Some kinetic aspects of unsteady-state partial oxidation reactions. Dynamic processes on metal oxide surfaces

It is shown that steady-state kinetic data do not allow the discrimination between the redox and associated mechanisms of the partial oxidation reactions. A discrimination between these mechanisms was performed using transient experiments. The obtained rate expressions are in agreement with experimental kinetic data for catalytic partial oxidation of o-xylene.

An influence of the conjugate oxidation of a catalyst surface on dynamics and kinetics of the heterogeneous catalytic oxidative reactions is considered. Computing simulation of methane oxidative coupling of methane reaction at lowered temperature and elevated pressure has been performed. It showed that the reaction order with respect to oxygen exceeding unity is consistent with the chain branching mechanism of the reaction in the presence of TiSi₂ and TiB₂ and showed the important role of the branching chain cycles in the low-temperature OCM reaction at elevated pressure.     

铁电体尺寸对其开关特性的影响

应用铁电体极化反转的Orihara Ishibashi理论 ,讨论了圆形铁电薄膜和球形铁电体的开关电流以及开关时间对系统尺寸的依赖性。数值计算表明 ,不论是二维还是三维铁电系统 ,其铁电畴反转过程中产生的开关电流都随系统尺寸减少而下降 ,开关时间随系统尺寸减少而缩短     

铸型尼龙改性的研究进展

铸型尼龙产品广泛地用于各种机械零件，改性后的铸型尼龙，可克服其自身的缺点，满足工业应用的要求。文章就我国近年来在铸型尼龙改性研究方面的情况及不同的改性方法做了详细的介绍。     

传播介质特性对爆破震动信号分析中小波包时频特征的影响

传播介质是指爆破震动赖以向外传播的地层介质 ,其基本特征是影响爆破震动时频分布的主要因素之一。当传播介质中有爆破震动通过时 ,其动态响应将会因其原地结构的不同而在响应持续时间、频谱、响应的衰减等特征方面均有较大差异。本文利用岩体 (岩土混合体 )基本质量指标BQ值以及完整性系数Kv 来量化传播介质特性。通过对不同岩层地质条件下产生的爆破震动进行小波包分析 ,探讨了传播介质特性量化参数与爆破震动时频分布之间的关系。研究中发现 ,传播介质特性对单段波形小波包细节信号的主振频带分布、峰值质点振速及衰减阻尼比等时频特征参数均有较大影响 ,其中主振频带分布范围随着传播介质的完整性系数Kv 值减小而增大 ,优势频率值随完整性系数Kv 值减小而增加 ,而峰值质点振速及衰减阻尼比与完整性系数Kv 值之间的规律性不强     

一种实用的新型双转动单螺杆泵

针对目前单螺杆泵使用中存在的转速低、振动大和离心力大等局限性,研制了一种实用的新型双转动单螺杆泵。这种泵结构简单,省掉了减速机构和万向装置,实现了内、外转子同方向高速平稳转动。该泵有4大特点:(1)把现有螺杆泵转子的滚动+绕偏心距摆动的复杂运动简化成绕其中心的纯转动,故噪声小,振动小,离心力小;(2)内、外转子是纯转动,无摆动现象,故动力轴和螺杆之间无需万向装置,内、外转子可制成全金属型,耐温达200℃以上;(3)无需减速机构,电动机可直接与内、外转子对接,使螺杆泵转速由400r/min提高到3500r/min;(4)外转子可以模块化加工。     

莺歌海盆地CO2成因及运聚特征的初步研究

在已获天然气地地化资料的基础上，重点论述了ＣＯ２天然气地化特征及成因类型，追踪和判识ＣＯ２气烃类气的气源，初步了ＯＣ２气的分布特征及控制因素，指出本区ＣＯ２气属壳源型岩石化学的成因，气源主要来自莺黄组中、下部含钙海相泥岩，与深部火山慢源的ＣＯ２气无关，谱不具深源的特征。     

Velocity Profile in Fixed Beds: A Study on the Representativeness of the Experimental Measurement of Downstream Flow Characteristics

Although considerable progress has been made in the development of experimental techniques for investigating velocity distribution inside a fixed bed, these techniques were limited to special cases. Consequently, the velocity distribution is normally measured at downstream of the fixed bed and then this measurement is considered to be representative for the flow inside the bed. To evaluate the representativeness of this technique, this work presents a study of the change in the flow characteristics, starting from the boundary of the fixed bed within the pipe to a downstream position where the experimental measurement is taken, by using simulations based on computational fluid dynamics methods.     

Assessment of Capillary Rise from Shallow Groundwater by the Simulation Model SIMWASER Using Either Estimated Pedotransfer Functions or Measured Hydraulic Parameters

The performance of the water balance and crop growth model SIMWASER to estimate the water supply of a lawn by capillary rise from shallow ground water was investigated by using lysimeter measurements with a sandy and a clayey soil. Moreover the robustness of the model was evaluated by running it either with measured hydraulic soil parameters or with estimated pedotransfer functions (PTFs) derived from texture and bulk density. Simulations were performed for the years 1996–1998 with input data from the lysimeter station Berlin-Dahlem (Germany) for lysimeters containing undisturbed sandy or clayey soil monoliths, with groundwater at 135 cm depth. Simulated evapotranspiration and percolation/capillary rise were in good agreement with the measured data for all variants, while simulated soil water storage was acceptable only for the variants using hydraulic soil data based on laboratory measurements or using PTFs derived from known soil class and bulk density. PTFs based on mean total pore volume of the respective soil classes yielded soil water storages which were evidently too high; therefore they should be used with care and must be avoided at all in simulating the soil water balance of arid sites with shallow groundwater.     

A unified proposal for characteristic testing methods and figure of merit of 8‐kV/3.5‐kVA class light‐triggered thyristors

Power devices with high capability have been developed. 8‐kV/3.5‐kA‐class light‐triggered thyristors have the highest capability among power devices. These devices are used in the Kii Channel HVDC transmission system in Japan. In this paper, we report the extracted problems of conventional testing methods of 8‐kV/3.5‐kA‐class light‐triggered thyristors among manufacturers, and the proposed unified testing methods on the basis of element characteristics and operating conditions in the Kii Channel HVDC system. Furthermore, we propose a figure of merit for power devices for the practical use, and try to extract elements used at the Kii Channel HVDC system with small margins and low withstand capabilities. © 2002 Wiley Periodicals, Inc. Electr Eng Jpn, 140(3): 61–70, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10024     

MV2000T智能变送器

较全面地介绍了ABB公司MV2 0 0 0T智能变送器的市场开发背景、工作原理、技术规格、性能特点及设计选型要点