粉末布法制备SiC/Ti基复合材料

用粉末布法制备了低成本SiC/Ti基复合材料.结果表明,采用合适的轧制参数即可容易地获得厚度合适、均匀的粉末布;热失重分析和热解残余物分析指出用来制备粉末布的有机粘结剂的去除过程分成两个阶段,合理除气后,基本没有残余物.使用真空热压工艺制备的SiC/Ti基复合材料,纤维分布基本均匀,纤维与基体的界面结合良好.     

苦味酸钾点火药在电点火头中的应用

通过理论分析和试验,从机械感度、燃烧精度、热安定性、性能、长贮等方面,对比分析了苦味酸钾点火药与DDNP点火药.结果表明:在电点火头制造中,采用苦味酸钾作为点火药的主要组分,具有热稳定性好、药头机械强度高、生产过程废品少、无环境污染等优点,尤其有利于提高电雷管的发火可靠性和一致性.     

Direct Methods Optimised for Solving Crystal Structure by Powder Diffraction Data: Limits,Strategies, and Prospects

The ab-initio crystal structure solution by powder diffraction data requires great efforts because of the collapse of the experimental information onto the one dimensional 2θ axis of the pattern. Different strategies will be described aiming at improving the process of extraction of the integrated intensities from the experimental pattern in order to make more straightforward the structure solution process by direct methods. Particular attention will be devoted to the EXPO program. Some of its performance will be analysed and results will be shown.     

Dispersion—flocculation studies on a Goethite-clay system

Dispersion–flocculation studies on a Goethite–clay system using flocculants were carried out as a function of flocculant concentrations, pH of slurry, time of agitation and dispersant dosage. Also, the effects of pH and polymer concentrations on the adsorption behaviour of the system were investigated. Results show that well flocculated goethite was preferentially obtained from 4% goethite/kaolinite clay suspensions, with 50 ppm causticised starch in the slurry at pH values of 3–11·5 and with 50 ppm polyacrylamide at pH values of 3–8. Good flocs were also obtained on flocculation of the goethite suspension with 50 ppm polyacrylamide at pH values of 5–7, while the kaolinite suspension did not respond to the same dosage of causticised starch in the same pH range. Results further reveal that for the goethite/kaolinite suspension, the best results was obtained with 50 ppm polyacrylamide at pH values of 7–10. Based on the data generated in the study, it was concluded that causticised starch is a better flocculant than polyacrylamide for goethite suspensions although polyacrylamide is an excellent flocculant for kaolinite suspensions.     

THE STICKY ISSUES OF DRYING

Unconrolled agglomeration of particles and adhesion of the particulate mass to wall surfaces are common severe problems in many drying operations. This paper reviews the mechanisms of interparticle and particle-surface attraction as well as the theory and the existing tests for characterising powders in terms of internal strength, wall friction and adhesion. The usefulness of the information obtained from these tests in dryer design and operation is critically reviewed. The importance of powder stickiness in various types of dryers is discussed and established methods of combating the problem are presented Recommendations an made for further research in the area of powder cohesion and adhesion.     

М.Ю.巴利新的粉末冶金理论

巴利新(原苏联)是世界知名的粉末冶金学家。1938年他提出的压制方程ln p=—AV+B仍为美国1984年出版的《金属手册》第九版第七卷‘粉末冶金’所引用。早在70年代,巴利新就根据他提出的一系列新理论,提出一个新的压制或固结方程式组α=~2z,f=F(,α),p=pαf,但除原苏联外,该方程鲜为人知。鉴于此,本文作者对巴利新60年代以来发表的一系列关于粉末冶金理论的论著进行了整理,现扼要地予以阐述,这对我国粉末冶金理论的研究或许是有益的。     

Effect of Reactor Ambient Pressure on the Morphology of Spray Dried Magnesium Sulphate Powders

The effect of reducing the reactor air pressure on the morphology of spray dried magnesium sulphate powders is investigated, experimentally. A reactor, capable of drying and pyrolyzing solution sprays at low pressures, is designed and manufactured. A vibrating mesh nebulizer is employed to generate the spray. Four different pressures, starting from 60 Torr to the atmospheric pressure, and two different reactor air temperatures of 130°C and 420°C, are considered. In addition, two different concentrations of magnesium sulphate solutions are tested. The results are explained based on the effect of reactor air pressure on the droplet evaporation rate.     

Dental amalgam – the effect of the technology of alloy powder preparation on the corrosion behaviour and the release of mercury

Dental amalgams are based on a broad spectrum of materials differing in their chemical composition, metallurgical treatment, and in the way the initial alloys powders are prepared. In addition to their chemical composition, amalgams based on various powders differ in both their microstructure and the amount of mercury needed for preparation. All these facts may affect electrochemical processes occurring during their interaction with oral fluids, and also mercury release. While verifying the effect of the technology used for the preparation of the high‐copper ternary alloy powder on the properties of resulting amalgams, this study aimed at the mechanism of their interaction with a model saliva solution as well as mercury release was included. Measurements were done in a model saliva solution using standard electrochemical methods and exposition measurements. The interaction of individual types of amalgams with artificial saliva did not reveal any significant differences. The free corrosion potential of all these amalgams in an aerated solution settled in the range of values in which tin oxidation, resulting in a layer of insoluble corrosion producsts, turned out to be the dominant anodic process. The rate of mercury release was the lowest for amalgams based on a gas‐atomized alloy. The highest rate of mercury release, and also its dependence on time, was exhibited by lathe‐cut powder based amalgam. In addition to different volume fraction of the Ag‐Hg phase and the level of its tin alloying, this different behaviour may be explained by differences in the rate at which a layer of tin corrosion products acting as a barrier to mercury release is formed.     

迁安精矿粉高碱度烧结矿试验研究

对迁安地区磁选精矿粉添加磷石粉和Ｂ２Ｏ３，生产二元碱率为２．０左右的高碱度烧结矿，在实验室和现场进行了试验。结果表明：加入少量磷灰石粉或硼即可完全抑制烧结矿冷却过程中的自然粉化现象；ＭｇＯ含量对烧结矿质量影响明显；烧结矿的冶金性能良好。