HA-ZrO2生物复合材料的制备

首先以H3PO4和Ca(OH)2为主要原料利用湿化学方法合成了结晶良好的羟基磷灰石粉体(HA),在该粉体中分别引入15%、20%和25wt%的m-ZrO2粉体,经成型后分别在900℃、1 000℃、1 100℃和1 200℃温度下煅烧1h,详细研究ZrO2含量和烧结温度对该复合材料物相及体积密度的影响规律.结果表明:随着烧成温度的升高,该复合材料的体积密度呈上升趋势,当温度为1 000℃时达到最大值,当温度进一步升高时,体积密度下降.而复合材料中的HA相随温度的升高而不断降低,当温度超过1 000℃时该趋势更加明显.随ZrO2的引入材料体积密度有一定提高,但当ZrO2含量超过20%时,其体积密度有所降低,当ZrO2含量为20%时,杂质含量最低.     

催化湿式氧化吡虫啉农药废水Cu/Mn催化剂稳定性

通过共沉淀法制备了用于湿式氧化吡虫啉农药废水的Cu/Mn复合氧化物催化剂,研究了焙烧温度和活性组分配比等因素对Cu/Mn复合氧化物催化剂的活性及稳定性的影响,确定了最佳制备条件,利用BET比表面积测定和XRD对催化剂进行了表征.结果表明,优化条件制备的Cu/Mn复合氧化物催化剂催化湿式氧化处理吡虫啉农药废水时,具有较高的催化活性和稳定性.Cu/Mn=2∶1,焙烧温度800℃,焙烧时间16h,COD去除率为93.12%,催化剂活性组分的流失小于0.3mg/L.对催化剂活性组分不易流失的原因进行了理论解释和计算.     

混凝土拱桥拱上建筑轻型化研究

制约混凝土拱桥向更大跨度发展的主要问题是结构自重大和施工架设困难。为提高混凝土拱桥的竞争力和促进该桥型的进一步发展,以420 m跨径的重庆万州长江大桥为工程背景,通过桥道系连续化和采用组合结构代替原有混凝土结构等方式来进行混凝土拱桥拱上建筑轻型化研究。与原设计在静力性能和地震响应分析的比较结果表明,桥道系连续化对减轻拱上建筑结构自重的效率较低,其静力性能与抗震性能提高也不大;而采用组合结构可使得拱上建筑结构自重减轻35%,拱脚轴力和弯矩分别降低了16%和17%,三向地震作用下的拱脚横向弯矩和拱顶横向位移分别减小了13%和18%,拱脚纵向弯矩、轴力分别降低了45%和44%,具有可行性。     

中空纤维分子印迹复合膜选择性分离萘普生对映体

以聚偏氟乙烯(PVDF)中空纤维超滤膜为支撑膜,S-(+)-萘普生为模板分子,4-乙烯基吡啶为功能单体,制备了分子印迹复合膜。通过紫外光谱法研究了模板分子与功能单体之间的相互作用,比较了热聚合和光聚合两种引发方式对膜形貌和性能的影响。试验结果表明,分子印迹聚合物膜中存在着三维空间结构和功能基均与模板分子互补的孔穴组成的通道,该通道可选择性地透过S-(+)-萘普生,在压力和亲和力的协同作用下,最大分离因子可达6.19。     

基于ABAQUS的钢管混凝土组合剪力墙弹塑性有限元分析

钢管混凝土组合剪力墙是一种新型剪力墙,能充分发挥不同受力体系和不同材料的抗震优势.采用大型有限元分析软件ABAQUS对该新型剪力墙进行了弹塑性有限元分析,研究了钢管混凝土组合剪力墙在荷载作用下的应力、应变等微观受力状态,揭示了其破坏过程和抗震机理.     

混杂纤维加固混凝土方柱的轴压性能试验研究

通过对不同加固方式下的钢筋混凝土短柱轴压性能试验,研究了混杂纤维约束混凝土柱的破坏形态及荷载与钢筋、混凝土之间的应变曲线关系,以承载力和延性为指标对比分析了不同混杂方式、混杂体积比的混杂纤维约束混凝土柱的受力性能.试验结果表明:混杂纤维的约束作用可以有效提高柱的承载能力,并使其延性得到显著改善;对于其混杂越均匀和二级拉伸破坏的试件,表现出更好的混杂效果,体现出混杂纤维的优越性.     

一类离散切换模糊组合系统的分散控制

针对一类离散的切换模糊组合系统,利用单Lyapunov函数方法和多Lyapunov函数方法设计出分散切换律和控制器,给出了利用矩阵不等式表达的系统在分散切换律和分散控制器作用下的可镇定条件,仿真结果表明了该方法的有效性。     

Effects of submicron diamonds on the growth of copper in Cu-diamond co-deposition

Submicron diamonds were co-deposited on aluminum substrates with copper from the acid copper sulfate electrolyte by electrolyte-suspension co-deposition.After submicron diamonds were added to the electrolyte,the shape of copper grains transformed from oval or round to polyhedron,the growth mode of copper grains transformed from columnar growth to gradual change in size,and the preferred orientation of copper grains transformed from (220) to (200).Analyzing the variation of cathodic overpotential,it was found that the cathodic overpotential tended to remain unchanged when copper plane (220) grew in the process of electrodepositing pure copper,while it tended to decrease with time when copper plane (200) grew m the process of co-deposition.It was inferred that copper plane (200) was propitious to the deposition of submicron diamonds.     

Effect of magnesium and nickel coatings on the wetting behavior of alumina toughened zirconia by molten Al-Mg ahoy

The wettability of alumina toughened zirconia (ZTA) by Al-Mg alloy was investigated using the sessile drop technique.The effects of nickel coating,magnesium content,nitrogen atmosphere,and processing temperature on the contact angle between the molten alloy and the substrate were determined.Likewise,the effect of these factors on the wetting properties was studied.The results showed that the nickel coating on the ceramic substrate caused a significant reduction in solid/liquid surface energy and the contact angle decreased obviously.The presence of magnesium in the molten aluminum alloy in nitrogen atmosphere reduced the contact angle effectively.The presence of magnesium in the alloy must be at a minimum amount of 2wt％-3wt％.Moreover,it was suggested that some chemical reactions in the Al-Mg-N system led to the production of Mg3N2 and A1N compositions.These compositions improved the wetting properties of the systems by reducing the surface energy of the molten.It was shown that increasing the temperature is also an effective factor for the enhancement of wetting properties.     

Effect of magnesium and nickel coatings on the wetting behavior of alumina toughened zirconia by molten Al-Mg alloy

The wettability of alumina toughened zirconia (ZTA) by Al-Mg alloy was investigated using the sessile drop technique. The effects of nickel coating, magnesium content, nitrogen atmosphere, and processing temperature on the contact angle between the molten alloy and the substrate were determined. Likewise, the effect of these factors on the wetting properties was studied. The results showed that the nickel coating on the ceramic substrate caused a significant reduction in solid/liquid surface energy and the contact angle decreased obvi-ously. The presence of magnesium in the molten aluminum alloy in nitrogen atmosphere reduced the contact angle effectively. The presence of magnesium in the alloy must be at a minimum amount of 2wt%-3wt%. Moreover, it was suggested that some chemical reactions in the Al-Mg-N system led to the production of Mg3N2 and AlN compositions. These compositions improved the wetting properties of the systems by reducing the surface energy of the molten. It was shown that increasing the temperature is also an effective factor for the enhancement of wetting properties.