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91.
采用外加恒电位下腐蚀电流-温度扫描方法研究了在0.5%Cl^-溶液中,SO4^2-浓度对316不锈钢点腐蚀行为的影响.结果表明,随着SO4^2-浓度的增加,钝化电流增加,开路电位降低.当SO4^2-浓度低于0.42%时,316不锈钢的临界点蚀温度比不存在SO4^2-时的临界点蚀温度低;当SO4^2-浓度大于0.42%时,临界点蚀温度比不存在SO4^2-时的临界点蚀温度高.从离子竞争吸附的角度进行分析,对SO4^2-加速与抑制点蚀两种作用规律的形成原因进行了解释. 相似文献
92.
F.c.c. solid Co---Pd alloys have been investigated thermodynamically by means of computer-aided Knudsen cell mass spectrometry. Thermodynamic evaluation has been performed by applying the “digital intensity ratio” method. The thermodynamic excess properties can be described algebraically by means of thermodynamically adapted power series with two adjustable parameters, i.e. C1G (−20 810 + 9.608T) J mol−1) and C2G (−30 720 + 6.78T) J mol−1). At 1470 K, f.c.c. solid Co---Pd alloys are characterized by negative molar excess Gibbs energies GE, exothermic molar heats of mixing (HE) and small negative molar excess entropies SE. At 1470 K, the minimum GE value is −4600 J mol−1 (61.9 at.% Pd), the minimum HE value is −9400 J mol−1 (59.5 at.% Pd) and the minimum SE value is −3.3 J mol−1 K−1 (55.9 at.% Pd). The thermodynamic activities of Co show small positive deviations from the ideal case for the Co-rich alloys (xPd < 0.34), and negative deviations from Raoults' law for alloys with higher Pd contents. The Pd activities aPd show negative deviations from the ideal case for all compositions. The phase diagram has been computed by means of a generally applicable procedure for the calculation of the equilibrium compositions of coexisting phases. This was achieved using the results of this work, thermodynamic data from earlier mass spectrometric studies on the liquid phase, and literature data for the heat capacities and enthalpies of Co and Pd. 相似文献
93.
H. -Y. Nie M. J. Walzak N. S. McIntyre 《Journal of Materials Engineering and Performance》2004,13(4):451-460
Atomic force microscopy (AFM) uses a very sharp pointed mechanical probe to collect real-space morphological information of
solid surfaces. AFM was used in this study to image the surface morphology of a biaxially oriented polypropylene film. The
polymer film is characterized by a nanometer-scale, fiberlike network structure, which reflects the drawing process used during
the fabrication of the film. AFM was used to study polymer-surface treatment to improve wettability by exposing the polymer
to ozone with or without ultraviolet (UV) irradiation. Surface-morphology changes observed by AFM are the result of the surface
oxidation induced by the treatment. Due to the topographic features of the polymer film, the fiberlike structure has been
used to check the performance of the AFM tip. An AFM image is a mixture of the surface morphology and the shape of the AFM
tip. Therefore, it is important to check the performance of a tip to ensure that the AFM image collected reflects the true
surface features of the sample, rather than contamination on the AFM tip. 相似文献
94.
张正国 《计算机与应用化学》2015,(2):199-202
首先对提取果胶后的葵花盘进行炭化,然后用蒸馏水在800℃条件下活化,制得炭材料800SP-W。800SP-W的比表面积可以达到389.72 m~2·g~(-1)。研究了炭材料对三硝基苯酚的吸附性能,800SP-W对三硝基苯酚的吸附在140 min达到平衡,吸附量为95.57 mg·g~(-1)。三硝基苯酚在800SP-W上的吸附行为服从一级动力学模型。800SP-W对三硝基苯酚的吸附符合Langmuir和Freundlich吸附模型,为单分子层吸附。 相似文献
95.
Yasuhiro Jimbo Yuki Tamatsukuri Minato Ito Kohei Yokoyama Yoshiharu Hirakata Shunpei Yamazaki 《Journal of the Society for Information Display》2015,23(7):313-318
To improve the reliability and mechanical durability of a flexible organic light‐emitting diode display, the entire flexible display is coated with an aluminum oxide film by atomic layer deposition (ALD). Because the step coverage of ALD is excellent, the AlOx film was deposited not only on the front and back surfaces but also on the side surfaces of the display. A high‐temperature and high‐humidity preservation test, repetitive bending tests, and a pencil hardness test were conducted on the flexible display with ALD‐AlOx coating. The display survived 500 h of a 65°C, 95% preservation test, endured a 100,000‐time repetitive bending test with a curvature radius of 4 mm, and was found to have a pencil hardness of 4H. 相似文献
96.
摘要:研究以阳离子表面活性剂HDTMA改性天然斜发沸石,制得HDTMA改性沸石,进而研究HDTMA改性沸石对废水中Cr(VI)的吸附特征。结果表明:HDTMAL改性沸石对cr(VI)吸附符合Langmuir等温式和拟二级动力学方程,饱和吸附量为10.99mg/g,吸附主要为化学吸附,但温度、pH值和干扰离-~HDTMA沸石吸附cr(VI)具有明显影响。 相似文献
97.
LUO Yu ZHAO RongKuo FERNANDEZ-DOMINGUEZ Antonio I. MAIER Stefan A. PENDRY John B. 《中国科学:信息科学(英文版)》2013,56(12):1-13
Transformation optics (TO) is a new tool for controlling electromagnetic fields. In the context of metamaterial technology, it provides a direct link between a desired electromagnetic (EM) phenomenon and the material response required for its occurrence. Recently, this powerful framework has been successfully exploited to study surface plasmon assisted phenomena such as light harvesting. Here, we review the general strategy based on TO to design plasmonic devices capable of harvesting light over a broadband spectrum and achieving considerable field confinement and enhancement. The methodology starts with two-dimensional (2D) cases, such as 2D metal edges, crescent-shaped cylinders, nanowire dimers, and rough metal surfaces, and is well extended to fully-fledged three-dimensional (3D) situations. The largely analytic approach gives physical insights into the processes involved and suggests a way forward to study a wide variety of plasmonic nanostructures. 相似文献
98.
99.
This paper presents a systematic study of light interferences at single thin films. Based on Fresnel's law, we have derived generic expressions of reflectance and transmittance for film interference, as well as specific expressions for free thin films and films coated on transparent or opaque objects. By combining film interference and volume absorption, we have obtained the reflectances and transmittances of film‐coated thin objects such as ribbons. Illumination models for all interference cases of single thin films are presented, and they have been implemented and tested for various structures and materials. 相似文献
100.
随着对分析仪器的小型化、便携式需求的提高,钨丝电热原子吸收光谱仪在便携式分析仪器方面显示了很大的潜力.为进一步满足现场分析的需要,以单片机为芯片,为小型钨丝电热原子吸收光谱仪的空心阴极灯和钨丝电热原子化器设计稳定的一体化恒流电源;并编写PC机的控制软件,以USB或RS232方式与电源通信,方便控制空心阴极灯和钨丝电热原子化器电流,以及原子吸收过程.以此电路设计的小型钨丝电热原子吸收光谱仪对镉、铅、金和银的标准溶液测试结果为:检出限分别为(0.1,6.0,5.0,0.6)μg/L,相对标准偏差分别为8.2%,5.3%,6.0%和7.2%.测试结果表明:电源很稳定,达到了文献报道的钨丝电热原子吸收光谱的分析性能. 相似文献