Synthesis and characterization of liquid crystalline polymers containing aromatic ester mesogen and a nonmesogenic ferrocene unit in the spacer

A new series of liquid crystalline polymers containing aromatic triad ester mesogen and 1,1′‐disubstituted ferrocene as a nonmesogenic unit along with polymethylene spacer was synthesized. The polymer was synthesized by a room temperature polycondensation reaction between bis(4‐chloroformyl phenyloxy alkyl ferrocene dicarboxylate) and quinol. The alkyl groups have been varied by an even number of methylene groups with a range from two to ten groups. All the polymers were found to possess liquid crystalline properties. The identification of the mesophase is more transparent with an increase in the spacer. The thermal characteristics were studied using thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results reveal that the thermal stability of the polymers was decreased with increasing spacer length. The T_g, T_m, and T_i of the polymers decreased with increasing methylene groups. The incorporation of the ferrocene moiety also has a considerable effect on the glass transition temperature. The char yield of the polymer decreases with an increasing methylene chain length. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3494–3501, 2002     

Semiochemicals and Social Signaling in the Wild European Rabbit in Australia: I. Scent Profiles of Chin Gland Secretion from the Field

The European rabbit (Oryctolagus cuniculus) uses the secretion of the chin gland in the maintenance of social status. Previous work has concentrated on secretion collected directly from the animal. In this study, the analysis was conducted by collecting scent marks made by free-ranging animals. Scent marks were found to be concentrated at the center of the area controlled by a social group, and at the boundaries between two adjacent social groups. Only the mark from dominant animals could be identified. Marks were also collected from the skin of rabbits, where they had been placed by the dominant individual. The mark found on the head of a subordinate animal may, in the future, be used to identify the dominant animal of the social group, who placed the mark.     

CNONIX标准符合性测试研究

CNONIX标准规范了图书出版行业在信息交互过程中的数据项及其格式,提高了数据质量和使用效率。为了保证第三方软件能够正确地生成符合CNONIX标准的XML文件以及检测一个XML文件是否符合CNONIX标准,提出了相关的标准符合性测试方法;对CNONIX标准中规定的元素属性进行了研究并且分析了其对测试用例的影响;设计了XML文件对于CNONIX标准符合性的检测规则;最后提供了一个应用实例对检测规则予以说明。     

基于ASL的模型驱动架构测试方法

针对模型驱动架构（MDA）下的软件开发方法中测试启动比较晚、难以发现隐藏在模型中的缺陷及UML模型描述缺乏精确语义等问题,提出了基于ASL的模型测试方法：从UML模型出发,将动作规约语言（ASL）运用于平台无关模型（PIM）上建立测试模型。给出了ASL语句在MDA过程中的工作原理、平台无关模型的建立过程、测试用例建立的步骤、测试执行的实施过程,最后结合实例,在UML图的基础上运用ASL对测试环境进行构建,并创建了系统的测试用例,对模型及业务逻辑进行了测试。实验结果表明,提出的基于ASL的模型测试方法既能利用模型驱动对复杂的测试用例进行简化和抽象,又能在软件生存期早期揭示软件的缺陷,防止缺陷随着软件开发过程的进行而被放大。     

Synthesis and Polymerization of Cationic bis(cyclopentadienyliron)arene Complexes Containing Arylazo Dyes

The synthesis of the title complexes was achieved via the reaction of -p-dichlorobenzene- -cyclopentadienyliron cations with 4,4′-bis(4-hydroxyphenyl)valeric acid to produce the diiron complexes which were then reacted with a number of arylazo dyes to give cationic bis(cyclopentadienyliron)arene complexes containing the arylazo dyes. These iron-containing monomers were subsequently polymerized via nucleophilic aromatic substitution using 1,8-octanedithiol, 4,4′-thiobisbenzenethiol, or bisphenol A to produce the desired coloured cationic organoiron polymers. The weight – average molecular weights were estimated to range from 11,800 to 31,600. UV–vis studies conducted in dimethylformamide (DMF) showed that the metallated polymers exhibited of 412–491 nm. Addition of HCl to the polymer solution caused a bathochromic shift into the range of 515–530 nm. Thermogravimetric analysis (TGA) revealed that the iron moieties were cleaved between 205 and 248 °C while the polyether/thioether backbone degraded between 380 and 613 °C. Differential scanning calorimetry (DSC) showed that the polymers exhibited glass transition temperatures (Tg) ranging from 106 to 184°C.This paper is dedicated to Professor Richard J. Puddephatt in recognition of his outstanding contribution to the field of metal-containing polymers.     

纳米管合成研究进展

当今纳米科学技术飞速发展，其中纳米管已构成了纳米材料的一个非常重要的类别。本文介绍近几年来由化学键结合的纳米管以及由分子间力形成的一些纳米或具有中观尺度的管状结构材料的合成研究进展。     

基于“CDIO”的“1+2”新教学模式研究

“CDIO”教学是将工程思维训练融合在教学各个环节当中,本文采用“CDIO”与“案例教学、启发教学”进行融合,组合成为一个新的“1+2”教学模式,以医学信息工程学院课程作为应用载体,将传统教学升华到工程思维教学、团队教学上,转变教师授课形式,激励和引导学生自主学习,为学生提供思维的空间和意境,帮助学生在学习时发现问题,发现、解决值得解决的问题,掌握计算在问题解决过程中发挥的作用,获得构建自身学科知识体系,终身自我学习的能力,滋生创新能力,达到学科知识与工程思维能力互相促进,共同提高的目的。     

Visitor-artwork network analysis using object detection with image-retrieval technique

Recent museum exhibitions are becoming a means by which to satisfy visitor demands. In order to provide visitor-centric exhibitions, artwork must be analyzed based on the behavior of visitors, and not merely according to museum professionals' points of view. This study aims to analyze the relationship between museum visitors and artwork via a network analysis based on visitor behavior using object detection techniques. Cameras installed in a museum recorded visitors, and an object detector with a content-based image-retrieval technique tracked visitors from the videos. The durations spent with different artworks were measured, and the data was converted into a bipartite graph. The relationships between different artwork types were analyzed with a visitor-centered artwork network. Based on the visitors’ behavior, significant artworks were identified and the artwork network was compared to the arrangement of the museum. The tendency of edges in the artwork network was also examined considering visitors' preferences for artworks. The method used here makes it possible to collect quantitative data, with the results possibly used as a basis and for reference when analyzing artwork in a visitor-centered approach.     

基于Word2Vec词嵌入和聚类模型的安全生产事故文本案例分类

安全生产事故的分析对应急管理能力提升具有重要意义.通过对安全生产案例的语义分析,利用Word2Vec词嵌入技术和聚类模型,选用CBOW+负采样技术实现词向量,并结合安全生产事故案例分类的数据特点,通过基于半监督学习的聚类模型算法,根据事故性质的认定特点,提出了一种优化初始聚类中心的算法,并利用K-means聚类算法实现安全事故文本案例的分类.实验表明该方法较好实现安全生产的事故案例分类,并对安全生产事故的多个维度分析具有很好借鉴意义.     

纯铜薄板矩形盒拉深中法兰曲边的变形分析

作为矩形盒拉深试验研究的一部分 ,分析了成形过程中光刻网格变形的测量结果 ,指出法兰曲边变形中 ,角对称线上凹模口附近的径向拉变形随矩形盒角半径rc 增大而增大 ,但周向压变形几乎与rc 无关。并且在角对称线上存在径向压变形的区域 ,有助于减低曲边材料的流入抵抗