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131.
《Advanced Materials Interfaces》2017,4(23)
Nonsilicon micromachining is a challenge, especially for large scale heterogeneous (hydrophilic/hydrophobic) surface fabrication. Here, mesh screen and diffusion welding technique are coupled to form a novel fabrication method. Mesh screen is used as mask. The diffusion welding technique sinters mesh screen on copper surface to form welding junction array. Chemical treatment of sintered package forms superhydrophobic nanostructures on surfaces except welding junction array. Separating mesh screen from copper substrate exposes hydrophilic dots array, corresponding to welding junction array. Thus, heterogeneous surface is created. By condensing wet air, main droplet and neighboring droplet occur on hydrophilic dot and superhydrophobic part, respectively. For horizontal surface, neighboring droplets initially generated on nanograsses behave consecutive events of coalescence, jump, and return, triggering contact/noncontact effect induced jumping. Thus, defect droplet area is formed and droplet size uniformity is broken. A nondimensional equation is proposed for the contact effect induced jumping analysis. Noncontact effect induced jumping is found for the first time. For vertical surface, droplet array behaves monodisperse size due to departure of merged neighboring droplets without returning, and equal opportunities of neighboring droplets captured by main droplets. The work opens a new way for large scale droplet array generation by controllable condensation. 相似文献
132.
The study of Nepenthes pitcher plants‐bioinspired anisotropic slippery liquid‐infused porous surfaces (SLIPS) is currently in its infancy. The factors that influence their anisotropic self‐cleaning and electric response of a drop's motion and the mechanism have not been fully elucidated. In order to address these problems, two new types of anisotropic slippery surfaces have been designed by using directional, porous, conductive reduced graphene oxide (rGO) films, and different lubricating fluids (conductive and nonconductive), which are used to study the influencing factors and the mechanism of anisotropic self‐cleaning and electric‐responsive control of a drop's motion. The results demonstrate the anisotropic self‐cleaning property of these two types of SLIPS is closely related to the interaction between liquid drops, lubricating fluids and dirt, and the conductive lubricating fluids filling the rGO porous film can reduce the response voltage of the electrically driven reversible control of a drop's slide. The uniqueness of this research lies in the use of two different lubricating fluids and graphene materials to prepare anisotropic SLIPS, identify the key factors to achieve an electrically driven system. These studies are essential for advancing the application of electronically responsive SLIPS in the fields of liquid directional transportation, microfluidics, microchips, and other related research. 相似文献
133.
Yiwei Li Weixia Zhang Jiliang Hu Yachao Wang Xiaojun Feng Wei Du Ming Guo Bi‐Feng Liu 《Advanced functional materials》2017,27(11)
Rapid and precise assembly of functional nanoparticles into well‐defined structures in large scale is motivated by broad fields. In this study, large‐scale transparent conductive circuit arrays are rapidly self‐assembled by simply pipetting a gold nanoparticles suspension onto a PDMS nanofilm patterned substrate with distinct hydrophilic/hydrophobic areas. The solution firstly self‐confines into predefined hydrophilic geometries, followed by assembly of nanoparticles into well‐defined circuits with 1D patterns by coffee ring effect. Submicrometer height and submicrometer‐ to micrometer‐width circuit arrays with various shapes are precisely generated by varying the PDMS nanofilm patterns. Thousands of circuits with different geometries are self‐assembled simultaneously within 1 min. The conductive circuits show good optical transparency up to 95%. After being transferred into PDMS elastomer sheet by encapsulating, the circuits remain highly conductive during bending and stretching. With the advantages of high‐throughput, equipment‐free, scalability, and precise control, this technique will open an avenue for fabricating large‐scale functional materials for applications in electronics, optoelectronics, and healthcare devices. 相似文献
134.
