无氰解吸工艺生产实践

结合生产实践讨论分析了影响载金炭解吸工艺指标的主要因素，介绍了无氰解吸工艺应用效果。     

The desorption of O2 during NO and N2O decomposition on Cu- and Fe-zeolites

The decomposition of NO and of N₂O over a CuZSM-5 zeolite and a Fe-mordenite, respectively, has been studied using tracer techniques. The results demonstrate the high mobility of the lattice oxygen ions in self-diffusion. They afford a possible explanation for the problem of how two extralattice oxygens located at positions remote from each other may combine to form the O₂ molecules which are spontaneously desorbed in these redox reactions. They show that a portion of the lattice oxygen mixes into the O₂ released on decomposition. The data also show that N¹⁸O and N₂ ¹⁸O undergo exchange with the catalyst oxygen under reaction conditions.On leave from Central Research Institute for Chemistry, Hungarian Academy of Sciences, H-1525 Budapest, Hungary.     

Mechanism of iodine vapor sorption in polyacetylene

Simultaneous measurements of weight uptake and conductivity variation during iodine vapor sorption of polyacetylenes (PA) at 20–25°C show that the sorption is a two-stages process. For the first stage, iodine diffusion to the fibrilar surface of the cis-rich and trans-rich PA is of Knudsen type pore diffusion as supported by the sorption measurements of hexane for the cis-rich PA, and has a diffusion coefficient in the order of 10⁷ cm²/sec. Conductivity of the PA rises rapidly and reaches a maximum at end of the stage. For the second stage, the diffusion is more restrictive and has a diffusion coefficient lower than the first stage by a factor of about 10 due to multilayer sorption of iodine, which leads to a decrease in the pore diameter and therefor the diffusion rate. In addition to the restricted diffusion in the second stage, diffusion of the iodine molecules adsorped on the fibrilar surface into the interior of the fibrils is appreciable for cis-rich PA (leading to a conductivity drop) and is negliglible for tran-rich PA (leading to insignificant variation in conductivity).     

RFCC吸收稳定系统改造

吉林油田炼油厂RFCC装置吸收稳定系统的干气中C3以上组分含量较高，损失大量的液化气，通过改造解吸塔的进料方式，吸效降低了解吸塔的温度，降低了干气中C3以上组分的含量，提高了液化气的收率，每年可增加经济效益280多万元。     

SMF-425树脂吸附和解吸铼的研究

研究了SMF-425型阴离子交换树脂在弱酸体系中吸附、解吸铼的性能和机理，结果表明，[H^ ]在0.1～1.0mol/L范围内，对铼的吸附有利，吸附平衡服从Freundish吸附等温式，吸附反应吸热，温度越高越有利于吸附。每g干树脂对铼的静态和动态饱和吸附容量分别为169.31mg、175.43mg。用2mol/L硫氰酸铵作淋洗剂，流速为2mL/min时，淋洗效果较好，结果令人满意。     

Ti-Mo合金的氢化物热解析动力学研究

本文对不同钼含量的钛钼合金Ti(1-x)Mox(x=3,11,20,33,50,at%)氢化物的热解析动力学进行了研究, 在高真空金属系统中测试了合金氢化物热解析量随时间的变化关系,应用反应速率分析方法计算了解析速率常数和表观活化能.研究结果发现,氢化物的热解析过程可用一级反应速率方程来描述,而氢原子在合金体相中的扩散是热解析过程的控速步骤.热解析表观活化能随Mo含量的增加而减小,说明氢化物的热稳定性随Mo含量的增加而降低.     

Study of Desorption Agent for LADS Process

This article refers to the procedure for selection, evaluation and development of the LADS-D desorption agent associated with the LADS-A adsorbent used in the non-hydroprocessing adsorptive desulfurization (LADS) process for FCC naphtha developed by LPEC Refining Research Institute. The LADS-D desorption agent can effectively remove the sulfides adsorbed on the LADS-A adsorbent. The saturated LADS-A adsorbent can be instantly regenerated by the LADS-D desorption agent to recover its adsorption activity. The LADS-D desorption agent can not only effectively remove all impurities adsorbed on the adsorbent, but also has strong ability to dissolve the impurities to keep a stable desorption efficiency of adsorbent to be basically commensurate with fresh adsorbent after extended use.     

High-temperature properties of the Bi-Sr-Ca-Cu-O system: Simultaneous occurrence of melting, oxygen desorption, and a metal-insulator transition

We have investigated the temperature dependence of the electrical transport and the thermogravimetric properties, from -200°C to +1000, of the Bi-Sr-Ca-Cu-O high-temperature superconductor. We conclude that this system has a cooperative, simultaneous-melting/oxygen desorption/metal-insulator transition that occurs near 900°C. We speculate on its nature and on its relationship to phenomena found in other high-T _c superconductors.     

A Strategy of Liquid-Grafted Slippery Sponges with Simultaneously Enhanced Absorption and Desorption Performances for Crude Oil Spill Remediation

Crude oil spill accidents pose a worldwide environmental threat. Oleophilic and hydrophobic absorbents that can selectively absorb oil from water have shown promising application potential in oil spill remediation. Simultaneous optimization of the absorption and desorption speed of absorbents towards oil is highly desirable for their recyclable usage, but remains a great challenge, because these two properties are generally conflicting. Here, a facile and ingenious strategy is proposed to tackle the above challenge via surface modification of porous sponges with highly flexible linear polydimethylsiloxane (LPDMS) brushes. The LPDMS brushes feature liquid-like properties at room temperature owing to its extremely low glass transition temperature, and act as a covalently-grafted lubrication layer throughout the 3D network channels of the sponge, which can minimize contact angle hysteresis and reduce friction between oil and sponge channel. Compared to the prevalent cross-linked polydimethylsiloxane (CPDMS) modification strategy, sponges modified with LPDMS brushes not only shows significantly enhanced absorption speed, but also exhibits superior desorption dynamics towards viscous crude oils. The design strategy of slippery sponges with liquid-like molecules may open a new avenue for developing advanced absorbents with simultaneously enhanced absorption and desorption performances for liquid separation and purification applications.