Two-dimensional-growth small molecular hole-transporting layer by ultrasonic spray coating for organic light-emitting devices

Two-dimensional-growth small molecular organic thin film with high quality is fabricated by ultrasonic spray coating technology (USC) from the toluene solution of 4,4′,4″-tris (carbazol-9-yl) triphenylamine (TCTA). In comparison to the vacuum thermal evaporation (VTE) TCTA film, the USC-TCTA film obtained from liquid-phase solution possesses more uniform surface topography. The differences between the USC-TCTA and the VTE-TCTA in optical property, electrical property and formation mechanism are also studied in detail. Besides, to evaluate the hole transport and electron blocking ability of USC-TCTA film, the organic light-emitting devices (OLEDs) employing USC-TCTA film as hole transport layer are fabricated successfully. Additionally, the green OLEDs based on USC-TCTA film perform as well as the ones with VTE-TCTA film in current density, luminance, efficiency and color stability, and show even better tolerance to high bias voltage.     

纳米分子电子器件的研究

纳米分子电子器件是未来电子器件发展的重要方向。对几种典型的纳米分子电子器件,如纳米分子开关、纳米分子整流器、纳米分子晶体管、纳米分子电磁器件和纳米分子电光器件的工作原理、应用前景等方面进行了介绍,同时分析了各自的优势与问题所在。这一领域所遇到的主要挑战问题在于器件的可靠性与生产的高成本。目前纳米分子电子器件的发展趋势和研究重点是通过对器件原理的深入研究以及制备方法的不断探索,找到提高器件可靠性的方法以及解决降低成本和适应市场化的问题。     

空间均匀和非均匀场下H2+辐射谐波的空间分布

为了了解H₂+分子辐射谐波的空间分布,采用数值求解非玻恩-奥本海默近似的薛定谔方程,进行了空间均匀和非均匀激光场下H₂+分子谐波辐射的空间分布研究。结果表明,在空间均匀场下,正向H核辐射谐波强度高于负向H核;在空间非均匀场下,由于金属结构表面出现的等离子共振增强现象,谐波截止能量得到延伸;负向H核辐射谐波强度明显高于正向H核,随后通过电离几率、电子布局、电子波函数以及谐波辐射的时频分析可以给出H₂+分子谐波空间分布的合理解释。通过叠加谐波谱上的谐波,可获得一个脉宽为36as的超短孤立阿秒脉冲。该研究对分子谐波的空间分布及阿秒脉冲的输出是有帮助的。     

基于边缘探测技术的激光单稳频指标分析

基于边缘探测技术的激光雷达实际应用中,激光器在工作中发射光信号的中心频率会发生漂移,激光频率的漂移过大,会直接影响边缘探测系统的测量精度。采用仿真计算的方法得到碘分子吸收滤波器在470nm~550nm范围内的吸收光谱谱线,以基于边缘探测技术的激光雷达监测大气信道和海洋水下信道环境参数为例,得到适合大气和海洋探测吸收谱线并确定发射激光信号的中心频率。通过理论分析,给出了满足探测要求的激光发射信号单稳频指标,为实际探测系统的设计奠定基础。     

C20富勒烯分子及C±20富勒烯离子特性分析与比较

以C1对称C20富勒烯分子为模型,在Gussion03上做了结构优化、频率计算以及自然键轨道理论(NBO)计算,并在同样的方法和基组下分别对C20分子得失一个电子的情况做了计算,并进行了分析和比较.结果表明:C1对称C20富勒烯分子不稳定,易于得失电子而以离子形式存在.C20,C+20,C-20三者的能量关系为:EC2...     

极性分子多层修饰的金属Ni核心核壳微粒的电流变液

通过研究TiO2包覆不同极性分子修饰金属Ni核心核壳微粒的结构及其电流变液的性能,分析Ni/TiO2基核壳结构微粒电流变液性能与极性分子种类、复合修饰以及所加电场强度的关系。结果表明,对同成分电流变液随极性分子的加入,其强度均出现不同程度的增加,多层修饰利于电流变液剪切强度的提高,十二烷基苯磺酸钠(SDBS)可显著提高电流变液的沉降稳定性。     

极性小分子对Ni/TiO_2核壳结构电流变液性能的影响

通过力学性能试验、形貌观察,重点研究电流变液的核壳微粒Ni/TiO2用Urea等极性分子修饰对电流变液性能、形貌的影响。结果表明,极性小分子可大幅提高电流变液的性能,对Ni/TiO2/Urea微粒存在一个Urea/Ti临界值,其值的质量分数为30%。     

An organic hydrogel film with micron-sized pillar array for real-time and indicator-free detection of Zn

A hydrogel sensing film for a real-time and indicator-free detection of Zn²⁺ is developed by embedding a fluorescent indicator 11,16-bis(phenyl)-6,6,21,21-tetramethyl-m-benzi-6,21-porphodimethene in a hydrogel host poly(2-hydroxyethyl methacrylate). The sensing film shows high stability and selectivity to Zn²⁺. The sensitivity of the sensing film is increased by fabricating a micron-sized pillar array on the surface of the sensing film to increase the surface area. For Zn²⁺ concentrations of 10⁻⁴ and 10⁻³ M, the response time is 30 and 3 s, respectively.     

A new dithienosilole-based oligothiophene with methyldicyanovinyl groups for high performance solution-processed organic solar cells

A new linear dithienosilole-based oligothiophene end-capped with methyl and electron-withdrawing dicyanovinyl groups, DTS(Oct)₂-(2T-DCV-Me)₂, was prepared in good yield. This oligomer exhibited broad absorption spectra in bulk down to the near-IR region with the optical edge at 900 nm, resulting in an initially high power conversion efficiency of 5.44% in solution-processed organic solar cells using PC₇₁BM as an acceptor.     

基于功率型LED的在体整体荧光光学成像

用发光二极管（LED）替代常用的荧光激发光源汞灯,以实现基于LED的整体荧光光学成像（简称整体成像）。首先通过光谱计算分析,探讨了在不同波段与汞灯激发的荧光量相当时LED需要输出的光通量。以此为依据选择LED,构建了基于功率型LED的整体成像系统,用其动态监测绿色荧光蛋白（GFP）标记的肿瘤在裸鼠体内生长和药物治疗过程。实验表明,功率型LED可在类似于整体成像需要较大光功率的场合中应用。光源替代时,若两光源的光谱在选择的波段内分布不一样,则有必要考虑不同波长的光激发荧光效率差异的影响。