高能超声作用下数种金属基复合材料的制备及机制

利用高能超声振动制备了A l/陶瓷, ZA 22/陶瓷(粒子平均直径2L) ,A l/P b (Pb 粒子直径< 25L) 和A l/F eA l₃等金属基复合材料, 弥散相在基体中有良好的分布均匀性。依据超声波对熔体作用时的空化和声流效应, 讨论了上述数种复合材料的制备机制。试验结果显示, 该项技术在制备数类金属基复合材料方面具有广泛的适用性。     

In situ FTIR spectroscopy on rhodium-exchanged NaX zeolite with different metal dispersion during syngas reaction

In situ FTIR spectroscopy has been applied to study the reason of the different selectivity behaviour of rhodium in the CO hydrogenation reaction in dependence on the different particle size. Several forms of molecularly adsorbed CO are observed, such as linearly- and bridgedbonded CO on metallic rhodium as well as dicarbonyl species with Rh(I) centres formed by oxidation of Rh(0) with protons in presence of CO. Furthermore, non-reactive formate, acetate, and carbonate species are produced as side products of the reaction. The higher selectivity to oxygenates, particularly to methanol, is explained by the existence of multiple-bonded CO present only on small rhodium crystallites. The multiple-bonded CO formed at low temperatures is converted at higher temperatures to the highly reactive formyl species, which is hydrogenated to methanol.     

Colour extension properties of individual pigments and effects on shades of foundations in cake form

The mechanism of colour change during the pigment dispersion process and during powder application to the skin surface was studied by examining the colour extension properties of Yellow. Red , and Black iron oxides in white powder bases. A new measure for the evaluation of the degree of colour extension was devised. This measure corresponded well with human visual sensation, and was found to be useful for comparing the rates of colour extension of pigments. The rate of colour extension of pigments was found to vary in the order: Yellow acicular Red granular Red Black. This result explains colour darkening and the change towards reddish tones during the pigment dispersion process, because Yellow extends fully in the early stage of the process but Red , especially in granular form, and Black continue to extend even in the later stage. Acicular Red iron oxide is more favourably employed than the granular form to attain sufficient colour extension of foundations with lower energy expenditure, and to decrease the discrepancy between the cake colour and the colour of applied powder.
Le développement des oxydes de fer et effet sur les nuances des fonds de teint compacts     

长途传输波分复用系统的设计

随着波分复用（WDM）技术的广泛应用，在工程调测和系统的运行过程中出现了由于系统的适应能力较差和灵活性不够而引起系统优化时间过长的问题，给运营商带来了许多不便，同时，WDM已经由一般的长途应用向超长距离传输和城域网方面发展，适应性和灵活性成为WDM系统网络应用的主要要求，本文将介绍WDM系统的关键技术，重点论述WDM网络设计的一些原则，最后提出WDM系统设计的注意事项。     

高稳定度CPM飞秒激光特性的研究

利用最优化动力学参数的方法,获得了高稳定度的CPM飞秒激光器运转特性。激光器输出平均脉宽43fs,中心波长624nm,平均功率20mW,脉宽不稳定度±3.3％,频率不稳定度小于10~(-6)。     

一种可用于可调谐环行Ti：Al_2O_3激光器的宽带单向器

本文介绍一种宽带单向器的原理及设计。选用ＴＧＧ作磁旋光介质，旋光石英晶片作补偿片，所设计的色散补偿型宽带单向器预计可在７００～１０００ｎｍ波长范围内实现环行激光腔中的单向行波运行；将其应用在可调谐环行Ｔｉ：Ａｌ２Ｏ３激光器中，获得了良好的实验结果。     

基于类间分散度和类内集中度的文本特征选择。

特征选择是文本分类的关键步骤之一,所选特征子集的优劣直接影响文本分类的结果。论文首先定义了两种特征分类能力：一种是特征对类间文档的分散程度,该分散度越大越好;另一种是特征对类内文档的聚集程度,该集中度越大越好。然后把这两种特征影响度有机地结合起来设计了一个新的特征选择方法,该方法能够对所选特征进行综合考虑,从而使获得的特征集具有较好的代表性。仿真实验表明所提特征选择方法在一定程度上能够提高文本分类性能。     

电能变换领域中随机脉宽调制技术研究概况及展望

相较于传统的脉宽调制技术,随机脉宽调制具备有效的谐波频谱分散能力,从而实现机电负载噪声的削弱。随机脉宽调制技术包括起步的随机开关调制、后续的随机脉冲位置与随机开关频率等3个基本方法。随着电力电子技术的整体发展,随机脉宽调制已从传统的载波调制逐渐拓展到空间矢量调制之中,应用范围日趋广泛,谐波频谱分散与功率谱峰值抑制的效果不断提升。同时,新的优化方案不断被提出,对谐波频谱及功率谱的分散效果亦在不断提高。梳理了随机脉宽调制的研究历程,总结了数种典型的随机脉宽调制的基本原理,并对未来随机脉宽调制的研究方向作出展望,为随机脉宽调制技术的深入研究提供参考。     

30%三唑锡悬浮剂的研制及作用机理分析

[目的]解决30%三唑锡悬浮剂分散稳定性的问题。[方法]为提高30%三唑锡悬浮剂分散稳定性,采用流点法对不同类型的分散剂进行初步筛选并测试表面张力,通过测试SC粒径、Zeta电势、悬浮率、流变性能确定分散剂配比与用量并对分散稳定机理进行分析。[结果]与单一分散剂制备SC相比,聚羧酸盐分散剂SD-816和聚氧乙烯醚磷酸酯分散剂SD-208复配体系制备的SC性能较优,其表观黏度、Zeta电势、粒径和悬浮率分别为386 mPa·s、-37.2 mV、2.58μm及98.4%。并且提出了聚羧酸盐分散剂和聚氧乙烯醚磷酸酯分散剂对农药三唑锡可能的分散机理。[结论]聚羧酸盐SD-816和聚氧乙烯醚磷酸酯SD-208的复配体系可同时提供静电排斥作用和空间位阻,明显改善SC体系的悬浮稳定性。     

MGH956合金TLP连接机理及接头组织分析

MGH956合金是采用机械合金化方法制造的氧化物弥散强化高温合金，具有高温力学性能好、高温抗氧化和抗腐蚀性能好的综合优势。自行研制了中间层合金KCol进行MGH956合金过渡液相(TLP)扩散连接试验，分析了接头组织、成分和连接工艺的关系，确定了MGH956合金TLP扩散连接机理。同时，对MGH956合金焊接接头中产生的夹渣缺陷进行了深入的分析。结果表明：在连接温度1240℃、保温8h条件下，可以获得焊接缺陷少、完整连续的焊接接头。