公司的Visual Basic 6．0开发平台上,编写了实现上述功能的软件,以图形和数值的方式,同时输出每次测定结果。该软件系统和钨丝原子吸收光谱仪硬件系统相配合,对铜标准溶液的测试结果为:检出限为0．0133μg/ml,线性范围为0．10- 4．0μg／ml,对1．0μg／ml Cu(n=10)测定的精密度为RSD=4．05％。