LF6铝合金的超塑性／扩散连接组合工艺试验及理论研究EI

本文研究了ＬＦ６铝合金的超塑性／扩散连接组合工艺，用变形和再结晶的方法细化晶粒，成功地进行了ＳＰＦ／ＤＢ工艺试验，利用电子探针观察了扩散连接接头的界面微观区域，并从机理上分析了金属的超塑性／扩散连接两种工艺之间的内部联系及其金属学行为。     

WC/Ni60真空熔烧涂层的组织结构特性

研究了真空熔烧WC Ni60复合涂层的显微组织结构特性 ,并测定了沿层深方向的显微硬度分布。研究结果表明 ,涂层与母材 4 5钢在界面处形成牢固的冶金结合 ,界面两侧的显微硬度呈连续性分布     

砌筑砂浆达不到设计要求的事故原因分析

从砂浆的配合比、和易性、原材料等对砌筑砂浆达不到设计要求的事故原因进行了分析。     

Study of miscibility enhancement in poly(styrene‐co‐4‐vinylphenol)/poly(ethylene oxide) blends by the spin labelling method

The electron spin resonance (ESR) spectra of end‐group spin labelled poly(ethylene oxide) (SLPEO) using 2,2,6,6‐tetramethyl‐piperdine‐1‐oxyl nitroxide and its blends with poly(styrene‐co‐4‐vinylphenol) (STVPhs) of different hydroxyl contents were recorded over a wide temperature range. For a blend of SLPEO and pure polystyrene (PS), the ESR spectrum was composed of a single motion component, indicating that PS was immiscible with PEO. For blends composed of SLPEO and different‐hydroxyl‐content STVPhs, two spectral components with different motion rates were observed over a certain temperature range. The difference between the motion rates should be attributed to micro‐heterogeneity in the blends, with the faster rate corresponding to a nitroxide radical motion trapped in the PEO‐rich domain and the slower rate corresponding to a nitroxide radical motion trapped in the STVPh‐rich domain. Variations in the values of a number of the ESR parameters (T_a, T_d and T_50G) and the apparent activation energy (E_a) with hydroxyl content in the blends indicated that the miscibility of the blends increased with increasing hydrogen‐bonding density due to specific interactions between the hydroxyl groups in STVPh and the ether oxygens in PEO. Copyright © 2004 Society of Chemical Industry     

基于PTFE的PCB的多层层压方法

介绍了采用不同材料类型的粘结膜、半固化片、所需设备和粘结材料,用于生产低到高层数的PTFE多层板的情况。     

劈刀和肋环夹持工况对超声键合换能系统电学特性的影响

通过实验分析了肋环夹持松紧度和劈刀存在两个因素对超声键合换能系统电学导纳特性的影响规律。对换能系统在悬挂有无劈刀和夹持8个松紧度等各个情况下进行谐振频率附近的导纳圆测量,确定换能系统等效电路各特征参数的变化情况。由实验结果的分析可知,劈刀的附加质量以及肋环松紧程度对换能系统谐振频率的影响不大,但劈刀的存在改变了换能系统的能量分布和耗散,是影响换能系统各特征参量的主要因素之一。这些结论有助于超声键合换能系统的优化。     

硬质合金与铁基复合材料热等静压扩散连接

以烧结结态硬质合金和粉末态铁基复合材料为连接对象，研究了两种材料的热等静压扩攻连接工艺，获得了直接连接接头和加镍作中间过渡层的间接连接接头，考察了接头的结合界面形貌，界面的元素扩散和界面结合强度。     

转炉溅渣层与镁碳砖炉衬的结合机理

通过对生产现场带有溅渣层的转炉炉衬残砖和试验室小型坩埚溅渣试验结果进行矿相显微结构分析、研究，确定了溅渣层的矿相组成、溅渣层与ＭｇＯ－Ｃ砖结合区域的矿相结构及坩埚溅渣层自上而下的矿相分布规律，并根据矿相结构分析中观察到的烧结层、结合层和溅渣层３个区域，提出了溅渣层与镁碳砖炉衬的结合机理为化学结合、机械镶嵌与化学烧结结合及冷凝结合３种形式。     

In Situ FTIR Study of the Formation of an Organosilane Layer at the Silica/Solution Interface

An FTIR experiment especially designed to study the growth of an organosilane layer at the interface between a solution and a flat silica surface is presented. High sensitivity is achieved by using the attenuated total reflection (ATR) technique in a liquid flow cell. The ATR crystal, either silicon or germanium, is covered with a very thin silica layer. Chemical reactions of a mono-and a di-hydrolyzable silane with the silica substrate have been investigated. The grafting of a submonolayer of the first reagent has been monitored by following the C-H and SiO-H vibrations. The density of grafted molecules has been estimated and information on the nature of the chemical bonding has been achieved. Evidence for the chain-polymerization of the dihydrolyzable silane at the substrate/solution interface has been inferred from the appearance of a Si-O-Si absorption band.