Catalyst instabilities during the liquid phase partial oxidation of methane

A promising catalytic system for the low temperature oxidation of methane to a methanol derivative has been investigated under both batch and semi-continuous operation in two different reactor types. The system comprises of a bimetallic palladium and copper(II) chloride catalyst contained in a trifluoroacetic acid (TFA) and an aqueous phase. Methane, oxygen and a co-reductant carbon monoxide constitute the gas phase. Typical operating conditions were a temperature of 85 °C and a pressure of 83 bar.

The yields of the methyl trifluoroacetate product observed in this present work were less than those obtained in other batch autoclave works, which employed only 4 ml of liquid phase, compared with 50 ml in this study. Furthermore, an encouraging initial product formation rate of ca. 40 mol/m³ h, quickly decreased after the first hour, and came to an apparent end after only 2 h. This observation had not been reported previously.

Work performed in a semi-continuous porous tube reactor (300 ml of re-circulating liquid phase) also showed the same reaction characteristics as in the batch reactor. Thus, the deteriorating product formation rate cannot be attributed to gaseous reactant depletion (batch operation). The results suggest problems associated with catalyst instabilities, e.g. with the previously elucidated Wacker chemistry.     

DDS技术在数字激光相位测距仪中的应用

本文介绍了直接数字合成(DDS)技术在激光相位测距仪中的应用。使用该技术研制的数字激光相位测距仪具有操作简便、携带方便、性能可靠的特点，测相精度优于干分之一。     

多模复合制导数据融合器性能评估系统方案设计

从构建多模复合制导数据融合器性能评估系统的需求出发，详细介绍了多模复合制导数据融合器性能评估系统的构建方案，并从软硬件两个方面介绍了构建这样一个系统所需要注意的问题和解决办法．     

原料酸卸车系统技术改进分析

分析了酸卸车系统存在的泵与管路的匹配、鹤管真空损失、酸腐蚀等技术问题，提出了鹤管的改进、卸车泵更新、真空系统水封、管路系统改进等保证真空能力的具体措施，实现了全自动、密闭卸车作业，最大限度地满足安全、快卸、底料少的要求。     

实施分销库管理的一些做法

介绍了中国石化山西阳泉石油分公司实施市县石油公司一体化管理体制的工作经验。其具体做法是：采取措施使思想、业务流程和服务与之接轨，开展创省级“青年文明号”活动和加强企业文化建设；实施两级绩效考核，工资与油品吞吐量挂钩；坚持以人为本，长短结合，立足基础，整体提升；用抓好培训、责任和制度的落实及监管，来强化基础管理的效果。     

南水北调中线水源工程的突变多准则评价

应用突变多准则评价法对南水北调中线水源工程项目的多方案比选作出评价决策。该方法为专家决策系统提供一种数学方法 ,以便用计算机实现多目标、多层次、多方案的评价决策。     

应用多抽样率信号处理实现SSB调制信号

在探讨了软件无线电的基本概念,基于软件无线电定义的发射平台结构及多抽样率数字信号处理的基本内容的基础上,着重探讨了软件无线电发射平台中多抽样率数字信号处理的应用,并以单边带调制信号(SSB)为例,指出与传统SSB产生方法不同的结构。     

Experience with Siberian Centralized Dispatch Regulation regarding location determination of damages sustained by intersystem high-voltage transmission lines

A set of measures that can be implemented by the Relay-Protection and Automated-Equipment Service for Centralized Dispatch Regulation (CDR) in Siberia to determine the location of damage sustained by inter-system 550-and 220-kV transmission lines maintained by the United Power System (UPS) of Siberia, and the methodology and technology of damage-location determination (DLD) are described. The damage sustained by the 500-kV high-voltage lines (HL), and the accuracy of DLD relative to zero-sequence emergency parameters are analyzed statically. __________ Translated from élektricheskie Stantsii, No. 5, pp. 59–62, May, 2006.     

一个新的具有指定接收者(t,n)门限签名加密方案

提出了一个具有指定接收考验证的签名加密方案。该方案是数字签名与公钥密码体制的有机集成。与普通数字签名方案相比，除了具有认证性、数据完整性外还具有保密性和接收方的隐私性。然后又利用门限方案首次构造了一个（t,n)门限签名加密方案。该(t,n)门限签名方案具有数据传输安全、顽健性、通信代价更小、执行效率更高等特点。     

Characterizing Performance Variation of Product Designs

Quality and reliability design practitioners have utilized Taguchi's methodology of matrix experimentation to generate computer simulation data for characterizing performance variation of product designs. However, the sampling strategy employed renders computer implementation of matrix experimentation cumbersome and statistically invalid. Weaknesses of this approach also include sample size limitation and overestimation of performance variation. An alternative approach that combines Monte Carlo simulation with the strategies of independent sampling across runs and correlated sampling between runs is presented. An application case study shows that the proposed approach constitutes an improvement on the matrix approach with respect to statistical validity and estimation accuracy.