Dong Wang Huifang Su Ryan T. K. Kwok Guogang Shan Anakin C. S. Leung Michelle M. S. Lee Herman H. Y. Sung Ian D. Williams Jacky W. Y. Lam Ben Zhong Tang 《Advanced functional materials》2017,27(46)
Red/near‐infrared (NIR) fluorescent molecules with aggregation‐induced emission (AIE) characteristics are of great interest in bioimaging and therapeutic applications. However, their complicated synthetic approaches remain the major barrier to implementing these applications. Herein, a one‐pot synthetic strategy to prepare a series of red/NIR‐emissive AIE luminogens (AIEgens) by fine‐tuning their molecular structures and substituents is reported. The obtained AIEgens possess simple structures, good solubilities, large Stokes shifts, and bright emissions, which enable their applications toward in vitro and in vivo imaging without any pre‐encapsulation or ‐modification steps. Excellent targeting specificities to lipid droplets (LDs), remarkable photostabilities, high brightness, and low working concentrations in cell imaging application make them remarkably impressive and superior to commercially available LD‐specific dyes. Interestingly, these AIEgens can efficiently generate reactive oxygen species upon visible light irradiation, endowing their effective application for photodynamic ablation of cancer cells. This study, thus, not only demonstrates a facile synthesis of red/NIR AIEgens for dual applications in simultaneous imaging and therapy, but also offers an ideal architecture for the construction of AIEgens with long emission wavelengths. 相似文献
135.
Francisca Holgado Gloria Márquez-Ruiz María Victoria Ruiz-Méndez Joaquín Velasco 《International Journal of Food Science & Technology》2020,55(2):833-840
The effect of oil droplet size (ODS) on the oxidative stability (OS) of dried microencapsulated oils has been scarcely studied, and results are contradictory. A few studies have shown increased OS when the ODS was reduced and this was attributed to a decrease in the surface oil content (SOC). Yet, in such studies, only the total oil fraction was evaluated. In the present work, the free (FO) and encapsulated oil (EO) fractions of freeze-dried microencapsulated sunflower oil were analysed to study the effect of changes in the ODS by using different homogenisation pressure (15 or 70 MPa) in the emulsification step. The OS of both the free and encapsulated fractions increased when the ODS was significantly reduced in two samples with different encapsulation matrix, namely caseinate/lactose and maltodextrin/sucrose/gelatine. A reduction in the SOC would explain the increased stability of the FO, but not that of the EO. An additional protective role of the interfacial film could have been involved. In conclusion, if the encapsulation matrix and the interfacial region are effective as oxygen barriers, a reduction in the ODS of the parent emulsion by an increase in the homogenisation pressure will result in capsules more stable against lipid oxidation. 相似文献
136.
There are many coolants frequently used in the industry for controlling not only heat transfer, but also temperature distribution in a confined domain. However, little is known on the thermal properties of sodium droplets. The qualitative analysis of differential equations that model the thermal explosion, nonlinear dynamic of sodium droplet with variable thermophysical properties when thermal radiations are considered as suggested by Cogley et al, Sohrab et al, and P‐1 approximation Sazhin et al is deliberated upon in this study. The governing equations, first‐order nonlinear ordinary differential equations, are nondimensionalized using the appropriate similarity variables. The existence and uniqueness of the solutions, concavity, and convexity of the temperature distribution, and positivity nature of the solutions of the dimensionless governing equations are established. It is concluded that there exists a solution for a certain range of the admissible parameters and when the reduced activation energy is negative and temperature distribution fits concavity. More so, the major criteria to obtain a positive solution are outlined in this study. 相似文献
137.
