削弱或抑制抗氧剂、光稳定剂作用的有关因素

介绍了削弱或抑制抗氧剂、光稳定剂作用的常见因素及实例，分析了防老化塑料制品发生提前老化现象的可能性和原因。     

Molecular motions of non-crystalline poly(aryl ether-ether-ketone) PEEK and influence of elecron beam irradiation

The dynamic mechanical relaxation of non-crystalline poly(aryl ether-ether-ketone) PEEK and the one irradiated with electron beam were studied. The three distinct γ, β, α′ relaxation maxima were observed in unirradiated PEEK from low to high temperature. It was revealed from the study on the irradiation effects that three different molecular processes are overlapped in γ relaxation peak, i.e., molecular motion of water bound to main chain (peak temperature; at ?100°C), local motion of main chain (at ?80°C), and local mode of the aligned and/or oriented moiety (at ?40°C). The β relaxation connected with the glass transition occurred at 150°C and it shifted to higher temperature by irradiation. The α′ relaxation which can be attributed to rearrangement of molecular chain due to crystallization was observed in unirradiated PEEK ～ 180°C and its magnitude decreased with the increase in irradiation dose. This effect indicates the formation of structures inhibiting crystallization such as crosslinking and/or short branching during irradiation. A new relaxation, β′, appeared in the temperature range of 40° to 100°C by irradiation and its magnitude increased with dose. This relaxation was attributed to rearrangement of molecular chain from loosened packing around chain ends, which were introduced into the non-crystalline region by chain scission under irradiation, to more rigid molecular packing, From these observations, we proposed that deterioration in mechanical properties of non-crystalline PEEK by high energy electron beam was brought about not only by chain scission but structural changes such as crosslinking and/or branching in the main chain.     

Transient and isotopic studies of the oxygen transport and exchange during oxidative coupling of methane on Sr promoted La2O3

Isotopic transient techniques were applied to study oxidative coupling of methane over lanthanum oxide and strontium promoted La₂O₃ catalysts. Results of the¹⁸O₂/¹⁶O₂ isotopic exchange experiments indicate that Sr promotion increases oxygen uptake from the lattice of the catalyst. Oxygen self diffusion coefficients, which were determined for the series of lanthana catalysts, reach a maximum for the 1% Sr/La₂O₃. Steps of¹⁸O₂ in the presence of a steady flow of methane over Sr/La₂O₃ catalysts, indicate that surface and bulk oxygen appear in the reaction products before gas-phase¹⁸O². Steps of CO₂ over catalysts in which lattice oxygen has been exchanged with¹⁸O₂, show that gas/solid exchange involves over 50% of the lattice oxygen. Under reaction conditions, methane pulses with no gas-phase oxygen yield negligible amounts of products which indicates that methane interacts with lattice oxygen only in the presence of the gas-phase oxygen.     

大口径光学透镜瞬态温度场模拟

为考察热辐射效应对光学元件稳、瞬态温度场的影响,给出了考虑辐射和导热耦合换热情况下复杂几何结构光学透镜稳、瞬态热特性的适体坐标下离散坐标法.对喷管形和圆柱形介质进行计算并与其他方法比较表明,建立的适体坐标系下辐射与导热耦合换热计算方法精度较好.对两端为球缺中间为圆柱的大口径透镜内的辐射与导热耦合换热过程进行了数值模拟.计算结果表明,为了精确地预测半透明介质如透镜内的温度分布,应该考虑辐射与导热耦合作用,且应当考虑介质的光谱特性.     

锡崖沟瀑布景观工程水力模型试验研究

根据锡崖沟景区规划设计,沿锡崖沟水库溢洪道下部开凿底洞引水,在水库下游红岩大峡谷常年形成20 m宽大瀑布.以满足瀑布流的重力和紊动阻力相似的原则进行了其正态模型设计.通过模型放水试验表明：流量变化对瀑布水流流态影响很大,溢流槽空间狭小,加之上游进口扇形扩散段扩散角偏大,水流扩散不充分,堰顶溢流不均匀,瀑布景观效果差.将模型的溢流堰顶修改为T型复式断面后,顺应了水流的流动特性,在各级流量下均能获得比较好的瀑布景观效果.     

Formation mechanism of subtrenches on cone-shaped patterned sapphire substrate

In this paper, the cone-shaped patterned sapphire substrates (PSS) were etched by an inductively couple plasma with BCl 3 as the reacting gas. The influence of the operating pressure and the RF bias power on subtrenches of the cone-shaped PSS and the formation mechanism of subtrenches were investigated. The profiles of patterns were characterized by FESEM (field emission scanning electron microscope). It showed that the subtrench size varied with the operating pressure and the RF bias power. As the operatin...     

FEM analyses for influences of stress corrosion and pressure solution on THM coupling in dual-porosity rock mass

With the models of stress corrosion and pressure solution, by Yasuhara et al., two computation conditions were designed for a hypothetical nuclear waste repository in an unsaturated dual-porosity rock mass: (i) the fracture apertures are changed with the stress corrosion and pressure solution (the porosity of rock matrix is also a function of stress); (ii) the fracture apertures and the porosity of rock matrix are constants. Then the corresponding two-dimensional FEM analyses for the coupled thermohydro-mec...     

军工院校大学文化与大学发展耦合度评价实证分析

大学文化在现代大学发展中的作用越来越突出,已成为提升大学核心竞争力的重要因素,越来越多的大学把大学文化建设作为学校建设的重要组成部分.因此,大学文化建设的效果评价十分重要.通过建立"大学文化与大学发展耦合度"评价模型,对军工院校大学文化建设的效果进行实证分析.结果表明,哈尔滨工程大学的大学文化与大学发展之间的耦合度较高,耦合作用较强,大学文化在促进学校自觉肩负服务国防使命、实现自身发展目标中的作用明显,大学文化系统与大学发展系统之间呈正相关关系.     

基于积分法的热非平衡效应下剪切液膜流的表面波演化模型

当液膜表面同时存在热非平衡效应和切应力作用时,引发液膜流动不稳定的扰动及其影响将更为复杂。基于边界层理论,通过建立气液界面受热非平衡效应和切应力耦合作用的液膜流动的理论模型,采用包含弱非线性项的积分法,推导出热非平衡效应下剪切液膜流的表面波积分演化模型,模型中包括了相变强度、切应力、雷诺数和倾斜角度等不同参数的影响,为分析复杂边界条件下的液膜流的演化特征和稳定性提供了一种可借鉴的理论模型。     

Antioxidizing component,musizin, inrumex japonicus houtt

A substance with antioxidant properties was obtained from the hexane extract of roots ofRumex japonicus Houtt. The active component of the hexane extract was isolated and characterized as 2-acetyl-1,8-dihydroxy-3-methyl naphthalene, trivially named musizin (MUS). The antioxidant activities of MUS in six types of fats and oils were higher than that of butyl hydroxyanisole (BHA) and δ-tocopherol (δ-TOC). Together, TOC and MUS have a synergistic effect, because comparable amounts of either had lower antioxidant activity than various combinations of the two antioxidants. When we studied the antioxidant properties of a mixture of MUS and δ-TOC with methyl linoleate (MeLH), we found that the rates of destruction of the two antioxidants were comparable, but that their destruction occurred sequentially, with MUS first followed by δ-TOC, after which the oxidation of MeLH quickly occurred. Comparison of the antioxidant activity of MUS and its analogs suggests that only one of the two hydroxyl groups in MUS is involved in its antioxidant activit. Intermolecular hydrogen bonding may be involved.