GH4169缺口件多轴加载下应力应变场的有限元分析

采用GH4169缺口试件在650 ℃下进行了高温拉扭疲劳断裂试验,利用ANSYS 6 1 有限元分析软件计算试件缺口周围的应力应变场,确定出试件在各种载荷状况下的应力集中系数。计算结果表明,该有限元建模方式是合理的,为以后缺口件的寿命预测过程奠定了基础。     

基于等幅周期荷载下软岩Bingham本构模型的研究

为建立一种描述等幅周期荷载下软岩应变特性的本构模型,将Bingham模型中的常值黏壶元件替换成与循环次数相关的变系数黏壶元件,常值弹性元件替换为随周期荷载循环次数的增大而衰减的非定值弹性元件,即可得到反映周期荷载下软岩各种应变规律的Bingham本构模型。当循环荷载应力上限值σmax大于岩石的临界强度σs时,模型为可反映软岩3个应变阶段的改进4参数Bingam模型;反之则为反映软岩前两个应变阶段的非常值2参数Hook模型。将周期荷载分解为一个定值荷载和一个平均应力值为零的周期荷载,基于流变力学理论给出了定值荷载作用下基于该模型的本构方程式,再根据黏弹性力学理论,给出了平均应力值为零的周期荷载下基于该模型的本构方程式,最后将已获得的本构方程式叠加即得到周期荷载下软岩本构方程式。结果表明:所建立的本构方程式可较好描述周期荷载下不同软岩各类应变特征,对各类软岩的应变曲线拟合的相关系数均在0.868以上,且同一种岩石模型中弹性元件系数初始值随周期荷载的动应力幅值的增大而减小,岩石加速应变速率参数随动应力幅值的增大而增大。     

循环荷载作用下重塑饱和粉黏土的刚度弱化特性研究

以东海大桥海上风电场项目为课题背景,通过动三轴系统对重塑饱和粉质黏土开展一系列长期不排水循环加载三轴试验,分别考虑围压、动应力比和频率3种因素,特别是对高频(f5 Hz)下土体的动力弱化特性进行了研究。试验结果表明:累积塑性应变与累积孔压随着循环次数的增加而增大并且趋于稳定,呈现出应变软化和孔压软化现象。割线动变形刚度模量和割线动弹性刚度模量则随着循环次数的增加,先急剧降低然后趋于稳定,从而表现出刚度弱化现象。进一步研究了割线动弹性刚度模量与循环应变幅值的关系,割线动弹性刚度模量的衰减趋势受动应力比和频率的影响不大,与围压有关,围压越大,割线动弹性刚度模量衰减趋势越慢,衰减稳定幅值越低。     

制氢装置转化催化剂失活原因分析及对策

中石化西安分公司制氢装置转化催化剂在短期生产运行过程中,因催化剂积碳导致转化炉管表面出现大面积花斑,近半数炉管出现红管,炉管差压增大,转化出口甲烷含量超标,芳烃穿透.对催化剂失活原因进行细致分析后表明:装置开停车频繁;转化催化剂多次积碳-烧碳使催化剂表面剥蚀破碎、跑损严重为主要原因.针对失活原因制定了相应对策.     

Activation of a Au/TiO2 Catalyst by Loading a Large Amount of Fe–Oxide: Oxidation of CO Enhanced by H2 and H2O

Catalytic activity of a 1 wt% Au/TiO₂ catalyst is markedly improved by loading a large amount of FeO_x, on which the oxidation of CO in excess H₂ is selectively promoted at temperature lower than 60 °C. Oxidation of CO with O₂ on the FeO_x/Au/TiO₂ catalyst is markedly enhanced by H₂, and H₂O moisture also enhances the oxidation of CO but its effect is not so large as the promotion by H₂. We deduced that activation of Au/TiO₂ catalyst by loading FeO_x is not caused by the size effect of Au particles but a new reaction path via hydroxyl carbonyl intermediate is responsible for the superior activity of the FeO_x/Au/TiO₂ catalyst.     