Xiang Ren Jingyuan Sun Zhengliang Huang Yao Yang Sihang Tian Jingdai Wang Yongrong Yang 《American Institute of Chemical Engineers》2020,66(5):e16909
Nowadays, the droplet–particle collision characteristics in the gas-phase ethylene polymerization process are still unclear. The high-speed photography and a quasi-circle imaging approach are employed to study the collision interaction characteristics between liquid droplets and polyethylene particles. The liquid film evolution is studied through variations of the film thickness on the particle north pole, the dynamic contact angle, center angle and film thickness at the maximum extension. Results have found that for n-hexane the threshold temperature of the recoil happening increases with increasing initial Weber number, but for 1-hexene it is stable. Over 70°C evaporation and splash occurs immediately. Under low Weber numbers, the water droplet stays for damping oscillations, the reference stable height of which is linearly related to temperatures. Moreover, three regimes of film thickness variation with time are identified and mathematically described, while Regime 3 characteristics are found strongly dependent on the liquid species, Weber number, and particle temperature. 相似文献
138.
This work aims to investigate the unsteady conjugate interphase mass transfer between a stationary deformed drop and the modest extensional flow in a cross-intersected 2D channel. It is very difficult to accurately quantify the transient mass transfer rate of solute in such a geometry. Therefore, we established a mathematical model on the basic of the Stokes equation and solved it by the boundary element method, which could deal precisely with a two-phase flow system with a deformable interface; meanwhile, the convection-diffusion equation was solved by the finite difference method to calculate the unsteady conjugate interphase mass transfer. The simulation results showed that the mass transfer rate, analyzed and characterized in terms of mean concentration variation and Sherwood number Sh, was affected by capillary number Ca, Peclet number Pe, viscosity ratio λ , interior-to-exterior diffusivity ratio K, distribution coefficient m, and wall effect factor W. 相似文献
139.
《International Journal of Hydrogen Energy》2021,46(66):33260-33271
The dynamic behavior of liquid droplets on a reconstructed real gas diffusion layer (GDL) surface with the inertial effect produced by the three dimensional (3D) flow channel is investigated using an improved pseudopotential multiphase model within the unified lattice Boltzmann model (ULBM) framework, which can realize thermodynamic consistency and tunable surface tension. The microstructure of the GDL (Toray-090) including carbon fibers and polytetrafluoroethylene (PTFE) is reconstructed by a stochastic and mixed-wettability model. The critical force formulation for the Cassie-Wenzel transition of a droplet on GDL surface is derived. The effects of inertia and contact angles on the liquid droplet transport process on a reconstructed real GDL surface with a 3D flow channel are investigated. The results show the normalized center-of-mass coordinate X may enter the channel wall area or fluctuate around the initial position. With increased inertia applied on the droplet, the normalized center-of-mass coordinate Y grows faster and the normalized center-of-mass coordinate Z decreases. It is found by the ULBM for the first time that the liquid droplet is pushed back into the GDL by inertial effect. With the increase of inertia and the decrease of contact angle of GDL, both the droplet penetration depth in GDL and the droplet invasion fraction increase. The droplet invasion fraction in GDL is up to 30%. 相似文献
140.
Hye-Seon Jeong Eunseo Kim Changwoo Nam Yoon Choi You-Jeong Lee David A. Weitz Hyomin Lee Chang-Hyung Choi 《Advanced functional materials》2021,31(18):2009553
A hydrogel microcapsule with an intermediate thin oil layer is presented to achieve smart release of a broad range of cargoes triggered via diverse stimuli. A microfluidic technique is used to produce triple emulsion droplets with a thin oil layer that separates the innermost aqueous phase from the hydrogel prepolymer phase, which transforms into a hydrogel shell via photopolymerization. The intermediate oil layer within the hydrogel microcapsule acts as an effective diffusion barrier, allowing encapsulation of various small cargoes within a porous hydrogel shell until a stimulus is applied to destabilize the oil layer. It is demonstrated that diverse stimuli including chemical dissolution, mechanical stress, and osmotic pressure can be utilized to release the encapsulated cargo on-demand. In addition, osmotic pressure and the hydrogel shell thickness can be independently tuned to control the onset time of release as well as the release behavior of multi-cargo encapsulated hydrogel microcapsule. The release can be either simultaneous or selective. 相似文献