Adsorption of H2S or SO2 on an activated carbon cloth modified by ammonia treatment

The aim of this research is to investigate how ammonia treatment of the surface can influence the activity of a viscose-based activated carbon cloth (ACC) for the oxidative retention of H₂S and SO₂ in humid air at 25 °C. Surface basic nitrogen groups were introduced either by treatment with ammonia/air at 300 °C or with ammonia/steam at 800 °C. The pore structure of the samples so prepared was examined by adsorption measurements. Changes in the surface chemistry were assessed by X-ray photoelectron spectroscopy, X-ray absorption spectroscopy and temperature programmed desorption (TPD). The change of ACC activity could not be merely attributed to surface nitrogen groups but to other changes in the support. Ammonia/steam treatment improved ACC performance the most, not only by introducing nitrogen surface groups, but also by extending the microporosity and by modifying the distribution of surface oxygen groups. Successive adsorption-regeneration cycles showed important differences between oxidative retention of H₂S and SO₂ and the subsequent catalyst/support regeneration process.     

Effect of Substrate Bias on Microstructure and Properties of Tetrahedral Amorphous Carbon Films

The microstructure and properties of tetrahedral amorphous carbon (ta-C) films deposited by the filtered cathodic vacuum arc technology has been investigated by visible Raman spectroscopy, AFM and Nano-indentor. The Raman spectra have been fitted with a s     

纳米材料的力学性能

综述了纳米晶体材料和纳米碳管材料的力学性能研究的最新进展。实验数据表明纳米晶体材料的强度与其晶粒尺寸大小的关系并不遵循Hall-Petch方程。相对于常规晶体材料 ,纳米材料的超塑性发生在更低的温度和更高的应变速率下。理论计算和实验数据表明 :纳米碳管是一种有着高刚性、高强度、高韧性和低密度的材料。纳米晶体材料和纳米碳管的异常的力学性能已经有了一些应用实例     

含氮杂环季铵盐缓蚀剂在CO2-3%NaCl溶液体系中的电化学行为

为控制CO2腐蚀，合成了含氮杂环季铵盐缓蚀剂9912-1，通过电化学实验，研究了该缓蚀剂在CO2-3％NaCl-H2O体系中对碳钢于25℃和90℃下的缓蚀行为。实验结果与挂片失重法测试的结果基本一致。低温下缓蚀效果优于高温下的缓蚀效果。而且该缓蚀剂与硫脲有很好的协同效应。Tafel曲线表明，该缓蚀过程是以控制阴极腐蚀为主，并对其缓蚀机理进行了初步探讨。     

膜-粉末炭反应器净化微污染源水

采用膜-粉末炭反应器处理微污染源水的试验结果表明,该工艺对水中的有机物具有较好的净化效果,在水温《10℃的条件下,处理可生化性很低的三家店水库水时对CODMn的去除率仍保持在65%左右;工艺对CODMn、UV254、UV410的去除效果依次增强.     

Hierarchical Self‐Assembly of Peptide‐Coated Carbon Nanotubes

Numerous applications, from molecular electronics to super‐strong composites, have been suggested for carbon nanotubes. Despite this promise, difficulty in assembling raw carbon nanotubes into functional structures is a deterrent for applications. In contrast, biological materials have evolved to self‐assemble, and the lessons of their self‐assembly can be applied to synthetic materials such as carbon nanotubes. Here we show that single‐walled carbon nanotubes, coated with a designed amphiphilic peptide, can be assembled into ordered hierarchical structures. This novel methodology offers a new route for controlling the physical properties of nanotube systems at all length scales from the nano‐ to the macroscale. Moreover, this technique is not limited to assembling carbon nanotubes, and could be modified to serve as a general procedure for controllably assembling other nanostructures into functional materials.     

活性炭的制备及应用新进展

综述了活性炭材料研究开发的新进展。重点介绍了煤、石油焦、沥青基活性炭的制备方法及针对不同用途的活性炭改性技术，为选择合适的活化方法和制备特殊功能的改性活性炭提供了参考。     

油气田开发中的CO2腐蚀及防护技术

综述了二氧化碳均匀腐蚀和局部腐蚀的机理，分析了二氧化碳腐蚀的各种影响因素，并对二氧化碳腐蚀的防护技术进行了概括，着重介绍了缓蚀剂防护技术研究进展，并提出了研究CO2腐蚀及其缓蚀剂应注意的几个问题。