三水草酸铀酰的红外激光化学

文章研究了三水草酸铀酰(UO_2C_2O_4·3H_2O)在兆瓦脉冲二氧化碳激光辐照下的红外激光化学反应,它与草酸铀酰的热分解反应不同,反应产物是二氧化铀和二氧化碳。反应的量子效率随激光波长不同而变化。     

激光导向伺服系统中满意PID调节器的LMI设计

利用带有图像处理功能的小型激光导向伺服系统,可以大大降低目标坐标测定仪操作手跟踪动态飞行目标的操作难度,从而提高激光回波率.与经典的矩阵分解方法不同,本文以线性矩阵不等式方法,研究了激光导向伺服系统的满意PID调节器设计问题.首先从约束指标的相容性出发,给出满足与给定圆形极点约束相容的输出方差的取值范围.然后,在此取值范围内,得到了求取同时满足上述两种约束的PID调节器参数的方法.靶场试验结果证明了其有效性.     

测距仪中新型的脉冲激光光源

针对现有测距仪中脉冲激光器存在寄生多脉冲的问题，提出并实现新型的采用同步泵浦声光调Q方法的测距仪用激光器、消除了寄生脉冲并提高了激光器的峰值功率。     

飞秒激光烧蚀研究进展

介绍飞秒激光烧蚀材料的机理论模型，阐述飞秒激光烧蚀的特性，揭示飞秒激光烧蚀的广泛应用前景。     

Synthesis and characterization of new thermally stable poly(ester‐imide)s derived from 2,2′‐bis(4‐trimellitimidophenoxy)biphenyl and 2,2′‐bis(4‐trimellitimidophenoxy)‐1,1′‐binaphthyl and various aromatic dihydroxy compounds

A series of new alternating aromatic poly(ester‐imide)s were prepared by the polycondensation of the preformed imide ring‐containing diacids, 2,2′‐bis(4‐trimellitimidophenoxy)biphenyl (2a) and 2,2′‐bis(4‐trimellitimidophenoxy)‐1,1′‐binaphthyl (2b) with various aromatic dihydroxy compounds in the presence of pyridine and lithium chloride. A model compound (3) was also prepared by the reaction of 2b with phenol, its synthesis permitting an optimization of polymerization conditions. Poly(ester‐imides) were fully characterized by FTIR, UV‐vis and NMR spectroscopy. Both biphenylene‐ and binaphthylene‐based poly(ester‐imide)s exhibited excellent solubility in common organic solvents such as tetrahydrofuran, m‐cresol, pyridine and dichloromethane. However, binaphthylene‐based poly(ester‐imide)s were more soluble than those of biphenylene‐based polymers in highly polar organic solvents, including N‐methyl‐2‐pyrrolidone, N,N‐dimethylacetamide, N,N‐dimethylformamide and dimethyl sulfoxide. From differential scanning calorimetry thermograms, the polymers showed glass‐transition temperatures between 261 and 315 °C. Thermal behaviour of the polymers obtained was characterized by thermogravimetric analysis, and the 10 % weight loss temperatures of the poly(ester‐imide)s was in the range 449–491 °C in nitrogen. Furthermore, crystallinity of the polymers was estimated by means of wide‐angle X‐ray diffraction. The resultant poly(ester‐imide)s exhibited nearly an amorphous nature, except poly(ester‐imide)s derived from hydroquinone and 4,4′‐dihydroxybiphenyl. In general, polymers containing binaphthyl units showed higher thermal stability but lower crystallinity than polymers containing biphenyl units. Copyright © 2005 Society of Chemical Industry     

反原形向量化与拟离散性

如何利用循环体诸如初值、终值、步长和下标式等数学对象的诸如恒等、正负、单调性一类的数学特征,按照严格推导出来的简单规则,绕过各种复杂的数据依赖关系图及其上诸如拓扑排序或等价变换等复杂的操作,直接从事向量化处理,这是极富实用价值的研究方向.文献[2,3,5]给出的可原形/准原形算法,以及本文的可反原形与拟离散性,正是这样的捷径.它们能使相当部分的常见循环,直接向量化.     

PTT直接酯化反应动力学研究

研究了不同温度下PTT(聚对苯二甲酸丙二醇酯)直接酯化反应动力学。建立了零级和一级反应动力学模型。用实验数据进行的检验表明,一级动力学模型更为接近该反应过程。     

Time Characterization of High Density Gas Jet from a Pulsed Supersonic Nozzle via Laser Produced Plasma

A high-density gas jet supersonic nozzle is reported in this paper. The jitter and actuation time of the nozzle is determined by the pin discharge and laser spark radiation respectively. The jitter time of the nozzle is within 10μs with the backing pressure as high as 25 bar. With a nanosecond laser pulse focused on the gas jet about 1 mm below the nozzle, the actuation time is calculated to be about 15 ms by detecting the laser produced spark radiation, which reveals the existence of the gas jet and the relative gas density evolving with time. Consequently the gas density is estimated to be well above 10^19 cm^-3, compared with theoretical simulations from the nozzle parameters.     

In‐Situ Observation of the Formation of MnS during Solidification of High Sulphur Steels

A Confocal Scanning Laser Microscope equipped with a gold image furnace was used to directly observe the precipitation of MnS during solidification of high sulphur steels under isothermal conditions in the temperature region 1440 to 1480°C on the free surface of the steel melt. For the case of Al‐killed steels, below 1480°C MnS particles were found to precipitate with Fe forming simultaneously around them. This MnS containing structure continued to grow rapidly (264 μm/s) as a surface film. The film gradually changed, as the level of S in the melt decreased, into a eutectic structure (with lamella spacing of 2 μm) as predicted by thermodynamics. In Si‐ killed steels there was significantly lower tendency to form MnS both in terms of time until precipitation occurred and growth rate.     

钛精矿回转窑直接还原过程结圈可能性的探讨

通过煤种，入窑球冷态强度和还原过程强度，以及钛精矿与煤灰混合物的软化温度等分析探讨了钛精矿预热球团回转窑直接还原产生结圈的可能性，获得了可以避免结圈的结论。