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排序方式: 共有1774条查询结果,搜索用时 15 毫秒
1.
Hung‐Yee Shu 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(3):273-280
Liquid–liquid two‐phase epoxidation from cyclohexene and cyclooctene in aqueous potassium peroxymonosulfate (commercially available as Oxone®) solution was studied as an application in pollution prevention. To avoid potential emissions of volatile organic compounds an aqueous solution was employed to replace the usual chlorinated solvents used in epoxide production. A droplet column reactor and stirred tank reactor were used to investigate two‐phase synthesis of epoxide. An aqueous Oxone® solution was used to oxidize a dispersion of alkene droplets and form epoxide. The study of aqueous epoxidation in both reactors showed that the epoxidation of alkenes can be represented as a first order reaction with respect to alkene. The salting out effect of Oxone® concentration was studied in both reactors and found to be very similar at optimal conditions. In comparing the two reactors, it was found that the droplet column reactor produces larger quantities of product per unit reactor volume for the same reaction time. The objective of this study is to provide an alternative reactor design and synthesis route that can meet pollution prevention goals. Copyright © 2004 Society of Chemical Industry 相似文献
2.
Thermal history and solute precipitation behavior of suspended solution droplets of sodium chloride (NaCl), magnesium sulphate (MgSO4), and zirconium hydroxychloride (ZrO(OH)Cl) evaporating at atmospheric and reduced pressures are studied. Experimental measurements on the variation of droplet diameter, solution concentration, and temperature during the evaporation period are presented and discussed. The results of solute precipitation behavior in solution droplets observed under an optical microscope are displayed and discussed. Results indicate that reducing the pressure (∼ 33 kPa) results in a change in the solution droplet evaporation rate, but the thermal histories of a particular solution droplet are similar at the atmospheric and reduced pressures. At atmospheric and reduced pressures used in this study, the d2 law for solution droplets is valid at early stages of the evaporation and before the solute precipitation initiates. Drying of MgSO4 and ZrO(OH)Cl solution droplets results in the formation of spherical particles, whereas drying of spherical NaCl solution droplets results in the formation of cubic particles. 相似文献
3.
Hyun Kyu Suh 《Fuel》2008,87(6):925-932
This paper investigates the effect of injection parameters on the characteristics of dimethyl ether (DME) as an alternative fuel in a diesel engine with experimental and analytical models based on empirical equations. In order to study macroscopic and microscopic characteristics of DME fuel, this work focuses on the atomization characteristics of DME and compares experimental and predicted results for spray development obtained by empirical models for diesel and DME fuel. Detailed comparisons of spray tip penetration from three different empirical correlations and from visualization experiments of diesel and DME fuels were conducted under various fuel injection conditions. In comparison with the results of different empirical equations for measured spray tip penetration, the experimental results of this study provide good agreement with the calculation results based on empirical equations, except during the earliest stage of the injected spray sequence. The results of atomization characteristics indicate that DME showed better spray characteristics than conventional diesel fuel. Also, the fuel injection delay and maximum injection rate of DME fuel are shorter and lower than those of diesel fuel at the same injection conditions, respectively. 相似文献
4.
Ebony A. Monson Donna R. Whelan Karla J. Helbig 《International journal of molecular sciences》2021,22(9)
Lipid droplets (LDs) have traditionally been thought of as solely lipid storage compartments for cells; however, in the last decade, they have emerged as critical organelles in health and disease. LDs are highly dynamic within cells, and their movement is critical in organelle–organelle interactions. Their dynamics are known to change during cellular stress or nutrient deprivation; however, their movement during pathogen infections, especially at very early timepoints, is under-researched. This study aimed to track LD dynamics in vitro, in an astrocytic model of infection. Cells were either stimulated with a dsRNA viral mimic, poly I:C, or infected with the RNA virus, Zika virus. Individual LDs within infected cells were analysed to determine displacement and speed, and average LD characteristics for multiple individual cells calculated. Both LD displacement and mean speed were significantly enhanced in stimulated cells over a time course of infection with an increase seen as early as 2 h post-infection. With the emerging role for LDs during innate host responses, understanding their dynamics is critical to elucidate how these organelles influence the outcome of viral infection. 相似文献
5.
Liquid—liquid thermally induced phase separation of the polymer—diluent system isotactic poly(propylene)—diphenyl ether was studied under an optical microscope. It was found that as the system phase separated, droplets of a diluent-rich phase formed within a polymer-rich matrix. These droplets grew in size and decreased in number by a process known as coarsening. The scaling exponent relating droplet diameter and time was determined. The scaling exponent was found to be a strong function of the droplet phase volume fraction, and this strong dependence on volume fraction was relatively insensitive to temperature. The influence of the ratio of interfacial tension between the phases and the viscosity of the matrix phase was less significant on the growth rate of the droplets. 相似文献
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8.
Jiaqing Chang Mingshan Chi Teng Shen Zhongwei Liang 《Journal of Adhesion Science and Technology》2020,34(10):1128-1143
AbstractVarious inks with different properties are widely used in the printed electronic industry. In order to obtain high quality inkjet printing, it is necessary to study the droplet formation process and its influencing factors comprehensively. Only in this way, the incentive conditions and liquid physical parameters of droplet ejection can be obtained and optimized. Firstly, the calculation model of the droplet ejection process is established for a tubular print head and the boundary conditions are set according to the driving characteristics. Secondly, the free surface flow is calculated in the simulation software and sequential pictures of the droplet formation processes are captured to validate the availability of the numerical algorithm. Finally, the droplet formation processes of the tubular piezoelectric print head are simulated under different incentive conditions, different viscosities and different surface tensions. Too small a driving energy is insufficient to cause the head to eject droplets. Excessive excitation energy will result in larger or multiple satellite droplets. Additionally, the thinning process of the liquid neck is examined carefully in this paper. Results show that surface tension and viscosity have a significant effect on the thinning speed of the liquid neck, but the effect is not as significant as previous studies. 相似文献
9.
Xin Huang Limin He Xiaoming Luo Ke Xu Yuling Lü Donghai Yang 《American Institute of Chemical Engineers》2021,67(5):e17165
The dynamic behaviors of two droplets and droplet cluster under an alternating current (AC) electric field are investigated. Two droplets generally undergo transformation from complete coalescence to partial coalescence and finally to non-coalescence as the electric capillary number Cap increases. The critical electric capillary number Capc for complete coalescence in the AC electric field remains unchanged and is twice as large as that in the direct current (DC) electric field when the frequency f ≥ 250 Hz. Charge transfer and reversal of electric field result in the reversal of the direction of electric force, which is the fundamental mechanism of non-coalescence of two droplets and chain formation in droplet cluster. The number of rebounds dramatically increases as f increases, promoting the stability of droplet chain. The droplet chains in the high-frequency AC electric field are longer and more stable than those in the low-frequency AC electric field. 相似文献
10.
Numerical simulation of gas metal arc welding temperature field 总被引:1,自引:0,他引:1
The infrared camera is used to investigate the temperature field of gas metal arc welding.The results show that the temperature distribution of weld pool and adjacent area appears cone shape.A new heat source model combined by Gaussian distribution heat source of the arc and conical distribution heat source of the droplet is set up based on the experimental results, and with the combined boundary conditions,the temperature field of gas metal arc welding is simulated using finite element method.According to the comparison between the results of experiment and simulation in temperature field shows that the new combined heat source model is more accurate and effective than the Gauss heat source model. 相似文献