Study of SO2 adsorption and thermal regeneration over activated carbon-supported copper oxide catalysts

The mechanisms of SO₂ adsorption and regeneration over activated carbon-supported copper oxide sorbent/catalysts were analyzed. Studies were carried out in a fixed-bed reactor equipped with a non-dispersive infrared gas analyzer to detect the reaction products and by using X-ray powder diffraction (XRPD) and temperature-programmed desorption (TPD) experiments to characterize the nature of the sulfate species and surface oxygen complexes. The results indicate that SO₂ was catalytically oxidized to SO₃ over a copper phase in the presence of gaseous oxygen, and then reacted with a copper site to form a sulfate linked to copper without desorption into the gas phase. The activated carbon support did not participate in this sulfation reaction. After the adsorption of SO₂, the exhausted sorbent/catalysts could be regenerated by direct heat treatment in inert gas at temperatures between 260 and 480 °C, while the neighboring surface oxygen complexes on the carbon surface were acting as the reducing agents to reduce CuSO₄ to Cu. During the subsequent adsorption process, the copper is rapidly oxidized by oxygen in the flue gas.     

Foam processing of poly(ethylene-co-vinyl acetate) rubber using supercritical carbon dioxide

Soft rubber foams like poly(ethylene-co-vinyl acetate) (EVA) are industrially applied in a broad range of products, including sports gear, insulation materials and drug delivery systems. In contrast to glassy polymers, few studies in literature concern the foaming of soft rubbers using supercritical carbon dioxide. In this study, open microporous matrices of EVA have been formed with CO₂. Prior to the foam expansion, sorption and swelling isotherms of CO₂ in EVA have been measured and the obtained isotherms have been correlated using the Sanchez-Lacombe equation of state. Additionally, a pressure-independent diffusion coefficient of CO₂ in EVA has been obtained from these experiments. The microporous foams have been formed by a pressure quench of the CO₂-swollen polymer matrix. Sorption pressure as well as temperature and decompression times appear to determine the pore size and bulk density of the foam. These parameters allow for a control of the foam structure of EVA rubbers.     

轮胎胎面胶耐磨性能研究

选择NR ,SBR和BR以及炭黑N3 3 9,N2 3 4,N2 2 0和N110等构成的体系 ,对胎面胶在不同压力、磨耗角度及磨耗里程下的耐磨性能进行了研究。结果表明 ,当NR/BR并用比为 70 / 3 0、炭黑N2 3 4/N110并用比为 40 / 12时 ,胎面胶的耐磨性能最佳。     

超轻型无人机光电侦察平台升降机构设计

为了解决搭载光电平台的无人机在飞行时受的阻力影响以及如何提高无人机的续航能力,增加无人机的飞行时间,针对此问题,设计了一种结构简单的无人机载光电侦察平台升降机构。光电平台工作时,通过升降机构伸出机外;光电平台停止工作时,收入机内,从而解决阻力的影响,另一方面,通过采用减轻升降机构重量,从而提高续航能力。升降机构采用碳纤维铝蜂窝夹层复合材料作为支撑板的主体材料,同以前应用的铝合金材料相比较,重量减轻4.5kg。经过多架次外场飞行试验,取得了良好效果,无人机续航能力有所加强。     

炭纤维载体表面快速固着机理研究

采用炭纤维作为生物膜载体材料进行了污水处理实验,对炭纤维载体表面快速固着机理进行了研究。研究发现,炭纤维能够在水中快速且大量的固着活性污泥微生物。采用表面积测定仪、扫描电镜和XPS研究了炭纤维的表面特征。结果显示,炭纤维的表面形貌、表面官能团及表面活性碳原子是影响炭纤维表面微生物快速且大量固着的主要因素。     

Influence of Zn ion implantation on structures and field emission properties of multi-walled carbon nanotube arrays

The structures and field emission properties of multi-walled carbon nanotube arrays implanted with Zn+ by MEVVA ion implanter have been investigated.The results revealed that Zn+implantation induced structural damage and that the top of carbon nanotubes with multi-layered graphite structure were transformed into carbon nanowires with amorphous structure.Meanwhile,C:Zn solid solution was synthesized after Zn+ implantation.The turn-on field and threshold field were 0.80 and 1.31 V/μm,respectively for original...     

隧道聚丙烯纤维混凝土抗渗性能分析及试验比较

作为一种新型隧道防水衬砌材料,聚丙烯纤维混凝土的抗渗研究大多还仅局限于抗渗机理的定性解释上。为进一步揭示其抗渗性能,结合断裂力学原理和细观结构的力学分析,推导出了混凝土内部裂纹处的纤维闭合力及其应力强度因子,提出了纤维对张开型裂纹扩展的阻碍效应解析式,并在此基础上,通过数值计算,对聚丙烯纤维混凝土的抗渗性能给出了合理解释;另一方面,为将其与传统的微膨胀混凝土的抗渗性能进行比较,开展了4组不同类型混凝土的抗渗性能试验,通过比较发现,工程中常用掺量的聚丙烯纤维混凝土的抗渗性能优于微膨胀混凝土,而合理双掺（聚丙烯纤维和微膨胀剂）可使混凝土的抗渗性能达到最佳。     

Coolplus吸湿排汗超薄针织物的开发

为解决Coolplus在纯纺针织物编织、染色过程中容易出现的问题.依据Coolplus纤维的性能和特点,结合生产实践探讨了纯Coolplus纤维单面提花针织物的织造及染整工艺,并且给出了具体生产工艺以及常用的染料、助剂的选择方法.     

装配式预应力空心板桥面混凝土铺装层病害及防治

针对影响桥梁使用和维修保养的桥面铺装层问题,研究分析了装配式预应力混凝土空心板桥面混凝土铺装层的纵桥向裂缝、横桥向裂缝、龟裂、松散剥落及伸缩缝处破坏等常见病害的产生机理,提出了相应的设计与施工措施.概括总结了钢纤维混凝土、合成纤维混凝土、混杂纤维混凝土和钢纤维轻混凝土在桥面铺装层中的研究成果,列举了几个需要进一步深入研究的课题.     

填充玻璃纤维滤膜基钛酸锶钡的手控注射式富集器对水中锌的富集性能

以多孔玻璃纤维滤膜基钛酸锶钡（BBST）为吸附材料,制备了手控注射式富集器;考察了该富集器对水中Zn2＋的吸附富集性能.结果表明：当介质的pH值为3-7时,多孔玻璃纤维滤膜基钛酸锶钡对水中的Zn2＋具有很强吸附能力,其静态吸附容量为24.30 mg/g;制备的富集器可实现对Zn2＋的动态吸附,被吸附的Zn2＋可用2.0%的EDTA溶液动态洗脱回收,其浓集因子可达500.提出了手控注射式钛酸锶钡富集器富集,火焰原子吸收光谱法测定水中痕量Zn2＋的新方法.方法检出限为0.09μg/L.应用于一次蒸馏水和纯净水中痕量Zn2＋的富集,用火焰原子吸收法测定,回收率为93.0%-102.0%.