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Conductive Papers Containing Metallized Polyester Fibers for Electromagnetic Interference Shielding 总被引:7,自引:0,他引:7
Conductive papers were developed for preventing or reducing electromagnetic interference (EMI), and their shielding efficiency was evaluated. This type of conductive paper consists of wood pulp, synthetic pulp and metallized polyester fibers (0.5–2.0 mm long and 14 m in diameter) whose surfaces are coated with nickel alone (Ni-PET) or copper and nickel double layers (Ni-Cu-PET) by electroless plating. In this report, the effect of the characteristics of these metallized fibers, such as their conductivity, geometry and the concentration of fibers in paper, which lead to high efficiency for shielding effectiveness is discussed. For instance, one of the conductive papers (80 g/m2) which was prepared by mixing 40% Ni-Cu-PET and 60% synthetic polyethylene pulp showed over 40 dB shielding effectiveness between 10 MHz and 1 GHz. 相似文献
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The carboxyl‐terminated butadiene‐a‐acrylonitrile rubber (CTBN) has been proved to be the most effective toughener for cyanate ester (CE) resin. This work mainly focuses on the different modification effects caused by the addition of CTBN with different acrylonitrile content. The phase separation, morphology of fracture surface, and physical properties of the blends are studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), dynamic mechanic analysis (DMA), and thermogravimetric analysis (TGA). It is testified that the compatibility and toughness between CE and CTBN had a positive correlation with the acrylonitrile content of CTBN. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
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MAH接枝EPDM增韧PA66的研究 总被引:7,自引:0,他引:7
研究了MAH(马来酸酐)接枝三元乙丙橡胶(EPDM—g-MAH)对尼龙66(PA66)的增韧作用。利用SEM(扫描电镜)观察了共混体系的微观形貌(形态结构),并运用小角激光散射(SALS)方法研究了EPDM的加入对PA66结晶性能的影响。结果表明,未接枝的EPDM与PA66的相容性很差,而EPDM—g—MAH与PA66相容性明显增加,EPDM-g—MAH粒子均匀分散在PA66中,共混体系力学性能有很大提高。随着EPDM—g—MAH用量的增加,PA66球晶尺寸变小,共混体系界面结合更加紧密。 相似文献
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在部分产品中,钢表面镀锌后表面再涂一层漆,其目的是为了增加耐腐蚀性能。但是锌可能会与漆层中的一些组份发生反应,降低漆膜性能。本文通过开展氟碳漆涂层和镀锌层湿热试验后性能测试研究,表明两者之间具有较好的相容性,可提高产品的防护性能。 相似文献
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Homogeneous solutions of syndiotactic polystyrene (sPS) in diglycidylether of bisphenol A (DGEBA), containing 2.5, 5 and 7.5 wt % of thermoplastic with or without 0.5 and 1 wt % of poly(styrene‐b‐ethylene oxide) (PS‐b‐PEO) block copolymer, were polymerized using a stoichiometric amount of an aromatic amine hardener, 4,4′‐methylene bis (3‐chloro‐2,6‐diethylaniline) (MCDEA). The dynamic‐mechanical properties and morphological changes of sPS‐(DGEBA/MCDEA) compatibilized with different amount of PS‐b‐PEO have been investigated in this paper. The addition of the block copolymer produced significant changes in the morphologies generated. The size of the dispersed spherical sPS spherulites does not change significantly, but less spherulites of sPS appeared upon network formation in the systems with compatibilizer, what means that addition of compatibilizer in this system delayed crystallization of sPS in sPS‐(DGEBA/MCDEA) systems and change phase separation mechanism from crystallization‐induced phase separation (CIPS) and reaction‐induced phase separation (RIPS) almost only to RIPS. Moreover, PS‐b‐PEO with higher molecular weight of PS block seems to be a more effective compatibilizer than one with lower molecular weight of PS block. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 479–488, 2006 相似文献
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The purpose of this study was to characterize the mechanical behavior of asphalt modified by styrene–butadiene–styrene (SBS) and sulfur. Viscosity, microscopy, and rheological tests were conducted to understand the engineering properties of the polymer‐modified asphalt (PMA). Without the addition of sulfur, the polymer‐modified asphalt was microheterogeneous and was made up of two distinct finely interlocked phases, especially at high SBS concentrations. After the addition of sulfur, the PMA was observed to have smaller asphalt domains and a fairly homogeneous dispersion of the asphalt in the SBS matrix. The compatibility between polymer and asphalt produced an elastic network into the asphalt. The addition of sulfur resulted in an excellent elastic system and substantially increased the rheological properties of the PMA. Because of the colloidal nature of asphalt cements, their engineering properties were greatly improved because of the reinforcement of the SBS polymer and the physical‐chemical interaction between SBS and asphalt. The difference in the softening point between the top and bottom layers decreased significantly, and elastic recovery increased when was sulfur was present. A viscoelastic model was examined and shown to be appropriate for predicting the rheological properties ofthe asphalt–SBS blend mixed with sulfur. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 2817–2825, 2007 相似文献