Numerical study of the transfer of shock-wave loading to a screened flat wall through a layer of a powdered medium and a subsequent air gap

The two-velocity, two-temperature model with two stresses in a mixture of a gas and solid particles contacting each other is used to numerically study the dynamic effect of an air shock wave incoming onto a solid wall with a screening layer of a porous powdered medium at some distance from the wall. The process is described for the case of one-dimensional planar motion of the gaseous and disperse phases under the assumption of a viscoelastic behavior of the powder skeleton. The effect of stepwise shock waves onto the porous powdered screen is considered. The influence of parameters of the screening layer and the air gap on the dynamics of loading of the screened solid wall is analyzed. __________ Translated from Fizika Goreniya i Vzryva, Vol. 43, No. 1, pp. 132–142, January–February, 2007.     

Mixing in Wave Processes Propagating in Gas Mixtures (Review)

A review is made of uptodate investigations in the field of physicomathematical modeling of mixing of solid particles with highvelocity gas flows arising under the action on shock waves, compression waves, and expansion waves on unstable dust deposits on the boundaries of channels or plates and in cavities, as well as on free clouds of particles. In particular, experiments in shock tubes with particles initially located in cavities and on surfaces are described. The experimental data presented in the form of distributions of particle concentrations at various points of space above the unstable layer, pressure distributions on the lower wall of the shock tube, etc., are used for verification of proposed mathematical models in regimes of single particles, interacting continua, and turbulent diffusion. An analysis of experimental and numerical data shows that the models considered sometimes allow adequate identification of the wave structure of motion of the mixture and the field of parameters inside and outside the layer.     

挡水结构水下爆炸作用的离心模型试验

水下爆炸包括冲击波和气泡脉动,两者能量相当,均会对结构产生毁伤作用。水下爆炸载荷试验唯有在离心机内才满足相似关系,设计试验时宜在离心机负载范围内尽可能增加模型尺寸以减小边界效应。针对挡水结构,在离心机内布置压力传感器、高速摄像机、加速度计及应变片测试了冲击波、气泡脉动载荷及结构产生的动力响应。通过试验对比了水下爆炸和空爆产生的载荷,分析其引起结构动力响应的差异。对于水下爆炸,重力加速度的增加引起气泡脉动冲量的减小,而气泡脉动产生的峰值应变基本与气泡冲量呈线性关系,因而模拟气泡脉动对结构作用时应考虑重力效应。     

二甲基二烯丙基氯化铵的合成

研究了以二甲氨、氯丙烯、氢氧化钠为原料,制备二甲基二烯丙基氯化铵(DMDAAC)的合成工艺。通过比较一步法、两步法和滴加法三种工艺路线,最终采用滴加法,具体工艺为用低于20℃水冷却,将氢氧化钠溶液和氯丙烯以交替滴加的方式加入到二甲氨溶液中,氯乙醇、氢氧化钠、二甲胺三者的物质的量之比为2∶1∶1。然后控制季铵化反应温度为45℃,反应10h后,进行减压蒸馏,减压过滤提纯产品,得到收率在60%以上的产品。该工艺流程简单,条件温和,适于工业生产。     

MACROPROCESS OF PARTICLE FORMATION IN SUSPENSION POLYMERIZATION OF STYRENE WITH INORGANIC STABILIZER SYSTEM

The macroprocess of particle formation from suspension droplets of styrene in a pdymerizationsystem was investigated.Inorganic hydroxyapatite or its mixture with polyvinyl alcohol as thepolymerization system was used.Those items such as the effects of the Weight fraction of dispersed-phase,the amount of the inorganic stabilizer and the agitation speed on the breakup and coalescence of thetransient dispersed drops etc.Were examined.Results showd that the dynamic behavior of the transi-ent polymer droplets changed in the presence of the suspension stabilizer during the reaction.     

Structure of the Reaction Zone of a Steady Detonation Wave in Dinitrodiazapentane

The massvelocity profiles in 2,4dinitro2,4diazapentane samples of different densities were registered by a laser interferometer and the electromagnetic technique. The reaction time was shown to reach 300 nsec and weakly depend on density, while the pressure in the chemical spike can be twice as high as that at the Chapman–Jouguet point. No special features due to diamond formation were observed in the massvelocity profiles registered in the chemical reaction zone.     

橡胶对HIPS树脂落锤指标的影响

通过对高抗冲聚苯乙烯树脂出现产品落锤指标偏低问题的分析，从橡胶配量及其粒径大小上进行了改进，同时改进了工艺操作，采取了提高反应釜搅拌速度、降低乙苯浓度等措施。结果产品合格率达到９９％以上，优级品率达到９８％以上。     

Flow modelling within non-homogeneous packings: The structural macro-correlations

The pressure drop and the fluid velocity profiles were investigated experimentally and numerically in the model packings of complex geometry. The numerical estimations were performed by means of the hybrid method involving the use of structural macro-correlations. In this paper it has been demonstrated on several examples that the structural macro-correlations allow to predict the macro-scale flow behaviour in non-homogeneous packings. Finally, the recent mechanistic approaches to flow modelling in packed tubes of low tube-to-particle diameter ratio have been discussed.     

Interaction of a shock pulse with a contact discontinuity

Passing of a triangular moderate-intensity pulse through a constant discontinuity is considered. Decay of the shock wave that passed into the second gas is analyzed. Damping of the detonation wave after burnout of the combustible mixture is discussed. __________ Translated from Fizika Goreniya i Vzryva, Vol. 43, No. 4, pp. 102–107, July–August, 2007.     

Processing and characterization of particles reinforced SiOC composites via pyrolysis of polysiloxane with SiC or/and Al fillers

Polysiloxane loaded with SiC as inert filler, and Al as active filler, was pyrolyzed in nitrogen to fabricate SiOC composites, and the processing and properties of the filled SiOC composites were investigated. Adding SiC fillers could reduce the linear shrinkage of filler-free cured polysiloxane in order to obtain monolithic SiC/SiOC composites. The flexural strength of SiC/SiOC composites reached 201.3 MPa at a SiC filler content of 27.6 vol.%. However, SiC/SiOC composites exhibited poor oxidation resistance, thermal shock resistance and high temperature resistance. Al fillers could react with hydrocarbon generated during polysiloxane pyrolysis at 600 °C and N₂ at 800 °C to form Al₄C₃ and AlN, respectively. The volume expansions resulting from these two reactions were in favor of the reduction in linear shrinkage and the improvement in flexural strength of SiC/SiOC composites. The flexural strength of Al-containing SiC/SiOC composites was 1.36 times that of SiC/SiOC composites without Al at an Al filler content of 20 vol.%. The addition of Al fillers remarkably improved the high temperature resistance and oxidation resistance of SiC/SiOC composites, but not thermal shock resistance.