Failure Analysis of Fuel System Assemblies

Fuel system assemblies used on recreational watercraft failed after a short time in service in a seawater environment. Examination of the assemblies revealed significant degradation of the polyacetal connectors of the wire subassemblies. Optical and microscopic evaluations indicated the complete loss of connector material implying decomposition of the resin, along with mud-cracking and a rough surface morphology signifying chemical attack. An elemental analysis performed on both an intact connector and degraded connector suggested a potential chemical agent in the form of zinc chloride. At elevated temperatures, concentrated zinc chloride solutions are known to decompose polyacetal resins. The source of the zinc chloride was established as corrosion products that resulted during the dezincification of the internal brass connector through exposure to saltwater in the application.     

Austenitizing treatment influence on the electrochemical corrosion behavior of 0.3C-14Cr-3Mo martensitic stainless steel

Effects of austenitizing treatment temperatures on aqueous corrosion properties of martensitic stainless steels were investigated by electrochemical tests (potentiodynamic test, potentiostatic test and electrochemical impedance spectroscopy), and surface analyses (optical microscopy and XRD). The results of potentiodynamic test revealed that the breakdown potential increased with the increased austenitizing temperature, indicating increased relative resistance to initiation of localized corrosion. EIS measurements showed that MSS3 (1030 °C) exhibits larger polarization resistance value than MSS1 (970 °C) and MSS2 (1000 °C) at passive and breakdown states. This was caused by decreasing the amount of Cr-rich M₂₃C₆ carbide which acts as preferential sites for pitting corrosion.     

曙光油田超稠油井套管损坏的机理和防治

超稠油特殊的油藏特点决定了其生产周期短、注汽频繁、出砂、汽窜、超覆现象严重，以及套管质量等因素的影响，套管损坏较为严重。对曙光油田超稠油井套管损坏的规律和机理进行了研究，并从钻井和完井工艺的完善、套管钢级和射孔工艺的选择、采油生产参数的确定、注汽管柱隔热效果的提高、防治砂工艺等方面，对套管损坏提出了预防措施和对策。并对套管损坏井制定了修复再利用方案。     

复合绝缘子耐电腐蚀特点及其电蚀老化区域性的差异

为了了解复合绝缘子外绝缘材质电蚀老化状态和区域性的差异,对Al(OH)3耐电腐蚀机理、外绝缘材质中Al(OH)3颗粒分布状态和环境污湿因素的实际情况进行了研究。Al(OH)3颗粒分解成水蒸气、析出白色粉末状氧化铝,并催化生成二氧化碳,将使外绝缘材质逐渐微观减薄和加大表面的粗糙度,而引起电蚀老化的污湿环境因素,近期不可能得到改善,因此必然引起其电蚀老化出现区域性差异。此外,外绝缘憎水表面污珠场强变化引起的电晕也是促使电蚀老化的重要因素。     

复合内衬在燃油加热炉中的应用

对导热油加热炉炉壁温度升高的原因进行了分析,介绍了新型复合内衬的特点,并对其技术特点、施工工艺及应用效果进行了简单阐述。     

油墨用聚氨酯胶粘剂的性能研究

主要研究用于印刷油墨的单组分溶剂型聚氨酯粘合剂，考查聚合物多元醇类型对树脂微观形态、机械性能以及印刷适应性和附着性等性能的影响。研究结果表明，聚酯型树脂的微相分离程度低于聚醚型，具有较好的机械性能、印刷适应性和附着性。     

两栖装甲装备新型防腐材料的研究

沿海地区特殊海洋环境造成装甲装备的严重腐蚀,为了研制一种新型的耐蚀有机涂层,该文作者研究了有机硅改性环氧树脂的化学反应,并对改性树脂的性能进行了测试分析.结果表明,改性树脂克服了环氧树脂的耐温性差、亲水性强以及盐水渗透率高的性能缺陷,为进一步制备该地区装甲装备防腐涂料奠定基础.     

Corrosion Control by water‐soluble extracts from leaves of economic plants

Water extracts from leaves of date palm, phoenix dactylifera, henna, Lawsonia inermis, and corn, Zea mays, were tested as corrosion inhibitors for steel, aluminum, copper and brass in acid chloride and sodium hydroxide solutions using weight loss, solution analysis and potential measurements. The inhibition action was found to critically depend on metal type and solution composition. Only, date palm and henna extracts were found highly effective in reducing corrosion rate of steel in acid chloride solutions and aluminum in sodium hydroxide solutions. The inhibition efficiency increased with increasing the concentration of the extract. The inhibition was interpreted in terms of chemisorption of some active ingredients in the leaves according to Temkin isotherm.     

液化气铜片腐蚀原因及解决措施

本文就引起液化石油气（LPG）铜片腐蚀不合格的原因进行了分析，对JX－1A精脱硫剂工业应用效果进行了探讨，结果表明JX－1A精脱硫剂在解决了LPG铜片腐蚀不合格方面有很好的效果。     

含氮杂环季铵盐缓蚀剂在CO2-3%NaCl溶液体系中的电化学行为

为控制CO2腐蚀，合成了含氮杂环季铵盐缓蚀剂9912-1，通过电化学实验，研究了该缓蚀剂在CO2-3％NaCl-H2O体系中对碳钢于25℃和90℃下的缓蚀行为。实验结果与挂片失重法测试的结果基本一致。低温下缓蚀效果优于高温下的缓蚀效果。而且该缓蚀剂与硫脲有很好的协同效应。Tafel曲线表明，该缓蚀过程是以控制阴极腐蚀为主，并对其缓蚀机理进行了初步探讨。