Flammability characteristics at applied heat flux levels up to 200 kW/m2

This paper documents the first of the two interrelated studies that were conducted to more fundamentally understand the scalability of flame heat flux, the motivation being that it has been reported that flame heat flux back to the burning surface in bench‐scale experiments is not the same as for large‐scale fires. The key aspect was the use of real scale applied heat flux up to 200kW/m² which is well beyond that typically considered in contemporary testing. The main conclusions are that decomposition kinetics needs to be included in the study of ignition and the energy balance for steady burning is too simplistic to represent the physics occurring. An unexpected non‐linear trend is observed in the typical plotting methods currently used in fire protection engineering for ignition and mass loss flux data for several materials tested and this non‐linearity is a true material response. Using measured temperature profiles in the condensed phase shows that viewing ignition as an inert material process is inaccurate at predicting the surface temperature at higher heat fluxes. The steady burning temperature profiles appear to be invariant with applied heat flux. This possible inaccuracy was investigated by obtaining the heat of gasification via the ‘typical technique’ using the mass loss flux data and comparing it to the commonly considered ‘fundamental’ value obtained from differential scanning calorimetry measurements. This comparison suggests that the ‘typical technique’ energy balance is too simplified to represent the physics occurring for any range of applied heat flux. Observed bubbling and melting phenomena provide a possible direction of study. Copyright © 2007 John Wiley & Sons, Ltd.     

电流变体特性及电流变体应用器件的进展

本文详细评述了电流变体(ERF)材料的组成、工作机理及其流变力学性能,提出以Bingham塑性体来近似描述电流变体的流变特性,综述了电流变体在智能材料、汽车离合器、液压阀门等器件中的应用,给出了含电流变体的双层智能复合材料梁单层、双层加电状态对其振动特性的影响,设计了含电流变体的主动控制式减振器,并对其在外加电场作用下的减振性能进行了评价。     

Fischer-Tropsch synthesis on Fe-Mn ultrafine catalysts

The Fischer-Tropsch (FT) synthesis on Fe-Mn ultrafine catalysts prepared by a special degradation method of Fe-Mn complexes is presented. The effects of preparation method and Mn content on the FT performance are examined and the active phases and the role of Mn are elucidated.     

大小样品在液氮中的淬冷沸腾换热比较研究

分析了大小样品在液氮中的淬冷沸腾换热特性。大小样品的淬冷沸腾换热有着明显的差别，小样品的热流密度比大样品的明显高得多。小样品的淬冷沸腾有一起始段，其温降高达６０Ｋ。从实验结果还可以看到，小样品的Ｌｅｉｄｅｎｆｒｏｓｔ点和临界热流点对应的壁面过热度明显比大样品的高。最后还分析了样品直径对临界热流密度的影响。     

有源滤波器非线性行为分析及其电磁干扰的抑制

对具有结构不稳定性的有源滤波器的非线性问题进行了研究，通过对绝缘栅双极型晶体管（IGBT）器件开关过程产生的瞬态电流脉冲的传播过程进行分析，将IGBT器件的控制电压引起的结构稳定问题的抑制转化为该瞬态电流脉冲传播通路的阻断。利用仿真和实验对正激式与反激式开关变换器进行抗干扰能力的研究，说明反激式开关变换器用于有源电力滤波器(APF)的辅助开关电源，更有利于APF对非线性问题的抑制。     

Kinetics of phenol oxidation in a trickle bed reactor over active carbon catalyst

The wet air oxidation of phenol over a commercial active carbon catalyst was studied in a trickle bed reactor (TBR) in the temperature and oxygen partial pressure ranges of 120–160 °C and 0.1–0.2 MPa, respectively. The performance of the active carbon was compared in terms of phenol and COD destruction. The weight change of active carbon due to reaction was also measured. Finally, oxic phenol adsorption isotherms were assessed in batch conditions at 25, 125 and 160 °C. In order to use the conversion data obtained from the TBR for a kinetic study, special care was taken to check the kinetic control in the TBR experiments. Several kinetic models including power law or Langmuir–Hinshelwood expressions were considered to describe the catalytic oxidation of phenol over active carbon. The simple power law model with first order dependence on both phenol and oxygen concentration predicted satisfactorily the experimental data not only over the entire range of operating conditions studied, but also outside its validity range. Copyright © 2005 Society of Chemical Industry     

光学活性物质的工业生产方法

本文介绍了光学８活性牺牲垢几种工业规模的生产方法及最新的进展，分析了各种方法的特点及存在的问题。     

环境湿度对贮存树脂的影响EI

通过对中温固化环氧树脂ＤＳＣ、扭辫分析、凝胶时间、粘度、力学性能的测定，固化反应活化能的计算，研究了在贮存树脂的过程中环境湿度对树脂的固化反应和性能的影响。     

活性炭载体的超声波处理对Pt／C催化剂活性的影响分析

通过对活性炭载体进行不同条件的超声波处理获得了具有不同表面化学性质的载体，使用比表面积（BET）、酸碱滴定等技术手段对载体的物理化学性质进行了表征。将经过超声波处理的活性炭载体制备成Pt／C催化剂，并将催化剂直接用于催化反应，考察了活性炭载体的不同超声波处理条件对Pt／C催化剂性能的影响。实验发现，活性炭载体经过超声波处理后，表面灰分含量、pH值和中孔孔容有较大的变化；使用经过60min超声波处理后中孔孔容较大的活性炭作为载体制备的Pt／C催化剂，在催化加氢反应性能测试中显示了最高的催化活性。在此基础上，就活性炭载体的超声波处理对Pt／C催化剂活性的影响进行了讨论。     

基于智能模糊控制策略的有源消声

有源消声是一种有效的低频噪声控制方法，由于空间有源消声过程具有时变性和非线性，传统的自适应算法不能进行很有效的控制。本文采用智能模糊控制策略，建立了基于智能模糊控制策略的有源消声系统，通过实验与传统自适应控制算法的消声效果作对比分析，证明智能模糊控制器不但控制速度快，易于实现，而且消声效果明显优于后者，具有较大的应用推广价值。