纤维与水泥基体黏结性能及影响因素研究北大核心CSCD

纤维混凝土的韧性来源于纤维的桥接作用,而桥接作用的核心问题是纤维与水泥基体的黏结性能。为了探究纤维对混凝土的增韧机理,本文开展了不同养护龄期(0~28 d)、拔出速率(1~30 mm/min)、纤维锚固长度(10~60 mm)以及粉煤灰掺量(0~30%)下聚丙烯纤维水泥基砂浆的单根纤维拔出试验(single fiber pull-out test,SFPT),基于能量耗散原理和试验数据,建立了聚丙烯纤维水泥基砂浆韧性指数与纤维拔出过程中吸能指数的数学关系,提出了基于广义灰色关联理论的界面黏结强度影响因素计算分析方法。研究结果表明:随着养护龄期、拔出速率和纤维锚固长度的增加,聚丙烯纤维水泥基体界面黏结强度均逐渐增大,但纤维的韧性指数在养护18 h时较佳,拔出速率6 mm/min、锚固长度20 mm时最佳。当粉煤灰掺量为20%左右,纤维-水泥基体界面黏结性能最佳。并基于广义灰色关联分析法,阐明了四种因素与界面黏结强度的数学关联,研究成果可以为纤维水泥基砂浆的设计与应用提供理论支撑。     

An exact Peano Series solution for bending analysis of imperfect layered functionally graded neutral magneto-electro-elastic plates resting on elastic foundations

In this article, a three-dimensional solution is presented for the bending analysis of functionally graded and layered neutral magneto-electro-elastic plates resting on two-parameter elastic foundations, considering imperfect interfacial bonding. The equations of motion, Gauss's equations for electrostatics and magnetostatics, and boundary and interface conditions are satisfied exactly regardless of the number of layers. No assumptions on deformations, stresses, and magnetic and electric fields along the thickness direction are introduced. The interfacial imperfection is modeled using a generalized spring layer. The state-space method is employed for solving the governing partial differential equations. Effects of a two-parameter elastic foundation, gradient index, bonding imperfection, and applied mechanical and electrical loads on the response of the functionally graded magneto-electro-elastic plate are discussed. The obtained exact solution can serve as a benchmark for assessing the accuracy of layered functionally graded magneto-electro-elastic plate theories.     

Sandwiched Thin‐Film Anode of Chemically Bonded Black Phosphorus/Graphene Hybrid for Lithium‐Ion Battery

A facile vacuum filtration method is applied for the first time to construct sandwich‐structure anode. Two layers of graphene stacks sandwich a composite of black phosphorus (BP), which not only protect BP from quickly degenerating but also serve as current collector instead of copper foil. The BP composite, reduced graphene oxide coated on BP via chemical bonding, is simply synthesized by solvothermal reaction at 140 °C. The sandwiched film anode used for lithium‐ion battery exhibits reversible capacities of 1401 mAh g^?1 during the 200th cycle at current density of 100 mA g^?1 indicating superior cycle performance. Besides, this facile vacuum filtration method may also be available for other anode material with well dispersion in N‐methyl pyrrolidone (NMP).     

Ti合金插层厚度对反应连接TiB_2基陶瓷/Ti-6Al-4V梯度复合材料的影响

将Ti合金插层引入(Ti+B_4C)反应原料和Ti合金底板之间,研究Ti合金插层厚度变化对超重力反应连接TiB2基陶瓷/Ti-6Al-4V梯度复合材料界面显微组织与力学性能的影响。热力学计算表明:合成反应的绝热温度远超Ti合金的熔点,可以保证不同厚度的Ti合金插层全部熔化。XRD、FESEM及EDS分析结果表明:在陶瓷和Ti合金底板之间形成梯度界面区,且随着Ti合金插层厚度的增加,梯度界面区的厚度也不断增大。自陶瓷基体至Ti合金底板,TiB_2和TiC_(1-x)的体积分数不断减少,而TiB的体积分数先增加而后减少,最终形成以TiB_2、TiC_(1-x)及TiB陶瓷相尺寸和分布为特征的梯度复合结构。而梯度连接区的硬度分布趋势更加平缓,其剪切强度不断提升。     

