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91.
The effects of the molecular weights (molecular weight of polystyrene, Mw,PS, varying from 2.9 to 129 k) on the surface morphologies of spin-coated and annealed polystyrene/poly (methyl methacrylate) (PS/PMMA=50/50, w/w) blend films were investigated by atomic force microscopy and X-ray photoelectron spectroscopy. For the spin-coated films, when the Mw,PS varied from 2.9 to 129 k, three different kinds of surface morphologies (a nanophase-separated morphology, a PMMA cellular or network-like morphology whose meshes filled with PS, a sea-island like morphology) were observed and their formation mechanisms are discussed, respectively. Upon annealing, two different morphology-evolution processes were observed. It is found that a upper PS-rich phase layer is formed when Mw,PS<4 k, and this behavior is mainly attributed to the low interfacial tension between PS and PMMA component. When Mw,PS>4 k, the PS-rich phase forms droplets on top of the PMMA-rich phase layer which wets the SiOx substrate. These results indicate that the surface morphology of the polymer blend films can be controlled by the polymer molecular weight and annealing conditions. 相似文献
92.
The effect of electrostatic and capillary forces on bumpy particle adhesion and removal in turbulent flows is studied. We use the JKR theory and account for the increase of adhesion by capillary force. The effects of electrostatic forces and nonlinear hydrodynamic drag are included in the analyses. The criteria for incipient rolling and sliding detachments and electrostatic lifting removal are evaluated. A turbulence burst model is used for evaluating the peak air velocity near the substrate. The critical shear velocities for detaching particles of different sizes under different conditions are evaluated. The electric field strength needed for electrostatic removal of particles with different charges is also estimated. The results are compared with those obtained in the absence of the capillary force. Comparisons of the model predictions with the available experimental data are also presented. 相似文献
93.
基于分级型模数转换器AD7884对分离脱落电连接器的分离力进行测量,采用8位单片机W77E58与之接口,进行数据处理并通过485串口传输到上位机。实现了对分离脱落电连接器的分离力进行测量,系统运行稳定,且与上位机数据交互简单、可靠。 相似文献
94.
浅析SRT-Ⅳ裂解炉炉管弯曲及断裂原因 总被引:1,自引:0,他引:1
主要分析计算了裂解炉炉管受力情况,进而得出结论:裂解炉自身结构的相互约束力和炉管渗碳是导致炉管弯曲、断裂的主要原因,并提出了相应的解决措施。 相似文献
95.
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97.
Brominated poly(isobutylene-co-4-methylstyrene) (BIMS) is a synthetic terpolymer which can be stoichiometrically cross-linked by N,N′-dicinnamylidene-1,6-hexanediamine (DIAK). The degree of cross-links on bulk samples was determined by measuring the low frequency shear modulus with parallel plate method. The surface modulus of the same samples was measured using a new method, shear modulation force microscopy (SMFM). The moduli of the bulk sample and the surface were found to have the same scaling with the cross-link density, and good agreement with rubber elasticity theory was obtained in both cases. The SMFM was then used to monitor the cross-linking process, as a function of DIAK concentration and curing time, in thin films where standard rheological methods cannot be applied. The results show that in all cases the cross-linking reaction at the surface reaches saturation in less than 10 min as compared to at least 1 h in the bulk samples. 相似文献
98.
Matthew F. Paige 《Polymer》2003,44(20):6345-6352
Three different forms of atomic force microscope (AFM) measurement, topography, friction force and phase imaging, have been used to investigate the surface morphology and local composition of an immiscible polystyrene (PS)/poly(methyl methacrylate) (PMMA) blend film. This sample forms discrete, micron-size domains in a continuous matrix, which is attributed to the segregation of PMMA in PS. When the samples were imaged in air, contrast in friction and phase images was caused by variations in sample topography only. When the samples were imaged under water, however, both friction and phase imaging yielded non-topographic contrast between domains. We ascribe the contrast in both of these imaging modes to preferential softening of the hydrophilic, PMMA-rich domains and to stronger tip-sample adhesive forces, highlighting the AFM's utility for probing local elastic properties and for compositional mapping of soft polymer samples. 相似文献
99.
Both confocal Raman microspectroscopy and atomic force microscopy (AFM) have been undertaken to study the crystalline and the morphological aspects of cast PA 6 films at a sub-microscopic scale. The percentages of the different crystalline structures present within PA 6 cast films, i.e. the monoclinic α, the pseudo-hexagonal β, and the monoclinic γ, have been measured by confocal Raman microspectroscopy. In cast films, the prevailing structure is the β one. AFM has been used to characterize the morphology of the PA 6 films. Simultaneously, the deformed state has been considered as well. Our main interest has been to follow the evolution of the percentage of each crystalline structure as a function of the plastic deformation mechanisms which are responsible of the yielding of PA 6 films: shear banding for temperatures T lower than 160 °C and formation of fibrils for 相似文献
100.
Structured dispersion particles suitable for pressure sensitive adhesives (PSA) were synthesized via swelling polymerization technique (EP 359562). Particles consisting of poly(n‐butyl acrylate) copolymerized with different types of carboxylic acids were used as seeds. The final particles were synthesized by swelling polymerization process, using 6 wt % styrene or 6 wt % methyl methacylate. The resulting particle morphology was analyzed by atomic force microscopy (AFM) and transmission electron microscopy (TEM). From previous works (Coll Surf A 2001, 183–185, 725–737; J Appl Polym Sci 2004, 91, 2610–2623) where two‐step emulsion polymerization was used on similar particles, it is expected that the particle morphology is affected by the polarity of the monomer used for swelling polymerization because of the phase compatibility (thermodynamic parameter). In this work, the seed particles used were always of a glass transition temperature (Tg) below polymerization temperature. The diffusion of the growing polymer chains from the swelling polymerization is therefore mainly affected by their own Tg and the influence of the carboxy groups on the chain length of the entering radicals (kinetic parameter). The different morphologies of the single particles are discussed qualitatively. The effects of reaction parameters are compared with the results given in the previous work. The structure of the corresponding dispersion films was characterized using AFM. Correlations to macroscopic properties such as the cohesive strength and peel adhesion to different substrates are discussed. The results are also compared with the application properties of the corresponding unmodified particles, statistical copolymers, and to blends with small sized PMMA or PS particles. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 1444–1455, 2006 相似文献