A Boronate Ester Driven Rechargeable Antibacterial Membrane for Fast Molecular Sieving

Membrane decorated with biocides is an effective way to suppress biofilm growth. However, their immediate biocidal effect usually suffers from a significant decline due to the irreversible consumption of the biocides. Here, a smart nanofiltration membrane is reported with rechargeable antibacterial capability that is fabricated by a facile interfacial polymerization via 3-aminophenylboronic acid and trimesoyl chloride on a polysulfone substrate. Biocides bearing diol groups can be grafted onto the membrane surface under neutral/alkaline condition and then released from the surface under acidic environment, due to the pH-responsive feature of boronate ester complexes. The resultant membrane exhibits integrated properties of fast bacterial inactivating efficiency, rechargeable antibacterial capability, and impressive stability. In addition, the achieved membrane shows remarkable separation efficiency to dye/monovalent salt system. The successful fabrication of the membrane with rechargeable anti-bacterial property provides new insights into the development of pH-responsive and sustainable antibacterial membranes.     

Defect‐Laden MoSe2 Quantum Dots Made by Turbulent Shear Mixing as Enhanced Electrocatalysts

A high density of edge sites and other defects can significantly improve the catalytic activity of layered 2D materials. Herein, this study demonstrates a novel top‐down strategy to maximize catalytic edge sites of MoSe₂ by breaking up bulk MoSe₂ into quantum dots (QDs) via “turbulent shear mixing” (TSM). The ultrasmall size of the MoSe₂ QDs provides a high fraction of atoms in reactive edge sites, thus significantly improving the catalytic activities. The violent TSM further introduces abundant defects as additional active sites for electrocatalytic reactions. These edge‐proliferated and defect‐laden MoSe₂ QDs are found to be efficient electrocatalysts for the hydrogen evolution reaction, and useful as counter electrodes in dye‐sensitized solar cells. The work provides a new paradigm for creating edge‐proliferated and defect‐rich QDs from bulk layered materials.     

CuInS2量子点敏化太阳能电池材料的研究进展

CuInS_2量子点因低毒、良好的光电性能和热电稳定性而成为量子点敏化太阳能电池(QDSSC)极具前景的量子点敏化剂。首先简单介绍了CuInS_2量子点材料的光电性质和QDSSC中CuInS_2量子点的合成,然后重点总结了CuInS_2量子点敏化电极的制备及各电池材料对QDSSC性能的影响,最后指出了该电池目前存在的问题以及对未来的展望。     

X射线光电子能谱法测定染料结构的探讨

应用Ｘ射线光电子能谱法测定酸性耐雕棕ＢＮ的结构,探索简化,加快染料结构剖析或分析的新方法。     

Synthesis and characterization of novel blue azo‐dye derivatives containing acrylate group for dye‐based color filters

Abstract— Even though dyes have a fine resolution and good chromaticities, they are not widely used as coloring materials for color filters (CFs) due to their low thermal stability and chemical resistance. A series of azo‐dye derivatives, which consist of two cross‐linkable acrylate or methacrylate groups to improve thermal and chemical properties, have been synthesized and used to fabricate color filters. The spectral properties and chemical/thermal stabilities of the fabricated CFs were investigated by comparing dye‐based CFs, without a complicated dispersion process, but with pigment‐based CFs using dispersed pigment. Also, more properties including the development test and surface morphologies lithographic properties were studied. The synthesized azo dyes were characterized by elemental analysis, UV‐visible spectra, IR, mass, and ¹H‐NMR spectra.     

反胶束体系中水团的笼效应

在反胶束体系中研究了菁染料的吸收光谱以及ω值对菁染料荧光光谱的影响．讨论了不同粒径的AgCl纳米粒子对反胶束体系中菁染料的吸附状态及J-聚集体形成的影响．特别研究了反胶束水团空间限定效应对菁染料荧光量子产率及J-聚集体的影响。     

Treatment of textile dye effluent using a self-made positively charged nanofiltration membrane

A self-made positively charged nanofi ltration(NF)membrane was used to treat textile dye effluent to generate water for reuse,and the factors affecting nanofi ltration process such as operating pressure,feed flow and membrane cleaning were investigated.With an applied pressure of 1.0 MPa and a feed flow of 40 L/h,this NF membrane has a removal of 93.3% for CODcr and a reduction of approximately 51.0% in TDS,salinity and conductivity achieving the chroma removal of 100%.The permeate obtained through this membrane is suitable for recycling.Moreover,the membrane could be reused after being cleaned with 1% NaOH solution.     

提高锦纶超细纤维匀染性的方法研究

针对锦纶超细纤维上染速率快、竭染率高、且容易产生上染不匀和染色牢度差等问题,从酸性染料的浓度、染色工艺的确定、以及匀染剂的使用等方面,探讨各因素对匀染性的影响．实验结果表明,浓度为3％（owf）,匀染剂用量为2％（owf）,浴比1：50,pH=5．5,100℃保温50min时,可得到较好匀染效果的织物,且耐磨擦牢度可提高至2-3级．     

基于3-(4-Biphenylyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole(TAZ)制备的薄膜电阻的磁效应

讨论了采用热蒸镀方法制备的结构为ITO/β-NPB(55-xnm)/Alq3(45nm)/TAZ(xnm)/LiF(0.5nm)/Al的器件的磁效应。在室温下研究了x分别取0、5、10、15nm时器件的电阻率与磁场之间的变化关系。结果表明,x=0nm时,在10V电压下,电阻率变化率Δρ/ρ随磁场强度的增大而增大;当磁场强度B=110mT时,Δρ/ρ达到最大,仅为8.22%。当x分别取5、10、15nm时,Δρ/ρ为随磁场的增大而减小;在相同磁场强度下,x越大,Δρ/ρ越大;当B=110mT,x=15nm,电压为10V时,Δρ/ρ的数值达到最大,为-16.92%。     

层状土入渗试验中指流发育的分形特征及入渗规律

土质结构差异较大的层状土入渗过程中易出现指流.为了了解层状土下层介质对指流发生发育的影响,以三种不同粒径的石英砂为下层介质和以砂壤土为上层介质进行了室内积水入渗的染色示踪试验.结果表明,下层介质粒径越大越易出现指流,且指流行进速度越快.指流发生后,入渗过程趋向于稳定,且下层土壤粒径越大,稳定入渗率与累积入渗量越小.采用湿润面积和湿润比描述指流发育的宏观特性,发现湿润面积和平均湿润比都随时间而增大,表明湿润锋趋于均匀.为定量研究层状土入渗中指流发育的分形特征,采用像素点覆盖法编制了计算染色示踪试验中分形维数发育的Matlab程序,对程序进行了验证并计算了四组试验指流发育的计盒维数.结果表明指流分布具有明显的分形特征,下层介质粒径越大计盒维数越小,且计盒维数随时间而增大.