中国炼铁系统的节能与环境保护

回顾了20世纪90年代以来,中国炼铁系统的节能和环境保护的进展.指出由于高炉喷煤技术的开发和推广,大大减少了焦炉的建设投资,真正从源头减少了铁前系统的能耗和污染.基于对炼铁系统二次能源的分析,从节能和减排温室气体来看,淘汰落后的小烧结、小高炉, 大力推广高炉TRT、高效干式除尘和利用高炉煤气发电及烧结余热回收利用等,将是今后工作的重点.     

Synthesis and Evaluation of Blends Formed by Polymeric Crown Ethers and a Fullerene-Containing Primary Ammonium Salt in Organic Thin Films

The synthesis of a series of polymers and cyclopolymers bearing crown ethers of differing structure and affinities towards primary ammonium ions is discussed. These polymers have been tested in their efficiency to form structurally homogeneous thin films when blended with an amphiphilic C₆₀ compound containing a primary ammonium ion functional group. The X-ray reflectivity characterization of the films revealed that the polymer bearing the crown ether with the least affinity for primary ammonium ions, but having the highest degree of polymerization, is the most effective in forming structurally homogeneous thin films.     

奥里油在电力工业的应用及环保处理

委内瑞拉富藏奥里油约469亿t，中国政府与委内瑞拉政府签订了合作生产和供应每年650万t奥里油的合作协议。介绍了奥里油的特性和在全球以及中国的应用情况，分析了奥里油燃烧发电带来的特殊的环保问题和处理方法。     

In situ polymerization and characterization of polyester‐based polyurethane/nano‐silica composites

Polyester‐based polyurethane/nano‐silica composites were obtained via in situ polymerization and investigated by Fourier‐transform infrared spectroscopy (FTIR), or FTIR coupled with attenuated total reflectance (FTIR‐ATR), Transmission electron microscopy (TEM), atomic force microscopy (AFM), an Instron testing machine, dynamic mechanical analysis (DMA) and ultraviolet‐visible spectrophotometry (UV‐vis). FTIR analysis showed that in situ polymerization provoked some chemical reactions between polyester molecules and nano‐silica particles. FTIR‐ATR, TEM and AFM analyses showed that both surface and interface contained nano‐silica particles. Instron testing and DMA data showed that introducing nano‐silica particles into polyurethane enhanced the hardness, glass temperature and adhesion strength of polyurethane to the substrate, but also increased the resin viscosity. UV‐vis spectrophotometry showed that nano‐silica obtained by the fumed method did not shield UV radiation in polyurethane films. Copyright © 2003 Society of Chemical Industry     

涂层材料的断裂分析(英文)

和基体厚度相比,涂层很薄,因此细观力学模型可把基体作为半无限弹性体。由于涂层和基体材料的膨胀系数及弹性系数不匹配,涂层材料中残余热应力的解析解为 E_c/(1-γ_c)·(α_s-α_c)△T。用有限元法校核,该应力和解析解吻合得好。通过对涂层产生裂纹驱动力和断裂韧性的讨论,提出了抗裂涂层厚度公式。     

化学镀SiCp／Ni－P复合镀层与基体结合强度及其影响因素

论述了ＳｉＣｐ／Ｎｉ－Ｐ复合镀层与钢基体的结合强度及其影响因素。复合镀层中离界面５μｍ厚度以内区域的组成及应力状态对镀层／基体的界面结合有决定性作用，在该区域以外ＳｉＣ粒径变化不影响镀层的结合强度。适当的热处理可提高界面结合力。     

一种碳－碳复合材料长寿命防氧化涂层的失效机制

用液相法联合ＣＶＤ法和硅化法制备了一种碳－碳复合材料复合梯度涂层，在此基础上对这种涂层在氧化过程中的失效机制进行了研究．结果表明：氧化层与液相层界面反应生成的气相产物是涂层失效的根本原因界面上气泡的不均匀形核、长大和破裂导致涂层表面出现孔洞．孔洞处气泡优先形核、长大和破裂并发展成为缺陷而使涂层失效     

n-Al2O3/Ni复合镀层的组织与滑动磨损性能研究

用电刷镀技术制得了镍基n-Al2O3复合镀层，并对镀层的滑动磨损性能进行了试验研究。纳米复合镀层的表面形貌比较细腻，镀层中纳米粒子分布均匀，与基质金属结合紧密。镀层显微硬度达到HV700，比快速镍镀层提高约40％。滑动磨损试验结果表明，随着纳米粒子含量的增大，镀层的耐磨性提高，摩擦系数也呈增大趋势；但当镀层中n-Al2O3粒子的超过2.56%(质量分数）时，镀层的耐磨性显著下降。纳米复合镀层的磨损机制以疲劳磨损为主，而快速镍底层以粘着磨损为主。     

石英晶体监控法镀制高精度光学薄膜

讨论了石英晶体监控法在光学薄膜镀制过程中的应用原理。通过与常规的光学监控法镀制的膜层相比较．证实了石英晶体监控法有助于提高光学薄膜的光学品质。试验表明所镀膜层的光学性能优异，在光通信和激光器等领域具有广阔的应用前景。     

Al2O3基耐磨陶瓷涂层的燃烧合成与应用

介绍了燃烧合成表面涂层技术的基本原理 ,开发了相应的制备工艺 ,并在此基础上研制了内覆陶瓷涂层的复合钢管、弯管及弯头。陶瓷涂层主要由α Al2 O3相、部分FeO·Al2 O3相和 3Al2 O3·2SiO2 相组成 ,采用添加剂可以有效提高熔体的流动性 ,使陶瓷的凝固和结晶过程得到进一步控制 ,有助于减少孔隙 ,提高陶瓷涂层的致密度。现场应用试验表明 ,涂层具有较好的耐磨性能 ,可使设备的使用寿命大为延长