改性Raney Cu催化一乙醇胺脱氢合成甘氨酸

一乙醇胺在氢氧化钠的水溶液中〔w(NaOH)=12%～18%〕,用含有铬和锗等贵金属改性的RaneyCu催化剂脱氢合成甘氨酸。反应温度150～180℃,反应压力0 8～1 2MPa,反应时间2～4h。实验结果表明:改性RaneyCu催化剂比普通RaneyCu有更好的活性和使用寿命,使一乙醇胺的平均转化率从92%提高到97%,有效使用寿命(一乙醇胺的转化率≥90%)从5次延长到15次以上。     

对ADSL接入方式铜缆可用线对率的分析

指出了为发展ADSL而提高市话音频铜线电缆的传输质量和维护水平的必要性,分析了铜线电缆线对有关指标参数低劣的原因和对传输ADSL的影响,并提出了一些改进的意见。     

离心浇铸法制备光谱控制样的分析研究

本文研究了应用高频熔化、冶炼、离心浇铸成型新技术,制备光谱控制样的方法及可行性,研究证明,利用本方法制备出的光谱控制样表面光洁度高,均匀性好,且组织结构和基体成份与分析试样一致,可用于光谱分析中工作曲线的校准和质量控制.     

Rendering of Surface and Volume Details in Volume Data*

Aiming at the detail rendering in volume data, a new volume illumination model, called Composed Scattering Model (CSM), is presented. In order to enhance different details in volume data, scattering intensity is decomposed into volume scattering intensity and surface scattering intensity with different weight functions. According to the Gauss probability distribution of gray and gradient of data, we propose an accurate method to detect the materials in a voxel, called composed segmentation. In addition, we discuss the principle of constructing these weight functions based on the operators defined in composed segmentation. CSM can generate images containing more details than most popular volume rendering models. This model has been applied to the direct volume rendering of 3D data sets obtained by CT and MRI. The resultant images show not only rich details but also clear boundary surfaces. CSM is demonstrated as an accurate volume rendering model suited for detail enhancement in volume data sets.     

Copper phthalocyanine as corrosion inhibitor for ASTM A606-4 steel in 16% hydrochloric acid

A study based on the corrosion inhibition properties of copper phthalocyanine is described. Coverage degrees of copper phthalocyanine (Cu-phcy) on ASTM-A606-4 steel, obtained by weight loss measurements, were fitted to Langmuir, Frumkin, Temkin and Flory–Huggins adsorption isotherms. A better fit to the Langmuir isotherm was obtained. The polarization curves showed that polarization of both the anodic and cathodic reactions were verified for concentrations higher than 10^–4 M, indicating a mixed type action. Only the anodic reactions were polarized for lower concentrations. At high frequencies the Nyquist diagrams showed one capacitive loop attributable to double layer charging and a small one at intermediary frequencies attributable to the faradaic process of hydrogen evolution. The formation of an adsorbed film was characterized by increasing charge transfer resistance values in the low frequency range for increasing inhibitor concentrations. According to the techniques used in this study, copper phthalocyanines showed a high corrosion inhibiting efficiency for all concentrations.     

孔径法测量铜带残余应力的试验研究

介绍了用于薄板残余应力测量的新方法——孔径法,该方法是通过测量冲孔直径的变化来间接求出各方向的残余应力;文中详细阐述了残余应力的标定方法;由于可针对不同材料建立了被测材料的平均应力(σ_l)与被测板材宽度(B)、厚度(H)以及冲孔后直径变化率(△D_i/D)之间的数学模型,因而使薄板残余应力测量变得简便而经济;此外还对该方法的分辨率与测量精度进行了实验、计算与分析。     

小方坯连铸机的PLC自动控制

本文对弧型小方坯连铸机工艺与设备进行了分析，介绍了连铸生产的ＰＬＣ控制系统。及其软件设计。     

铅黄铜水平连铸棒材熔铸工艺的试验研究

在工业生产条件下，对影响HPb59－1水平连铸律材热轧开裂的熔铸工艺进行了试验研究．取三个熔铸工艺因素：铸造速度、冷却水压力、冷却水温度．试验结果表明；铸造速度对热轧开裂影响极为显著，使其控制在410mm／min左右可获得较为理想的效果．     

Gildes model studies of aqueous chemistry. III. Initial SO2-induced atmospheric corrosion of copper

The GILDES computer model, incorporating Stumm's concept of proton- and ligand-promoted dissolution, has been used to simulate the exposure of copper at room temperature to 210 ppb sulfur dioxide and 80% relative humidity. The agreement is good between the calculations and laboratory exposures performed under these exposure conditions. Surface reactions are relatively more important at lower relative humidities and the dominant corrosion products formed are solid state Cu₂SO₃, CuSO₃ and Cu₂U. Free-radical redox processes are important participants and control the relative distribution of Cu(I)- and Cu(H)-containing corrosion products.     

铜蒸汽激光器双闸流管触发系统的研究

研制成用于钢蒸汽激光器的双间流管触发系统。用两个闸流管并联进行交替触发，总输入电功率达7．8kW。低功率运行时，激光器的效率为0．6％与单间流管激光器的效率一致。