铸造铝合金(ZL109)激光表面处理

采用功率为2kW级CO_2连续可调式横流激光光源,对不同涂层的ZL109试样表面进行了激光熔凝的实验研究。     

铁元素对ZL108合金铸造性能的影响

研究了铁、锰对ZL108活塞合金铸造性能的影响。试验表明,在磷变质ZL108合金中,随着铁含量的增加,其流动性降低,体收缩、线收缩也减少。在高铁ZL108合金中加入锰后,可提高流动性,因为锰能够抑制针状β铁相的有害影响。     

离子注入对铁及其低合金、铝及其合金耐腐蚀性能的影响

离子注入对金属腐蚀行为的研究已达30年．研究结果表明离子注入对改变金属表面成分和表面性能是极为有效的技术．本文概述了离子注入对铁及其低合金、铝及其合金的腐蚀电化学行为的影响．涉及的注入离子达十余种。     

稀土溶液标准物质的研制

选择7种稀土元素:La、Ce、Sm、Eu、Yb、Lu、Y为研究对象,采用高纯稀土氧化物(≥99 99%)为原料,经ICP MS及ICP AES对纯度进行分析后,分别制备成浓度为1000μg mL的稀土溶液标准物质。采用准确、可靠并能溯源的EDTA络合滴定法进行量值核对、均匀性及稳定性检验。对标准物质的不确定度进行了全面的评定。研制的稀土溶液一级标准物质,总不确定度优于0 6%,稳定性达两年以上。     

Procedure for the evaluation of the accumulation of defects in metallic structural materials under complex elastoplastic loading

Within framework of the continual fracture mechanics, we describe the engineering approach to the assessment of scattered microdamage accumulation kinetics in metallic materials under elastoplastic loading conditions in case of plane stressed state. Automatized experimental stand and the respective investigation technique are discussed. The stand has been developed based on modification of the UMé-10T electromechanic test machine. State-of-the-art computer technologies and microprocessing hardware are incorporated in the stand automation. We present the technique of experimental assessment of damage accumulation kinetics in metallic structural materials under complex elastoplastic loading conditions with account of two different fracture (cleavage and shear) processes, which technique is based on measuring the specific electric resistance of the specimen. __________ Translated from Problemy Prochnosti, No. 1, pp. 128–137, January–February, 2006.     

有机镍化合物催化烯烃聚合的研究进展

综述了有机镍化合物如烯丙基镍、乙酰丙酮镍、茂镍、二亚胺镍等催化烯烃聚合的研究进展。有机镍化合物可催化烯烃、α-烯烃(如乙烯、丙烯等)的齐聚及聚合、催化极性单体(如甲基丙烯酸甲酯、降冰片烯等)以及位阻较大的环烯烃、取代二烯烃、苯乙烯等的均聚和共聚。     

用有限带宽反射波波形分析法进行储层横向预测

以正演地震模拟为基础的有限带宽反射波渡形分析法是一种新的储层横向预测方法。首先利用波形分解确定地震反射层的地质属性,找出能反映岩性变化的反射波波形特征参数;然后,采用多元数据聚类分析和灰色系统理论完成储层横向的预测。文中以预测江苏 J 凹陷 F 构造上阜二段生物灰岩分布及厚度横向变化为例,简述了反射波波形分析的全过程。预测结果已为钻探证实。     

泥炭土地基钻孔漏浆的处理

以云南鸡石一级公路青鱼湾大桥为例，介绍了在软弱地层中施工桥梁钻孔灌注桩遇孔壁开裂漏浆时的处理方法，经试验证明，取得了较好的技术经济效果。     

古老的铁艺再次辉煌

铁艺实用美观，唤起人们的怀旧情怀，从公共场所到家居装饰，应用广泛。介绍铁艺选择、使用、维护与保养知识，分析，预测铁艺的市场前景。     

Preparation of monodisperse poly(vinyl alcohol) microspheres by heterogeneous surface saponification and iodine complex formation

Monodisperse poly(vinyl acetate) (PVAc) microspheres with high molecular weight obtained by suspension polymerization of vinyl acetate were saponified in alkaline aqueous solution to keep their spherical structure. The saponification was restricted on the surface of the PVAc microspheres and obtained particles had skin/core structure. Various poly(vinyl alcohol) (PVA) microspheres with different diameters and degrees of saponification (DSs) were obtained. The conversion of PVAc to PVA during the heterogeneous surface saponification time were examined by nuclear magnetic resonance spectroscopy and after 72 h hydrogel type PVA microspheres completely saponified were obtained. The crystal melting temperatures of the microspheres obtained by the saponification were measured a constant value of 238°C irrespective of varying DS, and the peaks became enlarged as reaction time. Iodine complexes were formed in saponified microspheres with DS of 41% and 99% by immersing them in I₂/KI aqueous solution and decomposed by the reduction of I₂ in the complexes to 2I^? using sodium sulfite to confirm whether the skin formed through the saponification was composed of PVA with high VA content. Obviously, characteristic blue color developments owing to I₅^?‐PVA complexes were observed in both saponified regions and a red in the PVAc core. Consequently, it was concluded that the PVA skins formed by heterogeneous surface saponification had high DSs. Such complexes endowed polymeric microspheres a good radiopacity which would be useful in clinical treatment of vascular diseases and were examined by X‐ray irradiation image. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008