The role of La2O3 loading in Pd/Al2O3-La2O3 prepared by sol–gel on the catalytic properties in the NO reduction with H2 was studied. The catalysts were characterized by N2 physisorption, temperature-programmed reduction, differential thermal analysis, temperature-programmed oxidation and temperature-programmed desorption of NO.
The physicochemical properties of Pd catalysts as well as the catalytic activity and selectivity are modified by La2O3 inclusion. The selectivity depends on the NO/H2 molar ratio (GHSV = 72,000 h−1) and the extent of interaction between Pd and La2O3. At NO/H2 = 0.5, the catalysts show high N2 selectivity (60–75%) at temperatures lower than 250 °C. For NO/H2 = 1, the N2 selectivity is almost 100% mainly for high temperatures, and even in the presence of 10% H2O vapor. The high N2 selectivity indicates a high capability of the catalysts to dissociate NO upon adsorption. This property is attributed to the creation of new adsorption sites through the formation of a surface PdOx phase interacting with La2O3. The formation of this phase is favored by the spreading of PdO promoted by La2O3. DTA shows that the phase transformation takes place at temperatures of 280–350 °C, while TPO indicates that this phase transformation is related to the oxidation process of PdO: in the case of Pd/Al2O3 the O2 uptake is consistent with the oxidation of PdO to PdO2, and when La2O3 is present the O2 uptake exceeds that amount (1.5 times). La2O3 in Pd catalysts promotes also the oxidation of Pd and dissociative adsorption of NO mainly at low temperatures (<250 °C) favoring the formation of N2. 相似文献
This paper discusses optimal binary codes and pure binary quantum codes created using Steane construction. First, a local search algorithm for a special subclass of quasi-cyclic codes is proposed, then five binary quasi-cyclic codes are built. Second, three classical construction methods are generalized for new codes from old such that they are suitable for constructing binary self-orthogonal codes, and 62 binary codes and six subcode chains of obtained self-orthogonal codes are designed. Third, six pure binary quantum codes are constructed from the code pairs obtained through Steane construction. There are 66 good binary codes that include 12 optimal linear codes, 45 known optimal linear codes, and nine known optimal self-orthogonal codes. The six pure binary quantum codes all achieve the performance of their additive counterparts constructed by quaternary construction and thus are known optimal codes. 相似文献
A novel network model of multiple source fountain coding is developed and a novel class of generic multiple source fountain codes with unequal error protection(UEP)property is proposed.The And–Or tree analysis technique is generalized to analyze the asymptotic performance of the proposed codes and a joint optimization method employing both linear and nonlinear programs is developed to optimize the degree distributions.Furthermore,we propose three basic methods to achieve UEP property and the performance of each method is discussed.We employ these analytical results and optimization method to design and discuss several UEP codes with two and four sources for different application scenarios.Simulation results verify that the proposed codes can be applied to the networks with any number of sources and can provide strong UEP property in various ways based on the proposed three basic methods. 相似文献
The paper reports experimental results for the viscosity of the vapor mixtures methanol-benzene (five mole fractions with densities up to 1.5kg·m–3 and 0.022 mol·L–1) and methanol-cyclohexane (four mole fractions with densities up to 1.9kg·m–3 and 0.026 mol·L–1). In analogy to the pure components, the measurements on the mixtures were carried out with an oscillating-disk viscometer with small gaps, completely made of quartz, beginning as near as possible to room temperature and continuing to a maximum temperature of 630 K. A first evaluation by means of the Chapman-Enskog theory of dilute gases has shown differences in the resulting values of the interaction viscosity
ij(0) in the limit of zero density exceeding the experimental errors. Consistent results were obtained by taking into account the initial density dependence of the viscosity within the framework of the modified Enskog theory for gaseous mixtures. The values of
ij(0) were also used to estimate binary diffusion coefficients of the mixtures. 相似文献
Viscosities for six binary mixtures of n-butylamine, di-n-butylamine, tri-n-butylamine, n-octylamine, di-n-octylamine, and tri-n-octylamine with cyclohexane have been measured at 303.15 K with an Ubbelohde suspendedlevel viscometer. Deviations of viscosities from a rectilinear dependence on mole fraction are attributed to H-bonding and to the size of alkylamine compounds. The application of the Eyring's theory of activation energy is examined. The free volume theory of Prigogine-Flory-Patterson (PFP) and the experimental excess enthalpy have been used to estimate excess viscosity ln = (ln /
10
– x2 ln
20
/
10
) and corresponding free volume, enthalpy, and entropy contributions for five binary mixtures of tri-n-alkylamine: triethyl, tripropyl, tributyl, trihexyl, and trioctylamine with cyclohexane. A comparison of experimental and theoretical excess viscosities indicates a failure of the PFP theory when two components of the mixture differ considerably in size. The size difference contribution to excess viscosity is related to (V2*1/2
– V1*1/2
), where V1*
and V2*
are hard-core volumes of two components of the mixture. 相似文献