Effect of alkali and ultraviolet (UV) radiation pretreatment on physical and mechanical properties of 1,6‐hexanediol diacrylate–grafted jute yarn by UV radiation

To improve the physicomechanical properties of jute yarn, grafting with 1,6‐hexanediol diacrylate (HDDA) monomer was performed by a UV radiation technique. A series of HDDA solutions of various concentrations in methanol were prepared. A small quantity of photoinitiator (Darocur‐1664) was also added to HDDA solutions. To optimize the conditions for grafting, the effects of monomer concentration, soaking time, and radiation doses were studied by varying the number of soaking times along with variation of monomer concentrations and UV radiation intensities. The extent of polymer loading and the mechanical properties like tensile strength (TS), elongation at break (Eb), and tensile modulus of both treated and untreated jute were investigated. The highest tensile strength, polymer loading, and modulus were achieved with 5% HDDA concentration, 5 min soaking time, and the 4th pass of UV radiation. This set of conditions was selected as optimum and produced enhanced tensile strength (67%), modulus (108%), and polymer loading (11%) over those of virgin fiber. To further improve the mechanical properties the jute yarns were pretreated with alkali (5% NaOH) solution and after that the alkali‐treated yarn were treated under UV radiation of various intensities. The pretreated samples were grafted with optimized monomer concentration (5% HDDA). Increased properties of alkali + UV‐pretreated and grafted samples such as polymer loading (12%), tensile strength (103%), elongation at break (46%), and modulus (114%) were achieved over those of virgin jute yarn. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 92: 18–24, 2004     

A203型低温氨合成催化剂使用小结

对Ａ２０３型低温氨合成催化剂的使用进行总结，介绍了该催化剂的装填，升温还原情况及使用效果。     

花岗岩残积土-土工格栅界面的后循环剪切行为研究

花岗岩残积土在华南、东南沿海、南岳、新疆等地区广泛分布,前人的研究多集中在结构性及微观特性上,后循环加载、位移演化、土壤密度等因素对筋-土界面的剪切特性及加筋作用效果的影响评估研究较少。从循环试验剪切刚度这一重要参数入手,以加载次数、加载频率值、位移振幅值、土壤重度值为自变量,应用控制变量法,通过设计循环直剪试验,得到加筋花岗岩残积土的剪切应力与剪切位移、垂直位移与剪切位移关系曲线进行观察对比,结果表明:花岗岩残积土土工格栅界面剪切刚度受位移半振幅、土壤干重度影响很大,受加载频率影响很小,循环加载并没有弱化后循环界面剪切强度,剪切位移与位移半振幅呈负相关关系。     

设抗震增强体的桩基础力学特性的原位试验研究

在过去的大地震中,许多桩基础因强烈振动和地基变形而遭受结构性破坏,因而提出一种既可以应用于新建桩基础,也可以应用于现有桩基础的抗震加固方法,即采用地基加固技术在桩基础中设置抗震增强体,以与桩基础的钢筋混凝土承台形成双层抗弯结构。采用等比例模型原位水平载荷试验和振动试验以及开挖检查等方法,对抗震加固的力学特性和构建质量进行加固前后的对比研究,进而证实了该加固方法的有效性和可行性,为同类工程起到了一定的参考意义。     

An economic–ecological model to evaluate impacts of nutrient abatement in the Baltic Sea

This paper presents a coupled economic–ecological model that integrates a catchment model with a marine model and incorporates economic data to analyse the long-term economic and ecological consequences of nutrient abatement in the Baltic Sea. The spatially explicit model describes dynamics of soil phosphorus in arable land, developments of nutrient concentrations and phytoplankton biomass in the sea basins, and inter-annual variation in nutrient loads and biophysical processes. The performance of the model is demonstrated by computing the least-cost solution to reach the good environmental state of the sea – as implied by the Baltic Sea Action Plan – within a time span of 40 years. The total cost of achieving this target is 1487 M€ annually. Spatially optimal allocation of load reductions differs from the load reduction targets of the Baltic Sea Action Plan, and focuses more on the control of phosphorus loads.