单向拉伸条件下补片参数对复合材料胶接修复结构的影响

建立含中心半穿透圆孔的损伤金属板修补结构的三维有限元模型,以应力集中系数(Stress Concentration Factor,SCF)和挠度w作为复合材料胶接修复效果的指标,分析单向拉伸条件下,正方形补片的长度、厚度和铺层方式对修复效果的影响。结果表明:补片长度取孔直径的3.5倍、厚度取孔深度的0.6~0.8倍、铺层方式取0°/90°铺层时,复合材料单面修复含损伤裂纹板的效果较好。根据分析结果制备了实验件,进行了单向静拉伸实验,修补实验件的破坏强度比未修补实验件提高了10.1%。     

Ti/Nb作中间层脉冲加压扩散连接TiC金属陶瓷与不锈钢

用Ti/Nb作中间层,在温度890℃、时间4~12min、脉冲压力2~10MPa、频率f=0.5Hz、恒压10MPa下,对TiC金属陶瓷和304不锈钢(304SS)进行脉冲加压与恒压扩散焊,获得了牢固的固相扩散焊接头。通过扫描电镜SEM、能谱EDS、X射线衍射XRD与剪切性能测试,对接头的显微组织、界面产物与强度进行分析。结果显示:两种接头的界面物相相似,主要有σ相,(β-Ti,Nb)与α+β-Ti固溶体。连接时间10min时,恒压下的TiC/304SS接头抗剪强度为55.6MPa,而脉冲加压下的接头抗剪强度达110MPa。恒压下接头断裂方式为TiC陶瓷断裂,而脉冲压力下接头断裂方式为TiC陶瓷与界面产物间交替进行的混合断裂。     

HARDOX 500/Q235B耐磨复合材料爆炸焊接试验研究

采用以Q235B为复层、以线状结合界面为微观判据设计爆炸焊接工艺,实现了HARDOX 500/Q235B耐磨复合材料的良好结合,结合性能和应用性能测试结果满足设计要求;金相观测结果表明,绝热剪切带是HARDOX 500复合材料产生宏观脆裂的内在原因。     

环氧胶粘剂及其胶接界面热氧老化机理研究

采用红外光谱、X射线光电子能谱和扫描电镜对环氧胶粘剂的热氧老化机理进行了研究。同时,对环氧胶接结构进行了力学性能分析,研究了热氧环境对其力学性能退化的影响。结果表明,环氧胶粘剂在热氧加速老化中发生的化学反应主要有后固化反应和氧化反应。热氧老化过程中,环氧胶中的羟基被氧化为醛基化合物,亚甲基被氧化为酰胺。热氧加速老化后的力学性能表明,环氧胶材料本体的耐老化性能好,界面粘接强度具有较好的稳定性。     

泡沫铝连接件焊接工艺的应用现状与展望

泡沫铝兼具结构与功能特性,为充分发挥泡沫铝的各种性能,常将其与致密金属进行复合得到三明治结构,以提高其综合力学性能并降低成本。三明治结构的连接方法众多,而焊接手段是最可靠的连接方式。首先介绍了泡沫铝的性能特点及焊接难点,综述了其焊接方法,包括常规电弧焊、激光焊、钎焊、扩散焊、搅拌摩擦焊、等离子焊以及超声波焊,再对各工艺的局限性进行阐述,最后对泡沫铝连接件焊接工艺的发展方向进行浅析。     

Challenges of Diffusion Bonding of Different Classes of Stainless Steels

Solid state diffusion bonding is used to produce monolithic parts exhibiting mechanical properties comparable to those of the bulk material. This requires diffusion of atoms across mating surfaces at high temperatures, accompanied by grain growth. In case of steel, polymorphy helps to limit the grain size, since the microstructure is transformed twice. The diffusion coefficient differs extremely for ferritic and austenitic phases. Alloying elements may shift or suppress phase transformation until the melting range. In this paper, diffusion bonding experiments are reported for austenitic, ferritic, and martensitic stainless steels possessing varying alloying elements and contents. Passivation layers of different compositions are formed, thus affecting the local diffusion coefficient and impeding diffusion across faying surfaces. As a consequence, different bonding temperatures are needed to obtain good bonding results, making it difficult to control the deformation of parts, since strong nonlinearities exist between temperature, bonding time, and bearing pressure. For martensitic stainless steel, it is shown that it is very easy to obtain good bonding results at low deformation, whereas ferritic and austenitic stainless steels require much more extreme bonding parameters.