钛母板包边方法试验研究

试验了钛母板各种包边方法，提出了在钛母板边缘端面上开槽并填胶粘剂包边，或者在钛母板边缘两面上开不对称燕尾槽并注射塑料包边的两种包边新方法与新工艺。     

Mechanical properties of copper‐clad laminate using composite naphthalene–phenyl‐based epoxy as prepreg

A composite was prepared that contained diglycidyl ether of tetrabromobisphenol A (DGETBA) and 1,5‐di(2,3‐epoxypropoxy)naphthalene (A), 4,4′‐bis(2,3‐epoxypropoxy)benzylideneaniline (B), or 4,4′‐bis(2,3‐epoxypropoxy)biphenyl (C), and then was cured using different ratios of dicyandiamide (DICY). The results of DSC, TGA, coefficient of thermal expansion, dielectric constant, and dissipation factor testing of the composite epoxy resins were analyzed, and investigation of the copper‐clad laminate using the composite epoxy resins as prepreg was also performed. Additionally, moisture absorption, peel strength, arc resistance, comparative tracking index, and flammability of the copper‐clad laminate were examined. Clearly, some of the physical or mechanical properties of the composite and the copper‐clad laminate can be improved by optimal addition of naphthalene–phenyl‐based epoxy. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1485–1492, 2005     

基于数值模拟的SBA水合反应器上封头与人孔安全评定

为了体现应力在复合板制设备中的具体分布情况以及常规设计方法和分析方法之间的差异,采用有限元分析软件对仲丁醇（SBA）水合反应器上封头和人孔在设计条件下的应力响应情况进行了分析,并结合JB4732—95所规定的应力强度对其结构强度进行了评定,通过等效三维模型应力分布对工程实际问题进行了求解分析。     

FR-4敷铜板专用四溴双酚A环氧树脂生产工艺优化

介绍了FR 4敷铜板专用CYD 5 2 1 A 80四溴双酚A环氧树脂的性能、生产原理、工艺流程及生产工艺的再优化 ,使产品色度、粘度指标均达到FR 4敷铜板的高标准要求。产品质量稳定 ,为CYD 5 2 1 A 80产品国产化奠定了技术基础。     

低成本高频电路用覆铜板的研制

本文介绍了国内外高频电路用覆铜板的技术进步,着重研究了一种环氧改性异氰酸酯类粘合剂,结果表明采用该粘合剂／E型玻璃纤维布制备的层压板产品具有成本低,介电性能良好等特点。     

Microstructure and mechanical properties of stainless steel clad plate joints produced by TIG and MAG hybrid welding

Abstract

This paper investigated the microstructure and mechanical properties of Q235/304 stainless steel clad plate welding seam produced by hybrid welding of tungsten inert gas welding (TIG) and metal active gas arc welding (MAG). The results showed that the dual phases containing ferrite and austenite appeared in the stainless steel covering welding (SSCW), while the partial martensite phases appeared in the carbon steel backing welding (CSBW), which is attributed to the dilution behavior of Ni and Cr elements from stainless steel to the Q235 steel results into the movement of the CCT curve to the right side and the decrease of critical martensite formation cooling rate. The CSBW possesses the highest microhardness value in the weld metal due to the existence of the martensite zone. The impact tests were carried out and the results showed that the Charpy absorbed energy of weldments (81?J) is almost equal to that of base clad plate (83?J). The SSCW layer possesses the ductile fracture characteristics accompanying many dimples. However, in the CSBW layer, some cleavage fracture characteristics are presented in the radiation zone while many dimples are located in the fibrous zone, revealing a complex combination of brittle and ductile fracture behavior, which is due to the existence of martensite zone, different stress states and crack propagation velocity.

• Highlights

• Hybrid (TIG, MAG) welding is suitable for welding stainless steel clad plate;

• The martensite formation in CSBW is related to dilution and diffusion of Cr and Ni;

• Partial martensite transformation can strengthen and toughen the welding seam.

     

反应等离子熔敷Cr7C3/γ-Fe金属陶瓷复合材料涂层组织与耐磨性

以Fe-Cr-C合金粉末为原料,采用优化的等离子熔敷工艺,在C级钢表面通过粉末反应制得由原位生成的新型Cr7C3/γ-Fe金属陶瓷复合材料涂层.并测试分析了涂层的显微组织和显微硬度分布,以及在室温干滑动试验条件下的耐磨性.结果表明,该涂层组织由规则块状初生相Cr7C3和γ-Fe奥氏体固溶体组成,与基材完全冶金结合,涂层厚度约1.5mm,具有较高的显微硬度（平均为870HV）,且硬度梯度分布合理;涂层在室温干滑动试验条件下具有优异的耐摩擦磨损性能.     

铜铝双金属管材挤压成形工艺参数分析

通过对双金属管材挤压成形的有限元模拟发现:当挤压模凹模带有锥角而芯棒为圆柱体时挤压铜铝双金属管材时常出现内层金属断裂的现象.为了解决这个缺陷通过反向思考提出了芯棒带有锥角而凹模为直筒的特殊的模具结构,并结合有限元软件Deform-3D分析了不同芯棒锥角下金属的变形情况,确定了合适的锥角大小,同时对双金属管材内外管材的厚度比也有限制要求,成功实现了铜铝双金属管件的挤压成形.通过对挤压过程中的芯棒进行强度校核对此挤压模具的结构进行了设计.     

等离子熔覆高铬铁基涂层的开裂行为与控制

以钛铁粉、铬粉、铁粉和碳的前驱体(蔗糖)等为原料通过前驱体碳化复合技术制备了复合粉末,并通过等离子熔覆技术在Q235钢表面制备了Fe-Cr-C和Fe-Cr-C-Ti涂层.采用XRD和SEM对涂层的相组成和显微组织结构进行了分析.结果表明,Fe-Cr-C涂层裂纹一般始于熔合区,沿初生碳化物(Cr,Fe)₇C₃晶界扩展成结晶裂纹,沿初生碳化物(Cr,Fe)₇C₃纤维方向扩展到涂层表面,形成垂直于涂层表面的垂直贯穿裂纹.少量裂纹起源于气孔或涂层边缘尖锐处.Fe-Cr-C涂层中添加Ti元素,可以合成大量TiC颗粒,形成奥氏体组织,减少或消除(Cr,Fe)₇C₃初生碳化物,改善(Cr,Fe)₇C₃共晶组织结构,有效提高了涂层韧性,抑制了涂层裂纹的产生.     

不锈钢包钢在红壤中的电偶腐蚀行为

通过失重法、电化学方法研究了不锈钢包钢在红壤中的电偶腐蚀行为,采用SEM、XRD观察分析试样的表面形貌及腐蚀产物。结果表明:不锈钢-碳钢电偶对的形成加速了阳极金属材料的腐蚀,随着电偶对阴阳极面积比的增加,电偶电流逐渐增大;不锈钢在浸泡45d后基本没有发生腐蚀,而碳钢则发生了极严重的全面腐蚀,腐蚀产物主要为铁的氧化物。