约束放电激励千瓦级基模CO2激光器

本文研究了约束放电激励千瓦级基模CO2激光器。约束放电激励的思想核心是:利用正交或基本正交的电场或者电磁场在阴极位降区附近形成对带电粒子的捕集阱,由此产生对放电过程中从阴极发出的带电粒子的约束作用从而影响整个气体放电激励过程。     

固体推进剂中有关粒度分布的数学处理

介绍了固体推进剂中有关颗粒度分布的数学处理方法，用几种数据统计分析的理论分布函数－正态分布，对数－正态分布，Ｋ分布，并以铝粉和含铝推进剂燃烧残渣的颗粒分布为例进行了分析，根据Ｃｕｌｉｃｋ微粒阻尼的理论计算模型，讨论了粒度分析在阻尼效应计算中的应用。     

含氮化合物废气选择性催化氧化技术研究进展

通过对当前含氮化合物废气治理技术的对比分析,总结选择性催化氧化的相关技术优势。根据对含氮化合物的种类及来源分析,介绍氨气、腈类、胺类及其他含氮化合物的催化净化技术。重点总结催化剂的种类、研发进展和在实际使用中可能遇到的问题,同时展望含氮化合物废气选择性催化氧化技术的研发方向。     

荫罩黑化及DX气与煤气成分的探讨

本文介绍了彩色显像管荫罩黑化反应的机理,详细说明了DX气制气流程,以及DX气的成分对黑化膜品质的影响。计算分析了成分不同的煤气在制成DX气时的成分变化。同时还分析了黑化工艺和黑化设备对煤气成分波动的适应性,及在生产实践中改变DX气制气时的煤气空气对黑化膜质量的影响。     

Stationary and traveling hot spots in the catalytic combustion of hydrogen in monoliths

In the course of catalytic combustion of hydrogen (1-5% H₂ in air) in monolith reactors, strongly localized stationary and traveling hot spots arise in response to a sudden and persistent rise of gas flow velocity. Such hot spots may occur, e.g. in a catalytic converter following the acceleration of a car or in a catalytic combustor as a result of a load increase. This phenomenon is illustrated by simulations using a two-phase reactor model. The temperature overshoot of the adiabatic limit is typically of the order of the adiabatic temperature rise itself.The following mechanism underlies this behavior. Light fuel is supplied to the catalytic wall by fast diffusion (in the direction perpendicular to flow), while the heat released by reaction is removed from the wall by the slower, mixture-averaged heat conduction. This leads to accumulation of heat at the catalytic surface that eventually saturates at high temperatures. The hot spots may exhibit intricate dynamics, propagating downstream or upstream, or they may remain stationary. The direction of propagation depends on the relative strength of convective downstream and conductive upstream contributions to the overall displacement of reaction fronts. Generally, the hot spot tends to drift downstream at low flow velocities, remain stationary at intermediate flow velocities, and drift upstream at high flow velocities.     

Cure reaction for modified diallylbisphenol A/diaminodiphenylsulfone/bismaleimide

The glass‐transition temperature as a function of curing conversion for a modified diallylbisphenol A/diaminodiphenylsulfone/bismaleimide (BMI) resin was investigated at different temperature regimes and modeled using a modified Di Benedetto equation. Although the relationship between the glass‐transition temperature and conversion of the BMI system conforms to the Di Benedetto equation for α < 0.6 and at lower cure temperatures, at higher cure temperatures the results deviated significantly from the equation; thus, it was an inadequate model for the system. Fourier transform IR analysis showed that the major crosslinking reactions did not occur during cure for the modified BMI at and below 150°C. However, as the cure temperature was increased, the crosslinking reactions responsible for 3‐dimensional network structures became more dominant. At 190°C the C? N? C_stretch vibration of the uncured maleimide ring converted into succinimide rings in the curing process. Simultaneously, a decrease was observed for the absorbance bands of ? C? H_bending (maleimide). The higher cure temperatures induced a significantly faster initial crosslinking rate and also resulted in a shorter period of time after which further crosslinking was retarded, because the increase in the crosslinks also physically slowed further crosslinking activity. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 227–235, 2002     

VSP旅行时反演应用于VSP—CDP转换

非零偏移距垂直地震剖面(VSP)模型的制作是非零偏移距VSP资料处理的关键环节之一,是VSP-CDP转换的基础。本文试用旅行时反演修正非零偏移距VSP的模型,以加速模型的制作过程,提高非零偏移距VSP的处理速度。用合成VSP资料试算表明:旅行时的随机误差对模型的制作影响不大;只要能较准确地确定界面位置,用旅行时反演修改制作非零偏移VSP模型是可行的。本文还探讨了初始模型的不同选择方法,并将旅行时反演用于实际VSP资料的处理。结果表明,大大地节省了非零偏移距VSP资料的处理时间。     

石脑油型加氢裂化催化剂的研制

采用共沉淀方法合成了石脑油一中氢裂化催化剂。在１００ｍＬ小型加氢装置上，对金属和分子筛含量等因素进行了考察，结果表明，研制的石脑油型加氢裂化催化剂具有初活性反应温度低，活性稳定性好等特点。     

Al2O3基耐磨陶瓷涂层的燃烧合成与应用

介绍了燃烧合成表面涂层技术的基本原理 ,开发了相应的制备工艺 ,并在此基础上研制了内覆陶瓷涂层的复合钢管、弯管及弯头。陶瓷涂层主要由α Al2 O3相、部分FeO·Al2 O3相和 3Al2 O3·2SiO2 相组成 ,采用添加剂可以有效提高熔体的流动性 ,使陶瓷的凝固和结晶过程得到进一步控制 ,有助于减少孔隙 ,提高陶瓷涂层的致密度。现场应用试验表明 ,涂层具有较好的耐磨性能 ,可使设备的使用寿命大为延长     

催化燃烧炉的节能性分析

传统的火焰燃气炉往往会产生不同数量的氮氧化物(NO和NO2)、一氧化碳等不完全燃烧产物,造成了环境污染和能源浪费.催化燃烧作为一种新的燃烧方式,打破了传统火焰燃烧的可燃界限,实现了贫甲烷/空气混合物在可燃界限以下的燃烧,燃烧效率高,提高了能源利用率.将催化燃烧应用于燃气炉,可以解决燃气炉由于火焰燃烧带来的燃烧效率低等缺点,达到节约能源的目的.以催化燃烧和燃气炉为依据,在催化燃烧炉Ⅰ型的基础上研制出催化燃烧炉Ⅱ型,分析了催化燃烧炉的热损失以及热效率,并与传统火焰燃烧炉做了比较.结果表明,催化燃烧炉Ⅱ型的热损失并不大,热效率较高,且其污染物排放量极低.