Synthesis of nitropyridine‐based π‐conjugated polymers and their chemical properties

π‐Conjugated poly(3‐nitropyridine‐2,5‐diyl) ( PPy‐3‐NO₂ ), poly(3,3′‐dinitro‐2,2′‐bipyridine‐5,5′‐diyl) ( PBpy‐3,3′‐diNO₂ ), and a poly(arylene ethynylene) type polymer consisting of a 3,3′‐dinitro‐2,2′‐bipyridine unit ( PAE‐1 ) were synthesized by Cu‐promoted Ullmann coupling reaction and Pd‐catalyzed coupling reaction. PPy‐3‐NO₂ and PAE‐1 were soluble in organic solvents such as DMSO, DMF, and chloroform, and gel permeation chromatography analysis showed a number average molecular weight (M_n) of 9,300 and 12,300, respectively. PPy‐3‐NO₂ gave intrinsic viscosity, [η], of 0.53 dL g^?1 in DMF. PBpy‐3,3′‐diNO₂ had somewhat lower solubility. The polymers exhibited a UV–vis peak at about 430 nm. PPy‐NO₂ received electrochemical reduction at ?1.5 V versus Ag⁺/Ag in acetonitrile, and gave an electrochemical redox cycle in a range from 0 to ?1.1 V versus Ag⁺/Ag in an aqueous solution. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1763–1767, 2006     

列管式废热锅炉火管管间液体流速场和温度场的试验研究

本文对列管式废热锅炉火管管间液体流速场和温度场进行了实验研究.采用W1269型水热膜探头和1050型热膜风速仪测定了流场速度分布,用铠装热电偶测量了工质温度分布,并就出水口位置的影响进行了研究,根据实验结果对流场进行了分析,解释了实际应用中上管板经常变形和泄漏等事故的起因.     

共轭聚合物在传感器上的应用

由于其特殊的光学和电子性质，共轭聚合物受到人们的广泛关注．共轭聚合物可以在各种传感器件中用作活性材料，例如：生物传感器；气体、湿度传感器；离子传感器；压力、温度传感器等．本文综述了共轭聚合物在传感器应用方面的一些新的进展．     

Dielectric and conductivity studies on cobalt phthalocyanine tetramers

Electrically conductive organic and metalloorganic polymers are of great interest and they have applications in electronic, optical, photonic, photoelectric, electrochemical, and dielectric devices. Tetrameric cobalt phthalocyanine was prepared by conventional chemical method. The dielectric permittivity of the tetrameric cobalt phthalocyanine sample was evaluated from the observed capacitance values in the frequency range 100 KHz to 5 MHz and in the temperature range of 300 to 383°K. It is found that the system obeys the Maxwell Wagner relaxation of space charge phenomenon. Further, from the permittivity studies AC conductivity was evaluated. The values of AC conductivity and DC conductivity were compared. Activation energy was calculated. To understand the conduction mechanism Mott's variable range hopping model was applied to the system. The T^?1/4 behavior of the DC conductivity along with the values of Mott's Temperature (T₀), density of states at the Fermi energy N (E_F), and range of hopping R and hopping energy W indicate that the transport of charge carriers are by three‐dimensional variable range hopping. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2529–2535, 2004     

照相染料还原电位的研究

本文测定了八个照相染料在不同pH条件下的还原电位。发现其中一些增感染料的还原电位与其溶液的pH值无关,而一些减感染料依赖于pH值的变化。本文用染料质子化机理分析了这些结果。     

基于增强型双向散列链的自愈组密钥分发方案

针对基于传统双向散列链的自愈组密钥分发方法无法抵制合谋攻击的不足,提出了引入滑动窗口和轻量级子链LiBHC结构的增强型双向散列链结构,并给出了基于该结构的自愈组密钥分发方案。该方案有效地解决了组密钥的无缝切换问题,更大程度地减少了合谋攻击对系统构成的安全威胁。分析表明,本方案在保持较好的资源开销优势的前提下,获得了更好的安全性和可靠性,更适用于节点俘获攻击多发的应用场景。     

Different diffusion behavior of cyclic chains under confinement

Molecular dynamics simulations of merging process of two isolated cyclic chains and that of linear chains have been performed, in order to find the difference between the two kinds of chain in bulk and in vacuum, where surface of the system restrains thousands of configurations showing up. Analysis indicates that in such confinement the chain ends at most moments float on the surface layer, and their mobility is much larger than the mean value of all atoms in linear chains, or that in cyclic chains. Comparison of the merging processes of cyclic chains and their linear counterparts was intensively carried out by several means of analyzing the trajectory files in statics and in dynamics. It was found that the segments of cyclic chains showed almost the same behavior of motion with that of linear chains. This is different diffusion behavior from that in bulk systems, where the cyclic chain has much higher diffusion rate. This modeling therefore indicates that in these confined systems because of the surface energy, the end groups are involuntarily kept on the surface, and lost the capacity of leading chain reptation through the other polymer chains, which is possibly the origin that the difference of diffusion behavior between the linear chain and the cyclic chain in the bulk almost disappears in the case of the confinement.     

加筋土在高边墙结构中的应用

分析了加筋土的结构特点及计算方法,结合临淮岗船闸工程监测数据,分析了加筋土对于高边墙水平荷载的减载效果。     

随机环境中马氏链的状态研究

利用马氏链的一般理论讨论了随机环境中马氏链的性质和状态分类。借助于随机环境中马氏链的特征数,首先讨论了状态本质与正则本质的关系,给出了正则本质态的一个充分条件,在此基础上研究了弱常返态与正则本质态的关系及本质态与非正则本质态的关系,而后在状态空间有限及联合空间不可分解的条件下对状态空间进行了分解。最后举出一个实例说明了文章结论的正确性。     

基于锚索计超长预应力束孔道摩阻研究

从设计、施工等环节对摩阻参数的掌控进行分析,列举影响预应力孔道摩阻参数的诸多因素,根据最小二乘法原理进行摩阻试验的理论推导,引入高精度穿心式锚索计对某桥超长束进行现场摩阻试验.通过将试验值与设计值进行对比分析,指出针对该类试验采用最小二乘法原理进行数据处理的方法存在不足之处,并给出解决对策,最后论述了摩阻试验的必要性和...