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31.
In this work, five branched polyethylenes with different branching units were synthesized using bidentate nickel (II) catalyst containing -diimine ligands. For comparison, one linear polyethylene was also prepared using tridentate iron (II) catalyst containing -diimine ligand. The crystalline structure of the polyethylenes was investigated using X-ray diffraction (XRD) and polarized optical microscope. The crystalline properties were also measured by differential scanning calorimeter (DSC). Viscoelastic properties of the polyethylenes were investigated using rheometric dynamic analyzer. The DSC and XRD results showed that highly branched polyethylenes exhibit no melting points and no predominating crystalline forms, while the linear polyethylene exhibits clear orthorhombic (110) and (200) reflections on XRD pattern and a clear melting point at 118 °C. The viscoelastic properties of the branched polyethylenes were very complicated due to the combined effect of the molecular weight difference and the degree of chain branching as well as the branching structure. 相似文献
32.
33.
E. Gorges L. M. Raez A. Schillings I. Egry 《International Journal of Thermophysics》1996,17(5):1163-1172
Electromagnetic levitation is a useful tool for measuring thermophysical properties of high-temperature melts such as liquid metals. Due to its noncontact nature, the undercooled regime is also accessible. Density and thermal expansion of a levitated drop can be derived from volume measurements, if its mass is known. Assuming cylindrical symmetry, the volume of a drop can be determined from its cross section. Using photography, such measurements on liquid metals have been performed in the past. Here we present an improvement of this method, which replaces the photographic camera with a CCD videocamera and subsequent digital image processing. This reduces the time effect required to obtain the results and allows one to average over disturbing surface oscillations. The specific problems of digital image processing, namely resolution and edge detection, are addressed and results on nickel are presented.Paper presented at the Fourth International Workshop on Subsecond Thermophysics, June 27–29, 1991, Köln, Germany. 相似文献
34.
微酸性光亮锡铅合金镀液分析方法 总被引:1,自引:0,他引:1
提出锡铅合金液中Sn^2+,Sn(IV),PB^2+、EDTQA、柠檬酸三钠的分析方法。 相似文献
35.
P.B. Spoor L. Koene W.R. Ter Veen L.J.J. Janssen 《Journal of Applied Electrochemistry》2002,32(1):1-10
The removal of nickel ions from dilute solutions using a process that combines an ion-exchange bed with electrodialysis has been studied. The main aspects include: the concentration of nickel ions in the diluate, the voltage over the cell and the current density distribution along the ion-exchange bed. The current density distribution provides insight into the state of the bed as it is simultaneously loaded with Ni2+ and regenerated with an electric potential difference applied perpendicular to it. A simple model is used to describe the state of the bed and the quantity of nickel removed from it as a function of time. Under specific conditions the precipitation of metal hydroxides is observed in the compartment containing the ion-exchange bed. The results show that hydroxide precipitation is related to the nickel concentration in solution and the electric potential gradient across the bed. 相似文献
36.
Sergei Zinovyev Andrei Shelepchikov Pietro Tundo 《Applied catalysis. B, Environmental》2007,72(3-4):289-298
A multipurpose study deals with the transfer hydrogenolysis of 1,3,5-trichlorobenzene to benzene in the 2-propanol–Raney nickel system in the presence of KOH. At 70 °C, no reaction occurs without KOH or with weaker bases, e.g. amines or poorly soluble inorganic bases; however saturated KOH as well as water over 1% suppress the reaction rate, presumably due to the competitive adsorption of these species on the catalyst. The catalytic activity also drops with time because of the deposition of the solid KCl on the catalyst but can be recovered at washing the catalyst with water. The deactivation by KCl can be mitigated with the addition of promoters, e.g. quaternary ammonium salts (Aliquat 336, CTAC) or trioctylamine. Aliquat 336 also promotes hydrodechlorination in the hydrothermal system using a 10% solution of 2-propanol in water, Raney nickel and potassium carbonate as base at 150–200 °C and 10–20 bar. Under these conditions, hexachlorobenzene was also selectively dechlorinated to benzene. 相似文献
37.
Li Yongjun Lei Xiaorong 《功能材料》1998,(2)
本文对化学镀NiPPTFE复合镀层的性能作了测定和评价。实验表明,用优化的镀液配方和工艺可获得含PTFE粒子25~30%vol的NiPPTFE复合镀层。这种镀层具有优良的结合力和良好的耐蚀性,其硬度随PTFE含量增加而降低,其特别突出的性能是优异的减摩性和耐磨性,是一种具有自润滑功能的表面复合材料。 相似文献
38.
电镀锡机组软熔导电辊脱锡技术研究 总被引:3,自引:0,他引:3
粘锡是电镀锡机组软熔导电辊失效的主要原因,应用化学方法脱锡是延长导电辊寿命的重要途径.开发了氢氧化钠(钾)为主要组成,并加入适量亚铅酸钠(钾)和硝酸(亚硝酸)钠配制而成脱锡剂,当脱锡剂温度为40~80℃,导电辊表面温度为40~70℃时,对粘锡导电辊具有很好的脱锡效果.粘锡导电辊脱锡后的表面粗糙度可以恢复到4.0μm以上,导电辊使用寿命提高80%,降低导电辊修复成本90%,并大幅度减少导电辊更换时间,提高电镀锡机组生产作业率. 相似文献
39.
A new discharge system for resistive self-heating has been constructed for the measurement of accurate thermophysical properties. A constant-current pulse is used to heat metals over a time interval of 50 to 100 s, reaching temperatures up to the boiling point. New techniques have been developed to obtain sound speeds in the pulse-heated sample, emissivities, and vapor pressure. A new pyrometer allows the extension of the measured temperature range down to the melting point of copper. 相似文献
40.