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排序方式: 共有335条查询结果,搜索用时 15 毫秒
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Jos J. M. Lenders Harshal R. Zope Ayana Yamagishi Paul H. H. Bomans Atsushi Arakaki Alexander Kros Gijsbertus de With Nico A. J. M. Sommerdijk 《Advanced functional materials》2015,25(5):711-719
Control over magnetite (Fe3O4) formation is difficult to achieve in synthetic systems without using non‐aqueous media and high temperatures. In contrast, Nature employs often intrinsically disordered proteins to tightly tailor the size, shape, purity, and organization of the nanocrystals to optimize their magnetic properties. Inspired by such “flexible polyelectrolytes,” here random copolypeptides having different amino acid compositions are used as control agents in the bioinspired coprecipitation of magnetite through a ferrihydrite precursor, following a recently developed mineralization protocol. Importantly, the copolypeptide library is designed such that the amino acid composition can be optimized to simultaneously direct the size of the nanoparticles as well as their dispersibility in aqueous media in a one‐pot manner. Acidic amino acids are demonstrated to regulate the crystal size by delaying nucleation and reducing growth. Their relative content thus can be balanced to tune between the superparamagnetic and ferrimagnetic regimes, and high contents of negatively charged amino acids result in colloidal stabilization of superparamagnetic nanoparticles at high pH. Conversely, with positively charged lysine‐rich copolypeptides ferrimagnetic crystals are obtained which are stabilized at neutral pH and self‐organize in chains, as visualized by cryo‐transmission electron microscopy. Altogether, the presented findings give important insights for the future development of additive‐mediated nanomaterial syntheses. 相似文献
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仿生型壳聚糖-明胶/溶胶凝胶生物玻璃复合支架的制备及其矿化性能研究 总被引:2,自引:0,他引:2
利用冷冻干燥法制备出用于骨和软骨组织工程的壳聚糖-明胶/溶胶凝胶生物玻璃(CS-Gel/SGBG)仿生型复合多孔支架,并进行了孔隙率的测定和显微形貌的观察;探讨了各组分不同用量对CS-Gel/SGBG复合支架显微结构的影响以及复合支架在模拟生理体液中的仿生矿化性能。研究表明,通过调节各组分的不同用量,可以制备出三维连通的复合多孔支架,且孔隙率达到90%以上;在模拟生理体液中浸泡后发现CS-Gel/SGBG支架表面有大量结晶态类骨碳酸羟基磷灰石生成,表明复合支架有良好的生物矿化性能。 相似文献
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微生物矿化技术作为一个新兴研究课题,近些年来得到了广泛关注,然而因其反应机制复杂,很难从时间和空间尺度对矿化反应过程进行定量表示。在微生物诱导碳酸盐沉淀原理的基础上,考虑细菌的吸附和筛滤效应,以及尿素水解动力学和沉淀动力学模型,对微生物矿化反应动力学理论进行了探究,并结合孔隙尺度下的微生物矿化反应试验,采用有限元软件进行多物理场耦合模拟。结果表明,细菌吸附和筛滤行为引起了细菌分布的差异性,而这种差异性进而影响了碳酸钙的沉积分布;溶液汇合初始段碳酸钙生成量横向分布不均匀,纵向分布呈增长趋势;经历40h的反应时间,渗透率可降低80%左右;当钙离子含量丰富时,碳酸钙沉淀速率受限于尿素水解速率;附着细菌量和沉淀速率的叠加效应表现为细菌被沉淀包裹的衰亡速率。本模型验证了微生物矿化沉积反应过程,丰富了微生物矿化反应理论,并有望为现场工程应用的效果预测提供参考。 相似文献
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The Tunable Porous Structure of Gelatin–Bioglass Nanocomposite Scaffolds for Bone Tissue Engineering Applications: Physicochemical,Mechanical, and In Vitro Properties 下载免费PDF全文
Unidirectional freeze‐casting method is used to fabricate gelatin–bioglass nanoparticles (BGNPs) scaffolds. Transmission electron microscopy (TEM) images show that sol–gel prepared BGNPs are distributed throughout the scaffold with diameters of less than 10 nm. Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetric are used to evaluate the physicochemical properties of BGNPs. Scanning electron microscopy (SEM) micrographs present an oriented porous structure and a homogeneous distribution of BGNPs in the gelatin matrix. The lamellar‐type structure indicates an improvement of mechanical strength and absorption capacity of the scaffolds. Increasing the concentration of BGNPs from 0 to 50 wt% have no noticeable effect on pore orientation, but decreases porosity and pore size distribution. Increase in BGNPs content improves the compressive strength. The absorption and biodegradation rate reduces with augmentation in BGNPs concentration. Bioactivity is evaluated through apatite formation after immersion of the nanocomposites in simulated body fluid and is verified by SEM–energy‐dispersive X‐ray spectroscopy (EDS), an element map analysis, X‐ray powder diffractometer, and FTIR spectrum. SEM images and methyl thiazolyl tetrazolium assay confirm the biocompatibility of scaffolds and the supportive behavior of nanocomposites in cellular spreading. The results show that gelatin–(30 wt%)bioglass nanocomposites have incipient physicochemical and biological properties. 相似文献
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